西湖茶园茶叶铅污染铅同位素示踪

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。     

广西佛子冲铅锌矿田成岩成矿时代研究

广西佛子冲铅锌矿田位于桂东南博白-岑溪多金属成矿带的NE端,区内发育燕山期花岗岩、花岗闪长岩、二长花岗斑岩和英安质凝灰熔岩等;其中花岗闪长岩和二长花岗斑岩与铅锌成矿关系密切,成矿岩体形成时代分别为156Ma和127Ma。     

A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

3D numerical modelling of fluid flow in the Val-d’Or orogenic gold district: major crustal shear zones drain fluids from overpressured vein fields

Fluid flow patterns have been determined using oxygen isotope isopleths in the Val-d’Or orogenic gold district. 3D numerical modelling of fluid flow and oxygen isotope exchange in the vein field shows that the fluid flow patterns can be reproduced if the lower boundary of the model is permeable, which represents middle or lower crustal rocks that are infiltrated by a metamorphic fluid generated at deeper levels. This boundary condition implies that the major crustal faults so conspicuous in vein fields do not act as the only major channel for upward fluid flow. The upper model boundary is impermeable except along the trace of major crustal faults where fluids are allowed to drain out of the vein field. This upper impermeable boundary condition represents a low-permeability layer in the crust that separates the overpressured fluid from the overlying hydrostatic fluid pressure regime. We propose that the role of major crustal faults in overpressured vein fields, independent of tectonic setting, is to drain hydrothermal fluids out of the vein field along a breach across an impermeable layer higher in the crust and above the vein field. This breach is crucial to allow flow out of the vein field and accumulation of metals in the fractures, and this breach has major implications for exploration for mineral resources. We propose that tectonic events that cause episodic metamorphic dehydration create a short-lived pulse of metamorphic fluid to rise along zones of transient permeability. This results in a fluid wave that propagates upward carrying metals to the mineralized area. Earthquakes along crustal shear zones cause dilation near jogs that draw fluids and deposit metals in an interconnected network of subsidiary shear zones. Fluid flow is arrested by an impermeable barrier separating the hydrostatic and lithostatic fluid pressure regimes. Fluids flow through the evolving and interconnected network of shear zones and by advection through the rock matrix. Episodic breaches in the impermeable barrier along the crustal shear zones allow fluid flow out of the vein field.     

河南南召水洞岭铜铅锌矿床地质特征及成因分析

通过地质详查和综合研究相结合的手段 ,从水洞岭铜铅锌矿床的地质特征入手 ,分析矿床成因 ,提出矿床属海相火山喷发沉积 -弱改造型的成因观点     

Distribution and Elimination of Lead Species in Soils Related to GAP of Chinese Medicinal Materials of Ligusticum Chuanxiong Hort

In this paper, the sequential extraction procedure was used for the selection of fractions of lead in seven stages corresponding to lead exchangeable, lead bounded to carbonates, to manganese oxides, to organic matters, to amorphous iron, and lead associated to crystallized iron, and to residuals. The vertical distributions of lead species were carried out in the soils related to good agriculture progress (GAP) of Chinese medical materials of Ligusticum chuanxiong Hort in Dujiangyan city and Wenchuan County, Sichuan Province. Based on those researches, it is found that the plant of Glycine Max (L.) Merr. has the character of lead enrichment and sorption, which is not reported in the literature. Using Glycine Max (L.) Merr. alternate planting with Ligusticum chuanxiong Hort is a valuable recommended in order to produce a high quality Chinese medical materials in order to eliminate the barrier on the beyond the lead limit for the import and export of Ligusticum chuanxiong Hort.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Lead-arsenic soil geochemical study as an exploration guide over the Killik volcanogenic massive sulfide deposit, Northeastern Turkey

A mountainous terrain, the eastern Pontide tectonic belt, located in northeastern Turkey, contains more than 60 known volcanogenic massive sulfide (VMS) deposits that differ in reserves (0.1–30 million tonnes) and grades. Soil geochemistry is conventionally used in exploration programs to discover concealed VMS deposits in the region. In the present study, Pb and As element pair were used as pathfinder elements to investigate the relationship of their anomalies to a completely delineated ore deposit (Killik VMS deposit) in an orientation survey that served as a natural physical model. Two hundred forty soil samples were analyzed in the present study. The two elements, which represent the opposite ends of the mobility range, revealed high contrast and overlapped each other at the location of the ore deposit due to enhancement of the anomalies by hydromorphic dispersion, which is an indication that soil samples would produce reliable results. The successful delineation of the deposit is remarkable considering the rough topography and the climatic limitations. Previously the extremely moist and temperate climate was thought to cause excessive leaching of the trace element pathfinders from the ore deposits to produce extensive anomalies usually extending away from the mineralization thus, leading to erroneous results and/or extensive anomalous areas. But the present research has shown that the method can be used effectively if the sampling and data evaluation is carefully conducted.     

Arsenic and lead mobility: From tailing materials to the aqueous compartment

This study concerns the mineralogy of the tailings of a former Ag–Pb mine (Auzelles district, France) and the contribution of the waste materials to the heavy metal dissemination in the environment. Accumulation of metals in fish flesh was reported and this pollution is attributed to past mining activities. Tailings were studied to establish the major transfer schemes of As and Pb in order to understand their mobility that leads to contamination of a whole ecosystem. Mineralogical investigation, solubility and compliance tests were performed to assess the stability of the metal-bearing phases. Among the various metallic elements measured, As and Pb show the highest bulk concentrations (up to 0.7% and 6.3% respectively) especially for samples presenting near neutral pH values. According to X-ray diffraction (XRD), Scanning Electron Microscopy (SEM-EDX), Electron Probe Micro-Analysis (EPMA) and micro-Raman spectrometry (μRS), tailings mineralogy still contain primary minerals such as sulfides (e.g., galena, pyrite), phosphates (monazite, apatite) and/or carbonates (e.g., (hydro-)cerussite, dolomite, siderite). Sulfates (e.g., anglesite, lanarkite, plumbojarosite and beudantite) are the main secondary metal-bearing phases with other interesting phases accounting for metals mobility such as Fe and/or Pb and/or Mn oxides (e.g., lepidocrocite, goethite -up to 15 wt% of Pb was measured-, plumboferrite-type phase, mimetite). The lowest Pb solubilities were obtained at pH 8–9 and at a larger range than for As for which the lowest solubilities are reached around pH 6–7. At this minimum solubility pH value, Pb concentrations released still over exceed the National Environmental Quality Standards (NEQS), whatever the samples. The highest solubility is reached at pH 2 for both elements whatever the considered sample. This represents up to 51% of total Pb and up to 46% of total As remobilized and concentrations exceeding the NEQS. As and Pb released mainly depends on the Fe/Mn oxides (e.g., goethite, lepidocrocite) and carbonates (cerussite) which are the less stable phases. Compliance tests also show that Pb concentrations released are higher than the upper limit for hazardous waste landfills. Determination of the mineralogy allows understanding both the solubility and leaching test experiments results, as well as to forecast the impact of the residues on the water quality at a mid-term scale.     

华南两类不同成因花岗岩的铅同位素组成特征

本文论述了华南两类不同成因花岗岩的铅同位素组成特征。不同类型的花岗岩,具有明显不同的铅同位素组成。改造型花岗岩相对富放射成因铅,其铅同位素比值较高,Pb/~(204)Pb>72;且相对富铀铅而贫钍铅,~(208)Pb/~(206)Pb<2.1。同熔型花岗岩则反之。利用有关的铅同位素图解和参数,可对花岗岩的成因类型进行划分。岩石的铅同位素组成与其成岩物质来源的关系,可从铀(钍)铅同位素的演化得到解释。研究结果表明,花岗岩的铅同位素组成特征,能够提供有关成岩物质来源的信息,从而作为划分花岗岩成因类型的又一个稳定同位素标志。