澧县曾家河芒硝岩盐矿床开发浅析

本文在分析矿床内外部建设条件的基础上,根据芒硝岩盐原料市场行情,着重对矿床开发的经济社会效益进行了评价,初步评价表明:国家和企业均可获得较丰厚的利润,还可安置1400多人就业。建议进一步开展地质勘查工作。     

淮安芒硝资源开发现状与发展对策

淮安芒硝资料的开发利用已使基我国东部新崛起的开采与加工基地，但问题也随之逐渐显现出来，主要是缺乏通盘规划、盲目扩大生产规模、污染环境以及勘查和基础设施跟不上等。就以上问题，作者对淮安芒硝开发提出了相应的对策与建议。     

柴达木盆地大浪滩地区表层芒硝的形成时代及环境意义

通过对柴达木盆地大浪滩地区的两次实地勘查,发现小梁山多处可见芒硝—碳酸盐粘土互层的露头,选取了完整沉积的D26剖面进行研究。比较盐湖学的研究表明,芒硝是典型的冷相盐类矿物;而碳酸盐粘土和石膏则反映了相对温暖潮湿和温暖的环境。本文通过对芒硝—碳酸盐粘土互层的矿物鉴定,石膏的铀系不平衡法定年,以及结合碳酸盐粘土的碳氧同位素分析,首次揭示出大浪滩地区在倒数第二次冰期（MIS 6阶段）前后经历了偏暖潮湿期（＞195.1 ka BP）→寒冷干旱期（195.1 ~ 169.9 ka BP）→偏暖湿期（169.9 ka BP ka BP）→冷暖交替时期（169.9 ka BP ~ 118 ka BP）→偏暖湿期（118 ka BP）的气候演变序列。经与黄土剖面,深海氧同位素和区域研究资料的对比表明,自中晚更新世以来,大浪滩地区不仅受到区域地质活动的影响,也与全球的气候变化同步响应。     

The thermal expansion and crystal structure of mirabilite (Na<Subscript>2</Subscript>SO<Subscript>4</Subscript>·10D<Subscript>2</Subscript>O) from 4.2 to 300 K,determined by time-of-flight neutron powder diffraction

We have collected high resolution neutron powder diffraction patterns from Na₂SO₄·10D₂O over the temperature range 4.2–300 K following rapid quenching in liquid nitrogen, and over a series of slow warming and cooling cycles. The crystal is monoclinic, space-group P2₁/c (Z = 4) with a = 11.44214(4) Å, b = 10.34276(4) Å, c = 12.75486(6) Å, β = 107.847(1)°, and V = 1436.794(8) Å³ at 4.2 K (slowly cooled), and a = 11.51472(6) Å, b = 10.36495(6) Å, c = 12.84651(7) Å, β = 107.7543(1)°, V = 1460.20(1) Å³ at 300 K. Structures were refined to R _P (Rietveld powder residual, \( R_{P} = {{\sum {\left| {I_{\text{obs}} - I_{\text{calc}} } \right|} } \mathord{\left/ {\vphantom {{\sum {\left| {I_{\text{obs}} - I_{\text{calc}} } \right|} } {\sum {I_{\text{obs}} } }}} \right. \kern-\nulldelimiterspace} {\sum {I_{\text{obs}} } }} \)) better than 2.5% at 4.2 K (quenched and slow cooled), 150 and 300 K. The sulfate disorder observed previously by Levy and Lisensky (Acta Cryst B34:3502–3510, 1978) was not present in our specimen, but we did observe changes with temperature in deuteron occupancies of the orientationally disordered water molecules coordinated to Na. The temperature dependence of the unit-cell volume from 4.2 to 300 K is well represented by a simple polynomial of the form V = ? 4.143(1) × 10^?7 T ³ + 0.00047(2) T² ? 0.027(2) T + 1437.0(1) Å³ (R ² = 99.98%). The coefficient of volume thermal expansion, α _V , is positive above 40 K, and displays a similar magnitude and temperature dependence to α _V in deuterated epsomite and meridianiite. The relationship between the magnitude and orientation of the principal axes of the thermal expansion tensor and the main structural elements are discussed; freezing in of deuteron disorder in the quenched specimen affects the thermal expansion, manifested most obviously as a change in the behaviour of the unit-cell parameter β.     

中国芒硝类矿产资源及硫酸钠产业状况

中国芒硝类矿产矿类齐全、资源丰富，硫酸钠资源居世界首位．硫酸钠产业起步于五十年代，八十年代得到迅速发展．至今，硫酸钠生产能力已跃居世界前列．改革开放和科技进步将为中国硫酸钠工矿业带来新的机遇．     

盐卤硼酸盐化学 ⅩⅩⅢ.小柴旦盐湖地表卤水常年性变化规律

通过对小柴旦盐湖地表卤水现场进行观测,取样分析和相图分析,研究了小柴旦湖水年变化规律,在不同季节,随着气温的变化,湖水呈现芒硝析出与回溶的变化规律。     

光卤石在芒硝溶液中溶解和转化动力学

本文研究了在恒速搅拌下，不同温度光卤石在芒硝溶液中溶解及转化机理，用溶解过程离子实验值拟合得到动力学方程，并求得了溶解反应的表观活化能，为生产硫酸钾提供了一定的基础。     

运城盐湖芒硝除钙镁方法研究与分析

就南风化工集团运城区域元明粉生产过程中遇到的水硝含钙镁高的问题,对各种除钙镁方法进行研究、分析和对比,最终得到一种经济实用的除钙镁方法。