H2O maser pumping: The effect of quasi-resonance energy transfer in collisions between H2 and H2O molecules

The effect of quasi-resonance energy transfer in collisions between H₂ and H₂O molecules in H₂O maser sources is investigated. New data on the state-to-state rate coefficients for collisional transitions for H₂O and H₂ molecules are used in the calculations. The results of ortho-H₂O level population inversion calculations for the 22.2-, 380-, 439-, and 621-GHz transitions are presented. The ortho-H₂O level population inversion is shown to depend significantly on the population distribution of the para-H₂ J = 0 and 2 rotational levels. The possibility of quasi-resonance energy transfer in collisions between H₂ molecules at highly excited rotational-vibrational levels and H₂O molecules is considered. The quasi-resonance energy transfer effect can play a significant role in pumping H₂O masers in the central regions of active galactic nuclei and in star-forming regions.