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Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
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In desert environments with low water and salt contents, rapid thermal variations may be an important source of rock weathering. We have obtained temperature measurements of the surface of rocks in hyper-arid hot and cold desert environments at a rate of 1/s over several days. The values of temperature change over 1-second intervals were similar in hot and cold deserts despite a 30 °C difference in absolute rock surface temperature. The average percentage of the time dT/dt > 2 °C/min was ~ 8 ± 3%, > 4 °C/min was 1 ± 0.9%, and > 8 °C/min was 0.02 ± 0.03%. The maximum change over a 1-second interval was ~ 10 °C/min. When sampled to simulate data taken over intervals longer than 1 s, we found a reduction in time spent above the 2 °C/min temperature gradient threshold. For 1-minute samples, the time spent above any given threshold was about two orders of magnitude lower than the corresponding value for 1-second sampling. We suggest that a rough measure of efficacy of weathering as a function of frequency is the product of the percentage of time spent above a given threshold value multiplied by the damping depth for the corresponding frequency. This product has a broad maximum for periods between 3 and 10 s. 相似文献
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