Origin and diagenesis of the Roque Nublo breccia,Gran Canaria (Canary Islands) — Petrology of roque nublo volcanics,II

The Pliocene Roque Nublo Series, the second of three major magmatic series on Gran Canaria (Canary Islands), consists of a lower sequence (200 m) of alkalic lavas (basanite to phonolite) and a thicker upper section (600 m) of interlayered lava and widespread breccia sheets: encompassing pyroclastic flow deposits, lahars and reworked epiclastic rocks. Components in the poorly sorted block — and ash — flow deposits are (unwelded) pumice, rock fragments, crystals, glass shards and, locally, bread-crust bombs. Some flow units are graded with fine-grained basal zones and lithic-rich lower and pumice-rich upper parts. Some have strongly grooved the underlying rocks, directions of these striations being independent of preexisting topography and are constant in direction for more than 5 km. The flows are thought to have been emplaced below minimum welding temperatures by collapse of eruption columns. They are similar in many respects to coarse-grained pyroclastic flow deposits found in andesite volcanoes. Glass of tephritic to phonolitic composition of clasts of the breccias is generally altered to «palagonite» and is partly replaced by clay minerals and zeolites (mainly chabazite and phillipsite). Palagonitization was a low temperature diagenetic process, resulting in the hydration of glass accompanied and followed by precipitation of zeolites and clay minerals. Electron-microprobe data suggest the following decreasing order of mobility of selected elements during palagonitization: Na, K, Al, Si, Ca, Mg, and Fe; Ti was assumed to be inert.