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Low temperature\lg f_{O_2 } - pH diagrams of sulfur isotope evolution in an equilibrium hydrothermal system
Authors:Xiachen Zhi  Weiji Cheng
Institution:1. Department of Earth and Space Sciences, University of Science and Technology of China, China
Abstract:According to Sakai-Ohmoto's theory regarding the evolution of sulfur isotopes in hydrothermal systems, in conjunction of new data on chemical resaction equilibrium constants and equilibrium isotopic fractionation factors as well as on individual ion activity coefficients of aqueous sulfur species, the following lgfo2.-pH diagrams are constructed:
  1. mole fractions of aqueous sulfur species (X i ),
  2. stability fields of some minerals in the Fe-S-O system,
  3. diagram depicting the oxidation-reduction-state ratio for aqueous sulfur species (R′)
  4. isotopic compositions of sulfur compounds ( \(\delta S_1 ^{34} \) ).
Keywords:
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