Biological and granulometric controls on sedimentary organic matter of an intertidal mudflat

A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.     

Depositional and post‐depositional history of warm stage deposits at Knocknacran,Co. Monaghan,Ireland: implications for preservation of Irish last interglacial deposits

Organic‐rich deposits, uncovered during overburden removal from mantled gypsum karst at Knocknacran opencast gypsum mine, Co. Monaghan, are the best candidate to date for a last interglacial record in Ireland. The two till and organic‐rich deposits (preserved at different quarry elevations) were emplaced on to a Tertiary dolerite surface during high‐energy flood events and subsequently folded and faulted by movement towards sinkholes in underlying gypsum. Uranium–thorium disequilibrium dating suggests that the organic‐rich deposits in the upper section were hydrologically isolated at ca. 41 ka and those in the lower section at ca. 86 ka. Interpretation of the pollen content, although tentative because of the depositional and post‐depositional history of the material, suggests that the organic material originated in a warm stage possibly warmer than the post‐Eemian interstadials. The unusual setting of preservation may indicate that in situ, last interglacial deposits have generally been removed by erosion in Ireland. Copyright © 2004 John Wiley & Sons, Ltd.     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

Natural radioactivity in sediment of Wei River,China

The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China. The activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in sediment samples ranged from 10.4 to 39.9 Bq kg⁻¹, 15.3 to 54.8 Bq kg⁻¹ and 514.8 to 1,175.5 Bq kg⁻¹, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities of Chinese soil and Shaanxi soil. Radium equivalent activity (Ra_eq), external hazard index (H _ex) and representative level index (I _γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the construction of dwellings. All the sediment samples have Ra_eq lower than the limit of 370 Bq kg⁻¹, H _ex less than unity and I _γr close to 1 Bq kg⁻¹. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h⁻¹ and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological risk and sediment can be safely used in construction.     

Controls on porphyroblast size along a regional metamorphic field gradient

Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens, respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites.     

庵东浅滩沉积分带和沉积速率

杭州湾南岸的庵东浅滩具有地貌特征、沉积类型和沉积构造各异的三个沉积相带。垂向沉积带为潮滩沉积体的盖层,以泥滩、粘土质粉砂和薄砂泥交互层为特征;改造带位于中低潮位线附近,以粉砂滩、潮沟系统、粉砂沉积和沙波层理为特征;横向沉积带为潮滩堆积体的基础,以滩坡、粉砂及细砂质粉砂沉积、冲刷-充填构造为特征。据潮汐韵律层的统计,庵东浅滩沉积速率的短周期分量,常态条件下为每半日潮周期0.1～2.0cm,异常条件下可达每半日潮周期4～64cm。沉积速率的长周期分量,据地形对比和~(210)Pb推算,垂向沉积带为2～4.5cm/a;改造带中的粉砂滩为2.1～4.5cm/a,潮沟影响范围内为1～10~1cm/a量级;横向沉积带则以高于50cm/a的高沉积速率和变幅为主。近10年来,该浅滩的年淤积量为6×10~7t/a,其中85％集中于横向沉积带。     

南黄海表层沉积物天然湿容重和含水量的分布及其与粒度之间的关系

本文论述了南黄海表层沉积物天然湿容重和含水量的分布,并利用回归分析的方法讨论了容重和含水量与粒度之间的关系。结果表明,容重和含水量与粘土粒级相关性最好,容重与粘土粒级含量(相似文献   

Field observations of waves generated by passing ships: A note

This short contribution reports the results of a field study on the nearshore characteristics of waves generated by both conventional and high speed passenger ferries. The field observations took place in the late summer of 2005, at a beach close to the port of Mytilene (Island of Lesbos, Greece), and involved the visual observation of ship waves, using digital video recordings and image processing techniques. The results showed that passage of the fast ferry was associated with a longer, more complex and energetic nearshore event; this event not only did include higher nearshore waves (up to 0.74 m) and was organised in different wave packets, but it was also an order of magnitude longer (∼ 680 s) than the conventional ferry event. Regarding the effects on beach sediment dynamics, the fast ferry waves were estimated to be very efficient in mobilising the nearshore sediments in contrast to those of the conventional ferry. The fast ferry service appears to generate daily prolonged nearshore events, which contain waves with higher energy than those expected from the normal summer wind wave regime of the area; these events also include some high and very steep waves, which can be particularly erosive. Therefore, fast ferry wakes may have considerable impacts on the seasonal beach sediment dynamics/morphodynamics and the nearshore benthic ecology, as well as they may pose significant risks to bathers, affecting the recreational use of the beaches exposed to fast ferry traffic. Finally, the study has shown that satisfactory field observations of the nearshore characteristics of ship-generated (and wind) waves can be obtained using inshore deployments of calibrated poles, digital video cameras and appropriate image processing algorithms.     

Response of the barrier island coastal region of southwestern Nigeria to climate and non-climate forcing

Despite threats emanating from the influence of climate and non-climate forcing on the barrier island coastal region of southwestern Nigeria, the extent of the coastal erosion is poorly understood. We report evidence of coastal erosion and sediment accumulation in the region over a 34-year period (1973–2017), using Landsat imagery at intervals of approximately six years. Landsat image corrections and various water-extraction algorithms were used to systematically delineate coastal erosion and accumulation in the area. The region was subdivided into western and eastern subregions separated by Lagos Harbour. In the west, erosion took place during the periods 1973–1979, 1979–1984, 1990–1999 and 2005–2011, whereas in the east, erosion occurred during 1973–1979, 1990–1999 and 1999–2005. Coastal sediment accumulation occurred in the east during 1979–1984, 1984–1990, 2005–2011 and 2011–2017, whereas gains in the west occurred during 1984–1990, 1999–2005 and 2011–2017. The study revealed substantial net erosion of 1 228.1 ha in the region as a whole, over the full period. Sediment accumulation accompanying the coastal erosion appears to be linked to longshore drift. Erosion between 1973 and 2011 was probably attributable to climate change (storms and tidal conditions), longshore drift, the inflow and outflow of water at Lagos Harbour, coastal morphology and, possibly, human impacts. However, the coastal changes between 2011 and 2017 were more obviously associated with human activities, such as development of the Eko Atlantic construction project. Coastal surveillance, together with the use of environmentally sensitive protective measures, could possibly help to reduce coastal erosion in the region. Careful coastal management practices, including artificial nourishing and the installation of resilient structures (e.g. seawalls), should be undertaken to protect human settlements that are already at risk from sea-level rise.