TEM study of a special grain boundary in a synthetic K-feldspar bicrystal: Manebach Twin

 A monoclinic KAlSi₃O₈ feldspar Manebach twin boundary was synthesized by diffusion bonding and examined using high-resolution transmission electron microscopy. The sharp (001) twin boundary is straight and free of strain. The boundary width is smaller than d₀₀₁. There is no rigid body shift observed at the twin boundary, and the feldspar structure is arranged symmetrically across (001). The twin boundary structure consists of bridged tetrahedral crankshafts, which are characteristic of the feldspar lattice. The grain boundary structure is in good agreement with the geometrical model of Taylor et al. (1934). The grain boundary composition of K_1/2H_1/2AlSi₃O₈ differs from their model. Received: 13 February 2002 / Accepted: 24 December 2002 Acknowledgements We thank M. Rühle, S. Hutt, J. Mayer, A. Strecker and U. Salzberger at MPI, Stuttgart, for their support and valuable advice in preparing TEM sections of bicrystals.     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

Conceptualizing multiple clusters in mega-city regions: The case of the biomedical industry in Beijing

This paper introduces a unique industrial configuration that has emerged in Beijing, where three economic clusters in the biomedical industry, originally established as industrial/research parks, have developed parallel to each other. This configuration of multiple co-located clusters of the same industry, which has not been discussed before, raises the question of whether the industrial/research parks are competing for the same resources, or whether they are complementary to each other and can collectively be viewed as a new type of industrial configuration. The paper conceptualizes a framework of multiple clusters in mega-city regions that distinguishes between collaborating and competing clusters and presents initial empirical evidence for the Beijing case. As such, this research aims to unravel the phenomenon of multiple clusters in mega-city regions and to understand the complex spatial interrelationships that exist within and beyond multiple co-located clusters in the same industry.     

The Mesozoic structural evolution of the Gorgon Platform,North Carnarvon Basin,Australia

The Gorgon Platform is located on the southeastern edge of the Exmouth Plateau in the North Carnarvon Basin, North West Shelf, Australia. A structural analysis using three-dimensional (3D) seismic data has revealed four major sets of extensional faults, namely, (1) the Exmouth Plateau extensional fault system, (2) the basin bounding fault system (Exmouth Plateau–Gorgon Platform Boundary Fault), (3) an intra-rift fault system in the graben between the Exmouth Plateau and the Gorgon Platform and (4) an intra-rift fault system within the graben between the Exmouth Plateau and the Exmouth Sub-basin. Fault throw-length analyses imply that the initial fault segments, which formed the Exmouth Plateau–Gorgon Platform Boundary Fault (EG Boundary Fault), were subsequently connected vertically and laterally by both soft- and hard-linked structures. These major extensional fault systems were controlled by three different extensional events during the Early and Middle Jurassic, Late Jurassic and Early Cretaceous, and illustrate the strong role of structural inheritance in determining fault orientation and linkage. The Lower and Middle Jurassic and Upper Jurassic to Lower Cretaceous syn-kinematic sequences are separated by unconformities.     

从全球生产网络到全球金融网络：理解全球-地方经济联系的新框架

全球化带来的新国际劳动分工使全球生产网络(Global Production Network, GPN)成为研究全球经济与区域发展的重要框架。与此同时,金融在现代社会经济运行中的地位日益提升,经济金融化在全球不同尺度下深刻影响着经济活动的空间分布和网络。因此,金融已经成为GPN研究不能忽略的重要环节。更重要的是,金融化带来的逻辑也日益深刻地影响到GPN的演化和运行。尽管GPN研究日益重视金融的作用,并开始研究金融业的全球生产网络,但是随着越来越多的企业通过获得国际股权投资或者在境外资本市场上市等方式融入全球资本市场,主要从生产角度理解地方经济融入全球过程的GPN难以对该现象深入分析。全球金融网络(Global Financial Network, GFN)为刻画和分析这个过程提供了新的框架。在这个分析框架中,地方经济体通过高级商业服务业(Advanced Business Service, ABS)企业与世界城市(国际金融中心)和离岸管辖区产生联系,从而融入GFN。论文介绍了GFN的基本结构,探讨了地方经济融入GFN的主要方式及其产生的影响。最后,提出GFN未来在理论和实证方面可继续深入研究的方向。     

Stable 85Rb micro vapour cells: fabrication based on anodic bonding and application in chip-scale atomic clocks

We describe the microfabrication of ⁸⁵Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions, the pure metallic Rb drops and buffer gases were obtained in the cells with a few mm³ internal volumes during the cell sealing process. At an ambient temperature of 90 ℃ the optical absorption resonance of ⁸⁵Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 kHz, have been detected. The sealing quality and the stability of the cells have also been demonstrated experimentally by using the helium leaking detection and the after-9-month optoelectronics measurement which shows a similar CPT signal as its original status. In addition, the physics package of chip-scale atomic clock (CSAC) based on the cell was realized. The measured frequency stability of the physics package can reach to 2.1×10^-10 at one second when the cell was heated to 100 ℃ which proved that the cell has the quality to be used in portable and battery-operated devices.     

Agricultural policy reforms and sustainable land management: a New Zealand case study

This paper examines the link between poverty and land management within the context of New Zealand's almost total removal of subsidies to agriculture since 1984. The impact of these policy changes is explored through the findings from a detailed study of sixteen farms in the North Island hill country. Stress is identified as a primary link between social damage and environmental degradation. This link reinforces the impact of other linkages expressed in reduced production, lower stocking rates, and reduced capital inputs. Deregulation is claimed to be good. This paper shows that in certain circumstances this is not so.     

电感耦合等离子体发射光谱法测定键合用硅铝丝中硅铁铜

采用电感耦合等离子体发射光谱法测定硅铝丝（Al—1％Si）中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法，优化了元素分析谱线和仪器的测量条件。实验表明，方法的加标回收率为99％～1叭％，相对标准偏差（n=6）低于1．4％，Si、Fe、Cu的检出限分别为8．5、1．0和0．4μg／L。该方法应用于快速测定键合硅铝丝中的各种元素，结果满意。     

Urban Economic Cluster Template and Its Dynamics of Beijing,China

Economic clusters have been a central focus of current urban and regional research, policies and practices. However, a meth- odology to identify and analyze policy-relevant economic cluster dynamics is still not well developed. Based on input-output （I-O） data of 1987, 1992, 1997, 2002 and 2007 of Beijing, this article presents an adapted principle component analysis for identifying the evolu- tion of local economic cluster patterns. This research addresses the changes of economic interaction of industries with complementary and common activities over time. The identified clusters provide an insight into the reality of economic development in a diversifying urban economy： the increasing importance of services and the growing interaction between service and manufacturing industries. Our method therefore provides the analysts with a better understanding of the emergence, disappearance and development of economic clus- ters citywide. The results could be used to assist monitoring urban economic development and designing more practical urban economic strategies.