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Dust formation and evolution in a Ca–Fe–SiO–H2–O2 vapour phase condensation experiment and astronomical implications
Authors:Frans J M Rietmeijer  Aurora Pun  Joseph A Nuth III
Institution:Department of Earth and Planetary Sciences, MSC03-2040, 1-University of New Mexico, Albuquerque, NM 87131-0001, USA;Astrochemistry Laboratory, Solar System Exploration Division, Code 691, NASA Goddard Space Flight Center, Greenbelt, MD 20771, USA
Abstract:Here, we report on a kinetically controlled vapour phase condensation experiment using a low-calcium Ca–Fe–SiO–H2–O2 vapour. Under these conditions of extreme disequilibrium, the condensate properties become predictable. They are amorphous solids with (predictable) deep metastable eutectic compositions. This study also shows how chemical evolution of the condensate grains will lead to chemically complex amorphous solids. The highly disordered structure of the deep metastable eutectic condensates is the very key to this predictable chemical evolution to grains with a silicate mineral composition, yet being amorphous. We compare our results with astronomical observations of dust around young stellar objects.
Keywords:astrochemistry  methods: laboratory  Solar system: general  planetary systems: protoplanetary discs
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