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排序方式: 共有93条查询结果,搜索用时 13 毫秒
1.
Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas 总被引:3,自引:0,他引:3
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters. 相似文献
2.
Sharon S. Crowley Peter D. Warwick Leslie F. Ruppert James Pontolillo 《International Journal of Coal Geology》1997,34(3-4)
The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin. 相似文献
3.
Urban development and flooding in Houston Texas, inferences from remote sensing data using neural network technique 总被引:3,自引:0,他引:3
Shuhab D. Khan 《Environmental Geology》2005,47(8):1120-1127
The effects of urban development on the natural ecosystem and its link to the increased flooding in Houston, Texas were evaluated. Houston is suitable for this type of analysis due to its 1.95 million population, large geographic area and fast growth rate. Using neural network techniques, four Landsat Thematic Mapper images were grouped into five land use classes for the period 1984 to 2003: vegetation, bare ground, water, concrete and asphalt. Results show that asphalt and concrete increased 21% in the time period 1984–1994, 39% in 1994–2000 and 114%, from 2000 to 2003, while vegetation suffered an overall decrease. When change detection data are compared with runoff ratio data, a relationship between increased runoff and urban development is apparent, which indicates increased chances of flooding. Initial results of this work are made available to the public in GIS format via internet using Arc Internet Map Server (ArcIMS) at . 相似文献
4.
This study investigated the potential for the uranium mineral carnotite (K2(UO2)2(VO4)2·3H2O) to precipitate from evaporating groundwater in the Texas Panhandle region of the United States. The evolution of groundwater chemistry during evaporation was modeled with the USGS geochemical code PHREEQC using water-quality data from 100 groundwater wells downloaded from the USGS National Water Information System (NWIS) database. While most modeled groundwater compositions precipitated calcite upon evaporation, not all groundwater became saturated with respect to carnotite with the system open to CO2. Thus, the formation of calcite is not a necessary condition for carnotite to form. Rather, the determining factor in achieving carnotite saturation was the evolution of groundwater chemistry during evaporation following calcite precipitation. Modeling in this study showed that if the initial major-ion groundwater composition was dominated by calcium-magnesium-sulfate (>70 precent Ca + Mg and >50 percent SO4 + Cl) or calcium-magnesium-bicarbonate (>70 percent Ca + Mg and <70 percent HCO3 + CO3) and following the precipitation of calcite, the concentration of calcium was greater than the carbonate alkalinity (2mCa+2 > mHCO3− + 2mCO3−2) carnotite saturation was achieved. If, however, the initial major-ion groundwater composition is sodium-bicarbonate (varying amounts of Na, 40–100 percent Na), calcium-sodium-sulfate, or calcium-magnesium-bicarbonate composition (>70 percent HCO3 + CO3) and following the precipitation of calcite, the concentration of calcium was less than the carbonate alkalinity (2mCa+2 < mHCO3- + 2mCO3−2) carnotite saturation was not achieved. In systems open to CO2, carnotite saturation occurred in most samples in evaporation amounts ranging from 95 percent to 99 percent with the partial pressure of CO2 ranging from 10−3.5 to 10−2.5 atm. Carnotite saturation occurred in a few samples in evaporation amounts ranging from 98 percent to 99 percent with the partial pressure of CO2 equal to 10−2.0 atm. Carnotite saturation did not occur in any groundwater with the system closed to CO2. 相似文献
5.
美国法尔韦油田位于东得克萨斯盆地中心附近。油田发现于1960年,同年投入生产。原始地质储量为4亿桶,至2003年累计产油2.17亿桶。原油具挥发性,接近饱和。主要储层为下白垩统James组礁石灰岩,主要为骨架粒状灰岩/泥粒灰岩和富含双壳类粒泥状灰岩,各岩相的平均孔隙度一般在7%~11%,但平均渗透率在各岩相中不均,最高达(37~44)×10-3"m2。介绍了该油田的勘探史,描述了盆地构造演化史、含油气系统、地层沉积相和储层特征。 相似文献
6.
Livestock grazing is the most common use of rangelands, and overgrazing by domestic livestock has stirred much debate concerning the continued use of public rangelands for livestock production. With the increase of wildlife-related enterprises on south Texas rangelands, there are little data available on the compatibility of livestock and wildlife management and in particular the effects of livestock grazing on plant communities in the semi-arid portions of the western South Texas Plains. The objective of this study was to compare forb diversity and density on rangelands subjected to various grazing under a high-intensity, low-frequency grazing system and nongrazed rangelands under controlled conditions. Four rangeland sites that were moderately grazed during the dormant season and 4 rangeland sites receiving long-term deferment from grazing were selected on the Chaparral Wildlife Management Area, Dimmit and La Salle Counties, Texas. Forb density was estimated with 20×50 cm2 quadrats during early spring 2000 and 2001. Forb diversity was greatest on grazed sites. Important annuals such as hooker plantain (Plantago hookeriana) and Rough buttonweed (Diodia teres) were more prevalent on grazed sites. Lazy daisy (Aphanostephus spp.) was more frequently encountered on nongrazed sites. Golden dalea (Dalea aurea), a beneficial perennial, was more common on grazed sites. Long-term deferment from livestock grazing appears detrimental to forb communities. A high-intensity, low-frequency grazing system utilizing moderate stocking rates employed during the dormant season is recommended for enhancing forb diversity and abundance. 相似文献
7.
Simulation-optimization approach to assess groundwater availability in Refugio County, TX 总被引:10,自引:0,他引:10
Sustainable management of groundwater resources is critical for viable development of semi-arid regions. Refugio County, TX,
is predominantly a rural community that is in close proximity to two large urban areas of Corpus Christi and San Antonio.
Large-scale water supply projects are being planned to export surplus water available in Refugio County to nearby growing
cities. Being a coastal county with several sensitive bays and estuaries, these projects have caused concerns with regard
to decreases in freshwater inflows to coastal bodies and raised the possibility of saltwater intrusion. A simulation model
characterizing groundwater flow in the shallower unconfined and the deeper semi-confined formations of the Gulf coast aquifer
was calibrated and evaluated. The model results were used in conjunction with a mathematical programming scheme to estimate
maximum available groundwater in the county. Stakeholder concerns were incorporated as constraints, which included prevention
of saltwater intrusion in the aquifer, limiting the amount of allowable drawdown in shallow aquifers, as well as maintaining
current flow gradients especially near baseflow-dependent streams and rivers. For the conditions assumed in this study, the
model results indicate that roughly 4.93 × 107 m3 of water can be extracted in a typical year. The management model was noted to be very sensitive to the imposed saltwater
intrusion constraint. 相似文献
8.
Cardiovascular disease (CVD) is the number one cause of death in the state of Texas. In order to develop effective healthcare policies to combat CVD, it is essential to understand what types of communities are most affected. In this paper, we develop a classification scheme to segment high-prevalence communities based on selected social and demographic characteristics. We find that while many high-prevalence areas reflect traditional relationships between socioeconomic deprivation and poor health outcomes, a subset of more affluent communities in Texas are also affected. This suggests the importance of tailored approaches to prevention that account for this diversity among high-prevalence neighborhoods. 相似文献
9.
Models of natural and human dynamics in forest landscapes: Cross-site and cross-cultural synthesis 总被引:1,自引:0,他引:1
Miguel F. Acevedo J. Baird Callicott Donald Lyons Judith Rosales Magdiel Ablan Giorgio Tonella Emilio Vilanova 《Geoforum》2008,39(2):846-866
We synthesize the study of coupled natural and human systems across sites and cultures through a process of simplification and abstraction based on multiple dimensions of human-nature connectedness: satisfaction of basic needs, psycho-cultural connectedness and regulation of use of natural resources. We thus provide both a place-based and general understanding of value-driven anthropogenic environmental change and response. Two questions guide this research: what are the crucial stakeholder values that drive land use decisions and thus land cover change? And how can knowledge of these values be used to make decisions and policies that sustain both the human and natural systems in a place? To explore these questions we build simulation models of four study sites, two in the State of Texas, United States, and two in Venezuela. All include protected areas, though they differ in the specifics of vegetation and land use. In the Texas sites, relatively affluent individuals are legally converting forests to residential, commercial, and industrial uses, while in Venezuela landless settlers are extra-legally converting forests for purposes of subsistence agriculture. Contemporary modeling techniques now facilitate simulations of stakeholder and ecosystem dynamics revealing emergent patterns. Such coupled human and natural systems are currently recognized as a form of biocomplexity. Our modeling framework is flexible enough to allow adaptation to each of the study sites, capturing the essential features of the respective natural and anthropogenic land use changes and stakeholder reactions. The interactions between human stakeholders are simulated using multi-agent models that act on forest landscape models, and receive feedback of the effects of these actions on ecological habitats and hydrological response. The multi-agent models employ a formal logic-based method for the Venezuelan sites and a decision analysis approach using multi-attribute utility functions for the Texas sites, differing more in style and emphasis than in substance. Our natural-systems models are generic and can be tailored according to site-specific conditions. Similar models of tree growth and patch transitions are used for all the study sites and the differing responses to environmental variables are specified for each local species and terrain conditions. 相似文献
10.
Studies on turbulent diffusion processes and evaluation of diffusivity values from hydrodynamic observations in Corpus Christi Bay 总被引:1,自引:0,他引:1
The physical process of dispersion which can be attributed to turbulence (turbulent diffusion) or shear (shear-augmented diffusion) within the flow field is very important as it ultimately governs the distribution of constituents of interest within the environment. A series of diffusion experiments were conducted in Corpus Christi Bay, TX with the purpose of characterizing turbulent diffusion through dispersion coefficients or turbulent diffusivity, Ki (i=x, y, z) dependent on the degree of randomness or turbulence intensity, I.Measured with a boat-mounted acoustic doppler current profiler (ADCP), the Eulerian velocity time-series of fluid particles in random motion, ui was used in the evaluation of the Eulerian time-scale of turbulence, TE based on the velocity correlation function, RE with TE being related to the Lagrangian time-scale TL through a scaling parameter, β(=TL/TE). Surface currents were obtained with high frequency (HF) Radar equipment deployed over the study area from which the horizontal velocity gradients were determined.Within the spatial scale of the experiment (1000 m), the observed low horizontal gradients (10−4 s−1) allowed for the generation of velocity time-series from an ADCP mounted on a moving platform. A numerical scheme for evaluating turbulent diffusivity values was developed on the basis of Eulerian current measurements and calibrated through the statistics of an evolving dye patch for the scaling parameter β which in this scheme was found to be in the range 1–3. 相似文献