The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system |
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Authors: | Gu Hongkan Liu Mingxing Li Guoji Bao Wanyou Zhang Shoulin |
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Affiliation: | (1) Institute of Oceanology, Academia Sinica, Qingdao |
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Abstract: | The experimental results show that, when the water is evaporated, the trace metal ions Zn2+ etc contained in this water can transfer in 100% concentration to water vapor under the limiting concentration of transfer. Therefore, the free energy, ΔG 0, can not be used directly to predict the feasibility of this trace concentration physico-chemical process. Occurrence of the thermodynamics anomaly phenomenon in trace concentration physico-chemical system is presented experimentally in the present paper. Contribution No. 1070 from the Institute of Oceanology, Academia Sinica. |
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