The solubility of calcite,strontianite and witherite in NaCl solutions at 25°C

The solubility of CaCO₃ (calcite), SiCO₃ (strontianite), and BaCO₃ (witherite) has been determined in NaCl solutions from 0.1 to 6 m at 25°C. Activity coefficients estimated from Pitzer's equations with higher order interaction terms (θ and Ψ) were used to extrapolate the results to infinite dilution. Thermodynamic values of $\text{pK}{}_{\mathrm{sp}}\text{= 8.46 ± 0.03,9.13 ± 0.03}$ and $\text{8.56 ± 0.04}$ were found, respectively, for CaCO₃, SrCO₃ and BaCO₃ at 25°C. These results are in reasonable agreement with literature data. Since Pitzer parameters for the interactions of CO₃^2? with Ca²⁺, Sr²⁺ and Ba²⁺ were not used, our results indicate that they are not necessary at low values of $\text{P}{}_{\mathrm{co2}}$.