Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.     

冬半年青藏高原低涡发生发展的天气学分析

本文针对冬半年高原低涡几个不同源地的低涡生成背景,着重分析500hpa环流场,指出:地形对低涡生成是非常重要的条件,但一定范围内有利的环境流场也是低涡生成不可缺少的外部条件。并给出了不同涡源区有利于低涡发生,发展的500hpa环流形势。     

一次西南低涡过程的地面场中尺度分析

本文运用带通滤波分析方法,对四川省1981年7月由西南低涡等天气系统引起的大暴雨过程作了地面气象要素场的中尺度诊断分析。结果表明,带通滤波后的场具有明显的中尺度特征,其中一些物理量场的适当配置与6小时后的暴雨中心有较好的对应关系。说明了此带通滤波方法在实际业务预报中具有一定的使用价值。     

调频式电涡传感器微机实现的探讨

分析了分频和ＣＴＣ计数采样中误读数的原因和解决方法，并利用微机软件实现非线性校正。此传感器用于位移测量系统中，具有０．０１ｍｍ的分辨率及优于１％的精度，可在－２０～６０℃温度范围内工作。     

摩擦作用对西南低涡扰动的影响

西南低涡是对流层下层的中尺度扰动。本文在零级近似条件下,采用p坐标系的基本方程组,在边界层内设计两层模式。通过一定的简化方程组后,得到:当Z≤1/2[kL~2/(μ~2Knu~*)] 时,摩擦效应具有二重性,一方面使扰动减弱;另一方面使扰动增强,而前者的影响略大于后者,最终使扰动消失。频率随高度Z的降低而增加。当Z>1/2[kL~2/(μ~2Knμ~*)]时,摩擦作用甚微,几乎可以忽略不计。频率虽然有两个值,但随高度Z的增加,他们趋于一个常值。     

Gravitational collapse and equilibrium conditions of a toroidal vortex with thermal pressure

We found the equilibrium conditions for a self-gravitating toroidal vortex by taking thermal pressure into account. These conditions are shown to significantly differ from those for a disk or a sphere. The evolution of a thin vortex turns it into a compact vortex that loses mechanical stability for low masses at a polytropic index γ<4/3 but retains stability for sufficiently high masses and densities determined by the velocity circulation in the vortex.     

氢化物发生及其在分析检测领域的应用

论述了氢化物发生的条件和普遍性及其在分析检测领域的应用,这些领域包括试样分解,分离富集,容量分析、比色分析、原子荧光光谱、原子吸收光谱、电感耦合等离子体原子发射光谱、电感耦合等离子体质谱等分析测试技术。     

微型氢化物发生装置在冷原子吸收分光光度法测汞中的应用

采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。     

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。     

无机盐类对天然矿物低温催化混合酯生烃反应的影响

脂肪酸酯是一类重要的生烃母质。选择了十四烷酸甲酯、十六烷酸甲酯和十八烷酸甲酯的混合酯为模型反应物,以方解石、白云石、伊利石、钙蒙脱石和黄铁矿为催化剂,分别考察了氯化钾、氯化镁、氯化钠、硫酸钠以及混合盐对天然矿物低温催化混合酯生烃反应的影响。结果表明,无机盐类对矿物催化下混合酯的生烃反应均有不同程度的影响,硫酸钠具有反催化作用,其它盐类具有正催化作用。且在各无机盐存在下,不同的矿物表现出不同的催化活性。