The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

Coupled and complex: Human-environment interaction in the Greater Yellowstone Ecosystem, USA

Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years.     

Genetic Diversity in Marine Molluscs: A Test of the Niche-Width Variation Hypothesis

Abstract. A test of the niche width variation hypothesis was conducted in the three Mediterranean littoral species of the family Trochidae: Monodonta turbinata, M. turbiformis and Gibbula richardi. Allozymic variation encoded by 26 gene loci was analyzed, and the levels of polymorphism (P), heterozygosity (H) and allele diversity per locus (A) were estimated and appear to support the niche-width variation hypothesis. The broad-niche species, M. turbiformis and G. richardi are more polymorphic and heterozygous than the relatively narrow-niche M. turbinata (P = 0.571; 0.731 and 0.417; H = 0.108; 0.116 and 0.078; A = 2.025; 2.489 and 1.965, respectively).     

A comparative study on the contents of vitamins in the natural and the cultured prawn

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Artificial Upwelling of Deep Seawater Using the Perpetual Salt Fountain for Cultivation of Ocean Desert

Deep seawater in the ocean contains a great deal of nutrients. Stommel et al. have proposed the notion of a “perpetual salt fountain” (Stommel et al., 1956). They noted the possibility of a permanent upwelling of deep seawater with no additional external energy source. If we can cause deep seawater to upwell extensively, we can achieve an ocean farm. We have succeeded in measuring the upwelling velocity by an experiment in the Mariana Trench area using a special measurement system. A 0.3 m diameter, 280 m long soft pipe made of PVC sheet was used in the experiment. The measured data, a verification experiment, and numerical simulation results, gave an estimate of upwelling velocity of 212 m/day. This revised version was published online in July 2006 with corrections to the Cover Date.     

天然气水合物成矿的沉积控制因素

天然气水合物是一种非常规的天然气矿藏，其形成与分布除了需要特定的温压条件外，还需要合适的沉积条件。截止2002年底，世界上共有l16处已直接或间接发现水合物，直接见到水合物样品的只有23处(海洋20处、陆地3处)，所以对水合物沉积条件的系统研究处于比较薄弱的阶段，文献报道也较少，目前认为其形成的沉积控制因素主要有岩性、沉积速率、有机碳含量、沉积环境及沉积相等4方面。     

苏北盐城凹陷复合含油气系统

苏北盐城凹陷含油气系统可划分为上、下2个复合含油气系统。上复合含油气系统，即Pz、K2p、K2t(生)-K2t、E1f1(储)一E1f1 E1f2(盖)，古生界、中生界浦口组和泰州组为烃源岩层，泰州组和阜宁组一段为储集层，阜宁组一段顶部至二段暗色泥岩为区域盖层，油气沿深大断裂运移，油气成藏关键时刻在古近纪晚期至新近纪早期，有利勘探区在深大断裂附近的中、新生界发育地区；下复合含油气系统，即Pz、K2p(生)-Pz、K2p(储)-K2p3 K2p4(盖)，油气通过断层或不整合运移，油气大量生成的关键时刻为古近纪早期，该系统中气藏分布在古生界被中生界覆盖地区。