Biomarker characterisation and hydrous pyrolysis of bitumens from Tertiary volcanics, queen Charlotte islands, British Columbia, Canada

A number of bitumen samples have been recovered from vugs and fractures in outcropping Tertiary basalts of the Queen Charlotte Islands off the west coast of British Columbia, Canada. n-Alkanes and acyclic isoprenoids are not present and the polycyclic biomarker distribution of the four samples analyzed by GC and GC-MS has been altered. One sample contains no remaining recognizable biomarkers. Two bitumens were also obtained from Lower Jurassic potential source rocks, including one from the Sandilands Formation, which was considered previously to be the most likely source of the Tertiary bitumens. Although these two bitumens were also taken from outcrops, they are considerably less biodegraded. The Sandilands Formation bitumen contains 28, 30-bisnorhopanes and since these compounds were not detected in the Tertiary bitumens, there is no evidence from the initial results for a Sandilands Formation contribution to the hydrocarbons in the Tertiary basalts. The presence of 18α(H)-oleanane in the saturate fraction of two of the Tertiary bitumens from widely separated locations indicates that they are at least partially sourced from Tertiary organic matter.Because the distribution of biomarkers in some samples has been severely affected by biodegradation, the asphaltenes of the bitumens were hydrously-pyrolysed and the saturate fractions of the resulting pyrolysates analysed for possible additional information on the origin of the bitumens. The pyrolysates from the more degraded samples contain compounds not detected in the saturate fractions of the original bitumen and show some of the expected characteristics of the original non-degraded bitumen. However, the compounds most useful for correlation are not present in the pyrolysates apparently due to their non-incorporation into the kerogen macromolecule. Our results suggest that hydrous-pyrolysis of asphaltenes is of limited use in the correlation of biodegraded samples and in determining their origins.     

Developing and Sequencing Community Engagement and Experiential Education: A Case Study of Urban Geography Teaching and Research

Community engagement curricula and course design can provide substantial experiences for both community members and participating students. Using a case study approach, this research focuses on four steps in this process: initial community relationship forming, engaging in community service, transitioning to civic engagement, and developing a community-based research program. Narrative examples from student course evaluations position these community-based experiences as transformative for multiple parties. Institutional structures are presented as helpful entrees to engagement for students, while noting that community relationships provide contextualized, powerful, and meaningful relationships, supporting recommendations for emerging and existing community engagement programs.     

Belonging in charlotte: multiscalar differences in local immigration politics and policies

In the context of Charlotte, North Carolina's, emergence as a “globalizing” pre‐emergent immigrant gateway, this paper focuses on a complex and multiscalar set of governmental policies and community‐development dynamics that are shaping localized response to Hispanic/Latino immigration. Specifically, we explore how these policies and dynamics play out spatially in the context of two Charlotte neighborhoods, both of which have similar historical roots and have become magnets for Latino settlement, yet display divergent contemporary place‐making paths. Our exploration reveals the ways in which contexts of receptivity and spaces of both exclusion and inclusion are created by the socio‐spatial components of public policy and the localized response to that policy at the intraurban level. Reinforcing the importance of space and place in the construction of receptivity contexts, the compared stories of Eastside and South Charlotte reveal that neighborhoods are never the product of one transformational force but of many—no matter how they may be perceived in the public imaginary.     

Molluscan biostratigraphy and paleomagnetism of Campanian strata, Queen Charlotte Islands, British Columbia: implications for Pacific coast North America biochronology

A previously uncollected fauna of ammonites, bivalves, and other molluscs, associated with radiolarian microfossils, has been newly recognized near Lawn Hill on the east coast of central Queen Charlotte Islands, British Columbia. The regional biostratigraphic zonation indicates that the Lawn Hill fauna is correlative with the Nostoceras hornbyense zonule of the Pachydiscus suciaensis ammonite biozone, recognized in the Nanaimo Group of southeast Vancouver Island. The Nostoceras hornbyense Zone (new) is herein proposed for strata of Pacific coast Canada containing the zonal index. Several molluscan taxa present in the Lawn Hill section are new to British Columbia and the ammonite fauna suggests that the Nostoceras hornbyense Zone is late Campanian in age, supported by radiolarian taxa present in the section. Strata sampled in the Lawn Hill section preserve reversed-polarity magnetization, considered likely correlative with Chron 32r. The presence of the Nostoceras hornbyense Zone on Queen Charlotte Islands is the first recognition of this zone in Canada north of central Vancouver Island and represents the youngest Cretaceous known in this region. Campanian radiolarians identified from the Lawn Hill section are also the first recognized from the Pacific coast of Canada.     

Nutrient availability in support of Karenia brevis blooms on the central West Florida Shelf: What keeps Karenia blooming?

Identifying nutrient sources, primarily nitrogen (N) and phosphorus (P), sufficient to support high biomass blooms of the red tide dinoflagellate, Karenia brevis, has remained problematic. The West Florida Shelf is oligotrophic, yet populations >10⁶ cells L⁻¹ frequently occur and blooms can persist for months. Here we examine the magnitude and variety of sources for N and P that are available to support blooms. Annual average in situ or background concentrations of inorganic N in the region where blooms occur range 0.02–0.2 μM while inorganic P ranges 0.025–0.24 μM. Such concentrations would be sufficient to support the growth of populations up to ∼3×10⁴ cells L⁻¹ with at least a 1 d turnover rate. Organic N concentrations average 1–2 orders of magnitude greater than inorganic N, 8–14 μM while organic P concentrations average 0.2–0.5 μM. Concentrations of organic N are sufficient to support blooms >10⁵ cells L⁻¹ but the extent to which this complex mixture of N species is utilizable is unknown. Other sources of nutrients included in our analysis are aerial deposition, estuarine flux, benthic flux, zooplankton excretion, N₂-fixation, and subsequent release of organic and inorganic N by Trichodesmium spp., and release of N and P from dead and decaying fish killed by the blooms. Inputs based on atmospheric deposition, benthic flux, and N₂-fixation, were minor contributors to the flux required to support growth of populations >2.6×10⁴ cells L⁻¹. N and P from decaying fish could theoretically maintain populations at moderate concentrations but insufficient data on the flux and subsequent mixing rates does not allow us to calculate average values. Zooplankton excretion rates, based on measured zooplankton population estimates and excretion rates could also supply all of the N and P required to support populations of 10⁵ and 10⁶ cells L⁻¹, respectively, but excretion is considered as “regenerated” nutrient input and can only maintain biomass rather than contribute to “new” biomass. The combined estuarine flux from Tampa Bay, Charlotte Harbor, and the Caloosahatchee River can supply a varying, but at times significant level of N and P to meet growth and photosynthesis requirements for populations of approximately 10⁵ cells L⁻¹ or below. Estimates of remineralization of dead fish could supply a significant proportion of bloom maintenance requirements but the rate of supply must still be determined. Overall, a combination of sources is required to maintain populations >10⁶ cells L⁻¹.     

Mutual relationships in neighborhood socioeconomic change

In this article, we investigate the factors that lead to changes in the socioeconomic complexion of urban neighborhoods along four critical dimensions: crime, youth social distress, home ownership, and economic conditions. We argue that the dynamics of these dimensions are better apprehended simultaneously considering their potential mutual relationships and we propose a cross-lagged panel model approach within a structural equation modeling framework. Neighborhoods in Charlotte, North Carolina, are used as a case study, and change is modeled at several time lags throughout the 2000–2010 decade. Findings indicate that the model performs well and that it offers a very promising avenue for modeling the socioeconomic changes of neighborhoods that accounts for complex longitudinal effects as well as spatial dependencies. Specifically, it shows that lower human capital manifested by a decline in youth indicators is significant in explaining subsequent increases in crime and declines in economic indicators. Also, the predominance of housing stock constructed in the 1950s and 1960s is a significant trigger of declines across all neighborhood indicators. Finally, spatial spillover effects between neighborhoods are found to be short-lived and dissipate after a few years.     

An Examination of the Challenges of Charlotte Manufacturers

Manufacturing employment has steadily declined in the Charlotte metropolitan area, with significant losses occurring in textiles, apparel, and related industries. Production activity remains widespread in the region, however, both in terms of the number of manufacturers and workers and the wide range of industries in which they are involved. Evidence from a survey of manufacturers within the Charlotte region indicates that a number of firms continue to succeed despite various competitive issues on the local and national scales. This article examines these challenges, their implications, and the strategies used to address these issues. Overall, manufacturers across the region are in a period of rapid change.     

Statistical Tests In The Absence Of Samples: A Comment

Abstract

Manufacturing employment has steadily declined in the Charlotte metropolitan area, with significant losses occurring in textiles, apparel, and related industries. Production activity remains widespread in the region, however, both in terms of the number of manufacturers and workers and the wide range of industries in which they are involved. Evidence from a survey of manufacturers within the Charlotte region indicates that a number of firms continue to succeed despite various competitive issues on the local and national scales. This article examines these challenges, their implications, and the strategies used to address these issues. Overall, manufacturers across the region are in a period of rapid change.     

Modeling water quality and hypoxia dynamics in Upper Charlotte Harbor,Florida, U.S.A. during 2000

Hypoxia has occurred in Upper Charlotte Harbor, a shallow (∼3 m) estuary in Southwest Florida, during moderate to high freshwater flows from the Peace and Myakka Rivers and after hurricanes, due to nutrient loading and vertical stratification. This paper studies the annual hypoxia and water quality dynamics in Upper Charlotte Harbor in 2000, using CH3D-IMS, an integrated modeling system which includes coupled models of circulation, wave, sediment transport, and water quality. The CH3D-IMS simulations showed that bottom-water hypoxic conditions occur during periods with relatively steady moderate to high (5–40 m³/s) freshwater inflows and sediment oxygen demand (SOD). During periods of relatively steady moderate to high river discharge, strong vertical salinity stratification results in reduced vertical mixing which prevents surface water from supplying dissolved oxygen (DO) to bottom water where SOD continuously consumes DO. There was significant temporal fluctuation of the hypoxic water volume, as a result of significant temporal variation in vertical turbulent mixing associated with combinations of spring-neap tides and river discharge. The validated modeling system could be used to forecast hypoxia.