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1.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
  相似文献   
2.
The concentrations of twenty four chemical elements in the surface layer of natural desert soils and the cultivated farmland soils were measured at a desert-oasis ecotone in the middle of Heihe river basin, north-west China. Background values were estimated for (a) major elements (Si 335.3 g kg− 1, Al 49.4 g kg− 1, Fe 19.1 g kg− 1, Ca 29.4 g kg− 1, Mg 8.9 g kg− 1, K 20.1 g kg− 1, Na 17.5 g kg− 1 and P 0.338 g kg− 1), (b) heavy metals and non-metals (Cr 55.8 mg kg− 1, Mn 404.8 mg kg− 1, Ni 17.7 mg kg− 1, Cu 5.1 mg kg− 1, Zn 33.7 mg kg− 1, Pb 15.5 mg kg− 1 and As 5.2 mg kg− 1) and (c) other trace elements (Ti 2.0 mg kg− 1, V 55.3 mg kg− 1, Co 5.7 mg kg− 1, Rb 82.4 mg kg− 1, Sr 232.9 mg kg− 1, Y 14.7 mg kg− 1, Zr 194.9 mg kg− 1, Nb 7.8 mg kg− 1 and Ba 720.6 mg kg− 1). After natural desert soil was cultivated for agricultural use, significant changes in element concentrations occurred under tillage, irrigation and fertilisation management. Compared to natural soil, the for the levels of Si, K, Na, Sr, Zr and Ba decreased, and no changes were observed for Rb, while the values of the other 17 elements increase in agricultural soil from 1.2 to 3.5 times. However, their absolute concentrations are still low, suggesting that the arable soil in this region remains comparatively a clean soil. The increased silt, clay and organic carbon content, under long-term irrigation, enriched the fine-grained materials, and application of fertilisers and manure contributed to the accumulation of most elements in arable soil. The accumulation of elements in agricultural soil increased with increasing cultivation years and extent of soil development.  相似文献   
3.
把鹧鸪菜藻体切成大小不同的切段、以及任意切碎,培养于添加氮、磷素的消毒海水中,后者分10℃、15℃、20℃、25℃四种不同温度条件培养,结果全部切段、切碎片都很快再生出假根附着于基质,并再生出一至多个叶状体;叶状体长大后从基部长出新的假根成为完整的幼苗(再生苗)。试验表明,大的切段其再生苗生长快、长度大,但出苗率(一定长度的藻体长出再生苗数量)低。培养温度较高时(20—25℃),藻体任意切碎片再生速度快、附着速度快、数量多且较牢固。利用藻体切碎片来培养鹧鸪菜幼苗是可行的;培养的适宜温度为20℃以上、海水比重为1.010左右。本文还对鹧鸪菜损伤藻体再生的情况(繁殖生殖学)进行一些观察和描述。  相似文献   
4.
大型海藻对富营养化海湾生物修复的研究进展   总被引:2,自引:0,他引:2  
近年来,我国诸多海湾富营养化严重,海湾赤潮和大规模的养殖生物病害频繁发生,海湾生态系统严重失衡。海带、裙带菜、紫菜、龙须菜等大型经济海藻,生物量大、生产力高,在生长过程中能大量吸收C、N、P等营养物质,栽培大型海藻是吸收、利用营养物质,防治富营养化的有效措施之一。本文综述了规模化栽培大型海藻对富营养化海湾生物修复的研究进展。  相似文献   
5.
虾塘赤潮灾害的防治对策   总被引:2,自引:1,他引:2  
本文报道了一次虾塘赤潮的防治过程,结合国内外有关赤潮防治的动态和作者的经验,提出了一些为避免虾塘内发生赤潮的防治对策。  相似文献   
6.
冬至初春黄海暖流的路径和起源   总被引:18,自引:0,他引:18  
主要根据近几年来中韩黄海水循环动力学合作调查结果,结合有关观测资料,进一步分析了冬至初春黄海暖流的路径和起源.与以往类似研究不同的主要有两点:(1)初步探讨了黄海暖流路径的季节和年际变异,并指出这种变异与北向风的强弱密切相关;(2)通过分析济州岛西侧海域混合水的去向,进一步确认了部分混合水绕济州岛运行,并进入济州海峡这一事实.同时,初步揭示进入黄海的混合水,即黄海暖流水,含有更多的东海陆架水成分.  相似文献   
7.
The radiometers on board the satellites ERS-1, TOPEX/Poseidon, ERS-2, GFO, Jason-1, and Envisat measure brightness temperatures at two or three different frequencies to determine the total columnal water vapor content and wet tropospheric path delay, a major correction to the altimeter range measurements. In order to asses the long-term stability of the path delay, the radiometers are calibrated against vicarious cold and hot references, against each other, and against several atmospheric models. Four of these radiometers exhibit significant drifts in at least one of the channels, resulting in yet unmodeled errors in path delay of up to 1 mm/year, thus limiting the accuracy at which global sea level rise can be inferred from the altimeter range measurements.  相似文献   
8.
等鞭金藻8701培养液的营养组成研究   总被引:4,自引:0,他引:4  
等鞭金藻8701品系是作用(周,孙)新分离的一个单细饵料藻种。其形态构造与绿光等鞭金藻相同,便适温远较后者为低。通过单因子和正交试验表明,培养液的最佳配方是在天然海水中加入NaNO330ppm,CO(HN2)215ppm,KH2PO4或NaH2PO4-8ppm,FeC6H5O70.5ppm,维生素B10.1ppm和维生素B120.0005ppm。  相似文献   
9.
1997~ 1 998年出现了 2 0世纪中最强的一次厄尔尼诺事件。根据长江洪水与厄尔尼诺事件的实测资料 ,指出 1 998年的长江巨洪与这次厄尔尼诺事件具有较密切的关系。同时讨论了厄尔尼诺事件影响长江洪水的物理途径 ,这对长江巨洪的长期及超长期预报具有较重要的指示作用  相似文献   
10.
The purpose of this study was to determine if and how a large, modern estuarine system, situated in the middle of an ancient carbonate platform, has affected its adjacent inner shelf both in the past during the last, post-glacial sea-level rise and during the present. An additional purpose was to determine if and how this inner shelf seaward of a major estuary differed from the inner shelves located just to the north and south but seaward of barrier-island shorelines. Through side-scan sonar mosaicking, bathymetric studies, and ground-truthing using surface grab samples as well as diver observations, two large submarine sand plains were mapped – one being the modern ebb-tidal delta and the other interpreted to be a relict ebb-tidal delta formed earlier in the Holocene. The most seaward portion of the inner shelf studied consists of a field of lobate, bathymetrically elevated, fine-sand accumulations, which were interpreted to be sediment-starved 3D dunes surrounded by small 2D dunes composed of coarse molluscan shell gravel. Additionally, exposed limestone hardbottoms supporting living benthic communities were found as well. This modern shelf sedimentary environment is situated on a large, buried shelf valley, which extends eastward beneath the modern Tampa Bay estuary. These observations plus the absence of an incised shelf valley having surficial bathymetric expression, and the absence of sand bodies normally associated with back-tracking estuarine systems indicate that there was no cross-shelf estuarine retreat path formed during the last rise in sea level. Instead, the modern Tampa Bay formed within a mid-platform, low-relief depression, which was flooded by rising marine waters late in the Holocene. With continued sea-level rise in the late Holocene, this early embayment was translated eastward or landward to its present position, whereby a larger ebb-tidal delta prograded out onto the inner shelf. Extensive linear sand ridges, common to the inner shelves to the north and south, did not form in this shelf province because it was a low-energy, open embayment lacking the wave climate and nearshore zone necessary to create such sand bodies. The distribution of bedforms on the inner shelf and the absence of seaward-oriented 2D dunes on the modern ebb-tidal delta indicate that the modern estuarine system has had little effect on its adjacent inner shelf.  相似文献   
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