One century sedimentary record of Hg and Pb pollution in the Sagua estuary (Cuba) derived from Pb and Cs chronology

The vertical distribution of Hg and Pb were determined in a sediment core collected from the Sagua estuary (North Cuba) that receives input from the Sagua river, one of the most polluted rivers discharging into the Cuban coastal environment. Depth profiles of metal concentrations were converted to time-based profiles using the ²¹⁰Pb dating method and confirmed with the ¹³⁷Cs fallout peak. The mean mass accumulation rate was estimated to be 0.17 ± 0.04 g cm⁻² y⁻¹ (mean sediment accumulation rate 0.52 ± 0.13 cm y⁻¹) and the core bottom was estimated to date back about 130 years. The historical sedimentary record showed a strong enrichment of mercury concentrations in the past decades, caused by the incomplete treatment of industrial wastes from a chlor-alkali plant with mercury-cell technology in the Sagua river basin. Lead fluxes to sediments showed a gradual increase from the 1920s to present, which agrees with a population increase in Sagua la Grande City. Fluxes of both metals have increased the past 25 years, with values reaching a maximum of 0.5 and 3.9 μg cm⁻² y⁻¹ for Hg and Pb, respectively.