The origin of alluvial gold in the Leadhills area of Scotland: evidence from interpretation of internal chemical characteristics

A detailed chemical study has been carried out of 1794 gold grains from 55 sites within an area approximately 7 km by 18 km around Leadhills in the turbidite-facies, wacke-dominant Southern Uplands terrane of Scotland, formed as an accretionary thrust complex at the Laurentian continental margin during Ordovician and Silurian subduction of the Iapetus Ocean. The Leadhills area has had a long history of alluvial gold working, since at least 1510, and probably much earlier, but few bedrock sources of mineralisation have been located. Quantitative electron microprobe point analyses were obtained of sectioned and polished gold grains and of the associated microscopic inclusions, which in total comprised 35 types of opaque minerals. Microchemical X-ray maps were also obtained using a fully automated electron microprobe to show internal chemical compositional variation, to resolve the components of multiple and composite inclusions and to help in the identification of the smallest examples. Silver is present within most grains but Cu, Hg and Pd were only detected in about 3% of the grains. The shapes of cumulative frequency plots of the Ag contents of grains from different sites allow recognition of populations from different sources and enables comparison and differentiation between sites. In one of the main rivers, the Shortcleugh Water, the nature of the gold is generally similar, both in terms of Ag content and inclusion type, but a further type of gold, relatively rich in Ag and containing distinctive Ni and Sb-rich inclusions, is also present in 4 adjacent samples in one sector of the watercourse. This component of the samples reflects downstream dispersion, of up to 400 m, of gold grains from a mineralised structure cutting the river almost perpendicularly. Elsewhere abrupt changes in the nature of the alluvial gold within streams reflect a series of different sources and indicate limited glacial and alluvial dispersion. Four main types of gold which are considered to be derived from different varieties of source mineralisation can be recognised on the basis of composition and inclusion assemblage. The commonest type (ca. 70%) contains 8.4–13.1% Ag and inclusions, mostly of arsenopyrite, pyrrhotite, pyrite, chalcopyrite, galena, sphalerite and cobaltite, characteristics typical of mesothermal gold from shear-zones within a turbidite environment, suggesting sources within the local Lower Palaeozoic sedimentary rocks. The second type is richer in Ag (15.8–31.3%) with a basic igneous signature indicated from inclusions of Sb-rich gersdorffite, pyrite, Ni arsenide and other Ni-rich minerals, and shows some spatial association with discordant Tertiary basaltic dykes which cut the sedimentary rocks. The third type, mostly found in an area mantled by glacial drift, is poor in Ag (<1.2%) but frequently Cu-bearing and with inclusions of platinoids and Cu oxide. Associated with this type of gold are grains of the intermetallic compound Au₃Cu and platinoids such as isoferroplatinum and a complex Ir-rich phase. Its source is problematical and could partly reflect detrital material associated with ophiolitic debris, which is common in the northernmost turbidites, and partly a local source of lode gold. The fourth gold type is also Ag-poor (<3.2%), but frequently contains Pd, up to 6.3%, while the inclusions comprise selenides of Pb, Hg and Cu. In nearby areas this type of gold is associated with Permian red beds and associated basaltic volcanics and also structures in the Lower Palaeozoic into which oxidising solutions derived from the red bed sequence have penetrated.