Radiative association in Li+H revisited: the role of quasi-bound states

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.