Modelling of deformation response and chemo‐mechanical coupling in chalk

A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.     

Estimation of dispersion in estuaries by a self-consistent method

Longitudinal and transverse dispersion in estuaries may be determined in principle by measuring the change in time of the concentration field of a water soluble dye. In practice, measurements may take the form of several sampling runs crossing the dye patch. The coefficients of dispersion are usually estimated from the second moments of the concentration field; the use of second moments, in particular, introduces errors because measurements at long times or distance are unduly emphasized.A self-consistent method, free of the disadvantages inherent in the use of higher moments, is described in which the distribution of concentration in space is related to the zeroth spatial moment of concentration. In this formulation, based upon sampling runs across the dye patch, the concentration field in the estuary may be directly and simply related to the dispersion coefficients in both the intercept and gradient of a linear graph.The methods are illustrated by the characterization of a series of experiments in the Inner Estuary of Milford Haven.     

A transdisciplinary analysis of water problems in the mountainous karst areas of Morocco

Water management and engineering in the karstic High Atlas of Morocco are difficult tasks under the prevailing geological, hydrogeological, geomorphological, vegetational and climatic conditions. It is important to be able to understand and predict the characteristics and availability of water for future water planning in the region under changing climatic and agricultural conditions. An interdisciplinary analysis of problems and adequate hydrological modelling tools developed by geologists, hydrologists and biologists are necessary. The karst areas of the High Atlas Mountains are characterised by impermeable triassic basalt underlying substantial subsurface reservoirs with high potential discharge rates. The karst groundwater aquifers are extensive but largely unknown in dimension, probably with a hierarchical network of groundwater flow paths. It is estimated that approximately 70% of the surface water is directly lost to groundwater. Steep landslide- and debris flow prone slopes exist next to coarse-grained, highly porous river beds. Infrequent, high intensity rainfall or snowmelt causes a particularly high flood risk to these karst areas. In addition, agriculture and land use changes have degraded the karst areas. The most important driving forces for degradation include permanent overgrazing even during droughts and the use of firewood by a continually growing population. Large scale degradation of vegetation has occurred in the oro-mediterranean (mountainous Mediterranean) zone, between 2600 and 3400 m which coincides with the most important zone for karstic groundwater creation. The combination of high amounts of groundwater flow and rapid surface flow due to sparse vegetation has increased the problems of flood flow.     

Seasonally Hypersaline Estuaries in Mediterranean-climate Regions

Data collected in three Californian estuaries indicate that hypersaline conditions exist during the dry summers typical of a Mediterranean climate. The generalised seasonal and longitudinal hydrographic structures are described and explained. It is argued that this seasonal hypersalinity is common and that it represents a major class of estuaries. The observed accumulation of salt indicates surprisingly long residence times in small basins which have free exchange with the ocean. This semi-isolation of the inner basin leads to a large build-up or severe depletion of nutrients, pollutants and plankton in these systems. Of concern are the trends to increase pollutant loading in the same systems that are experiencing an increase in residence times owing to freshwater extraction in the watershed.     

Strength Analysis of Turret Mooring Productive/Storage Tanker

The longitudinal strength of turret mooring productive/storage tanker is studied.A numeri-cal example has been implemented according to the method presented in this paper to give practical il-lustration.From the results of the numerical example,it is concluded that the turret hole located near theforward of the amidships has small effect on the longitudinal strength of the ship hull.As for design ex-treme value of wave bending moment of storage tanker,statistic method is a more reasonablemethodology,especially with the consideration of the servere environmental conditions.The primary esti-mation of design section modulus of turret storage tanker can be determined by this design bending mo-ment.     

ZnS柱撑高岭石-蒙脱石混层矿物纳米复合材料的制备及其光降解伊红-B的研究

以硫尿和乙酸锌为前驱物,通过离子交换和溶液热反应的方法在有机高岭石蒙脱石混层矿物(高蒙混层矿物)层间原位合成了ZnS纳米粒子,得到ZnS柱撑高岭石蒙脱石混层矿物纳米复合材料。X射线粉末衍射分析(XRD)表明高蒙混层矿物的d001从原来的0.98nm被柱撑到1.95nm,表明层间被插入了直径小于1nm的ZnS纳米颗粒。扫描电镜(SEM)观察发现,原高蒙混层矿物的有序片层结构部分被破坏,在被剥离的片层上面均匀覆盖了ZnS颗粒聚集体,粒径在25nm左右。透射电镜(TEM)显示,ZnS颗粒聚集体是由3～5nm的颗粒堆积而成,夹杂在被剥离的高蒙混层矿物层中。选区电子衍射(SAED)和能量散射谱(EDS)测定表明形成的ZnS属于六方晶系,结晶度较低。光降解伊红_B(eosion_B)实验表明该纳米复合物具有极高的反应活性,紫外可见吸收光谱(UV_Vis)跟踪反应历程,表明降解过程中没有其他中间产物生成,20min之内降解率达到99.1%。本方法制备的ZnS柱撑高蒙混层矿物纳米复合材料与前人制备的ZnS纳米粒子相比具有更高的催化活性,方法更简单,原料较便宜,可重复利用。     

Soil degradation: a global problem endangering sustainable development

1 Introduction Soil is not only the major natural resource on which human being depends for the production of food, feed, fiber, renewable energy and raw materials, but also plays a key role in maintaining the complex terrestrial ecosystems and climate systems of this planet. Recent rapid increase in the human population is placing a great strain on the worlds soil resources. Only about 11% of the global land surface covered by the soils are being used to raise crops and livestock, in other …     

Changes in soil organic carbon and other physical soil properties along adjacent Mediterranean forest, grassland, and cropland ecosystems in Turkey

Cultivation, overgrazing, and overharvesting are seriously degrading forest and grassland ecosystems in the Taurus Mountains of the southern Mediterranean region of Turkey. This study investigated the effects of changes on soil organic carbon (SOC) content and other physical soil properties over a 12-year period in three adjacent ecosystems in a Mediterranean plateau. The ecosystems were cropland (converted from grasslands in 1990), open forest, and grassland. Soil samples from two depths, 0–10 and 10–20 cm, were collected for chemical and physical analyses at each of cropland, open forest, and grassland ecosystems. SOC pools at the 0–20 cm depth of cropland, forest, and grassland ecosystems were estimated at 32,636, 56,480, and 57,317 kg ha⁻¹, respectively. Conversion of grassland into cropland during the 12-year period increased the bulk density by 10.5% and soil erodibility by 46.2%; it decreased SOM by 48.8%, SOC content by 43%, available water capacity (AWC) by 30.5%, and total porosity by 9.1% for the 0–20 cm soil depth (p<0.001). The correlation matrix revealed that SOC content was positively correlated with AWC, total porosity, mean weight diameter (MWD), forest, and grassland, and negatively with bulk density, pH, soil erodibility factor, and cropland. The multiple regression (MLR) models indicated that any two of the three ecosystems and one of the two soil depths accounted for 86.5% of variation in mean SOC values ((p<0.001).     

Longitudinal Displacement of the Subtropical High in the Western Pacific in Summer and its Influence

Using the relative vorticity averaged over a certain area, a new index for measuring the longitudinal position of the subtropical high (SH) in the western Pacific is proposed to avoid the increasing trend of heights in the previous indices based on geopotential height. The years of extreme westward and eastward extension of SH using the new index are in good agreement with those defined by height index. There exists a distinct difference in large-scale circulation between the eastward and westward extension of SH under the new definition, which includes not only the circulation in the middle latitudes but also the flow in the lower latitudes. It seems that when the SH extends far to the east (west), the summer monsoon in the South China Sea is stronger (weaker) and established earlier (later). In addition, there exists a good relationship between the longitudinal position of SH and the summer rainfall in China. A remarkable negative correlation area appears in the Changjiang River valley, indicating that when the SH extends westward (eastward), the precipitation in that region increases (decreases). A positive correlation region is found in South China, showing the decrease of rainfall when the SH extends westward. On the other hand, the rainfall is heavier when the SH retreats eastward. However, the anomalous longitudinal position of SH is not significantly related to the precipitation in North China. The calculation of correlation coefficients between the index of longitudinal position of SH and surface temperature in China shows that a large area of positive values, higher than 0.6 in the center, covers the whole of North China, even extending eastward to the Korean Peninsula and Japan Islands when using NCEP/NCAR reanalysis data to do the correlation calculation. This means that when the longitudinal position of the SH withdraws eastward in summer, the temperature over North China is higher. On the other hand, when it moves westward, the temperature there is lower. This could explain the phenomenon of the seriously high temperatures over North China during recent summers, because the longitudinal position of SH in recent summers was located far away from the Asian continent. Another region with large negative correlation coefficients is found in South China.     

元谋干热河谷坡耕地土壤侵蚀造成的土地退化

在元谋干热河谷土壤侵蚀特征分析的基础上，对坡耕地土壤侵蚀造成的土地退化进行了模拟研究。结果表明，土壤侵蚀造成表层耕作土壤的物理性能下降、养分流失和水分入渗能力降低。表层耕作土壤的容重比下层土壤低12．7％，总孔隙度高10．9％，有机质高37．3％，120min累计入渗总量是下层土壤的1．6-2．2倍。模拟土壤侵蚀与土地生产力关系的小区试验结果显示，坡耕地每流失1cm表土，土地生产力水平平均下降4．54％。