Geochemical surveillance of active volcanoes: data on the fumaroles of Vulcano (Aeolian Islands,Italy)

Temperature and chemical composition of condensates of higher temperature fumaroles, located on the rim of the crater of Vulcano, were studied over a period of one year. Maximum temperature changed from 216°C (June 1977) to 291°C (May 1978). HCl is the main constituent of condensates which, in comparison with data from fumaroles of other volcanoes, contain also noteworthy quantities of boron and bromine. Since these chemical characteristics suggested the possible inflow of water of marine origin into the volcanic conduit, experimental data on seawater-rock reactions at high temperatures and pressures were taken into account. A model is drafted for the volcanic system, in which the occurrence of an aquifer interposed between the magma chamber and the surface is considered. The vaporization of this aquifer would feed the fumaroles giving rise, through different mixing processes with surface waters, to the observed differences in temperature and chemical composition. However, data available at present are not sufficient to support the proposed model, which must be mainly considered as a working hypothesis.