Groundwater mixing between different aquifer types in a complex structural setting discerned by elemental and stable isotope geochemistry

Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ¹³C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ¹³C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ¹⁸O and δD ratios during the fall [δ¹⁸O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ¹⁸O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd.     

Permeability of coals and characteristics of desorption tests: Implications for coalbed methane production

Desorption tests, conducted before development drilling, can predict early production rates of coalbed methane wells. In this study, results from 136 desorption tests from 30 coreholes are compared to subsequent production histories of surrounding wells. Coals studied are from the Carboniferous Pottsville Formation in the Black Warrior Basin of Alabama, USA. The investigation indicates that the best predictor for gas production is ‘‘gas yield at 120 days, divided by sample depth'. This quotient has a higher correlation with actual gas production than other variables examined, including original reserves in-place. Gas content of coal generally increases with depth. However, coal permeability, and hence the recovery factor, tends to decrease with depth. Therefore, coalbed methane exploration should focus on finding the optimal balance between gas yield and depth. Commercially successful wells are characterized by coals with high gas yields at shallow depths. Desorption tests, especially of slowly-desorbing coals, should be run for a minimum of 120 days, or else should be extrapolated to that time if tests are terminated earlier.     

BOOK REVIEWS

Books reviewed in this article: The Mexican Colonial Copper Industry. Elinore M. Barrett . The Control Revolution: Technological and Economic Origins of the Information Society . James R. Beniger . Land Degradation and Society . Piers M. Blaikie And Harold C. Brookfield , Eds . La carte, mode d'emploi. Roger Brunet . France: les dynamiques du territoire . Roger Brunet AND Jacques Sallois , EDS. At the Crossroads—The Mineral Problems of the United States . Eugene N. Cameron . A Census of One Billion People , Papers for International Seminar on China's 1982 Population Census. Li Chengrui , ED. Les Milieux “Naturels” du Globe . Jean Demangeot . The Geophysiology of Amazonia: Vegetation and Climate Interactions : Robert E. Dickinson , ED. Tenn-Tom Country . James F. Doster And David C. Weaver . Family Farming in Europe and America . Boguslaw Galeski And Eugene Wilkening , EDS. The Geography of Urban Transportation . Susan Hanson , Ed. Combating Desertification in Developing Countries . J. K. Jain , ED. Cartography in France—1660–1848. Science, Engineering and Statecraft . Josef W. Konvitz . Distribution of Distances in Pregeographical Space . Hans Kuiper . Physical Geography Lab Manual: A New Experimental Approach . Neal G. Lineback And John M. Harlin . Physical Geography: A Landscape Appreciation , 2nd ed. Tom L. Mc Knight . The Desert Is No Lady: Southwestern Landscapes in Women's Writing and Art . Vera Norwood And Janice Monk , EDS. France: A Geographical, Social, and Economic Survey . Philippe Pinchemel , translated, by D. Elkins and T. H. Elkins. Gene Banks and the World's Food . Donald L. Plucknett , Nigel J. H. Smith , J. T. Williams , And N. Murthi Anishetty . Latin American Development: Geographical Perspectives . David Preston , Ed. Making Sense of Development: An Introduction to Classical and Contemporary Theories of Development and Their Application to Southeast Asia . P. W. Preston . The History of the Countryside. Oliver Rackham . The Third World in Perspective . H. A. Reitsma AND J. M. G. Kleinpenning . The Industrial Geography of Australia . David C. Rich . The Recruiting Game , 2nd Ed., revised. John F. Rooney , JR. A Cultural Geography of North American Indians . Thomas E. Ross AND Tyrel G. Moore , EDS. Eastern Europe . Dean S. Rugg . Human Territoriality: Its Theory and History . Cambridge Studies in Historical Geography: 7. Robert David Sack . Experimental Fluvial Geomorphology . Stanley A. Schumm , M. Paul Mosley , AND William E. Weaver . The New Urban Landscape . David Schuyler . Atlas of American Women . Barbara Gimla Shortridge . Impacts of Hazardous Technology: The Psycho-Social Effects of Restarting TMI-1 . John Sorensen , Jon Soderstrom , Emily Copenhaver , Sam Carnes AND Robert Bolin . Modern Physical Geography , 3rd Ed., (Third Edition). Arthur N. Strahler AND Alan H. Strahler . India: Economic Resource Base and Contemporary Political Patterns . B. L. Sukhwal .     

Journey‐to‐Work Patterns in the Age of Sprawl: Evidence from Two Midsize Southern Metropolitan Areas*

Among others, one commonly identified negative consequence of urban sprawl is an increase in the length of the journey to work. However, there has been more discussion of this than serious scrutiny, hence the relationship between urban sprawl and commuting patterns, especially at the intraurban level, remains unclear. Using the 2000 Census Transportation Planning Package (CTPP) data for two Southeastern metropolitan areas, this research investigates the extent to which workers living in sprawl areas commute farther to work than those living in higher density areas. The analysis of variance confirms that workers commuting from sprawl areas to urban areas experience a longer commute in terms of time as well as mileage, though this varies when workplace and home locations are taken into account. However, multivariate statistical results suggest that there are limits to the utility of sprawl as a predictor of travel behavior compared to workers' socioeconomic characteristics, as other factors appear to be equally or more important.     

A modeling study of seawater intrusion in Alabama Gulf Coast,USA

A numerical model of variable-density groundwater flow and miscible salt transport is developed to investigate the extent of seawater intrusion in the Gulf coast aquifers of Alabama, USA. The SEAWAT code is used to solve the density-dependent groundwater flow and solute transport governing equations. The numerical model is calibrated against the observed hydraulic heads measured in 1996 by adjusting the zonation and values of hydraulic conductivity and recharge rate. Using the calibrated model and assuming all the hydrogeologic conditions remain the same as those in 1996, a predictive 40-year simulation run indicates that further seawater intrusion into the coastal aquifers can occur in the study area. Moreover, the predicted intrusion may be more significant in the deeper aquifer than the shallower ones. As the population continues to grow and the demand for groundwater pumping intensifies beyond the 1996 level, it can be expected that the actual extent of seawater intrusion in the future would be more severe than the model prediction. Better strategies for groundwater development and management will be necessary to protect the freshwater aquifers from contamination by seawater intrusion.

Water quality modeling of the Cahaba River,Alabama

The Cahaba River, a sixth-order stream, tributary to the Mobile-Alabama River, is one of the few free-flowing rivers in Alabama. The Cahaba River lies in north-central Alabama and its watershed includes a variety of land uses from forested and agricultural to urban. Water quantity and quality modeling of the Cahaba River using several modules of the hydrologic simulation program FORTRAN (HSPF) and the nonpoint source model (NPSM) using the GIS-based BASINS package showed good agreement with measured flow data for low- and high-flow years but poor agreement with total nitrogen concentrations in the water column. Disparities between modeling and measured water quality data are attributed to the limited point source data available for nitrogen inputs to the stream and the lack of nitrogen-transformation process modeling with the NPSM. Future simulations should include use of models with detailed nitrogen transformation modules.     

Partisan Shifts in Presidential and Gubernatorial Elections in Alabama, 1932–1994*

Although the Republican Party has been competitive in presidential elections in the South for nearly three decades, it has only recently become a force in southern state and local elections. In Alabama, the GOP has dominated presidential voting since 1964, but has only become competitive during the past decade in gubernatorial elections. Why did the GOP first experience success in Alabama in presidential elections 30 years ago, but only recently become competitive in gubernatorial elections? This paper addresses this question using a county-level analysis of both presidential and gubernatorial election returns. It concludes that George Wallace's long political career is the dominant reason for the lag in GOP success in gubernatorial elections.     

Correcting the errors from variable sea salt retention and water of hydration in loss on ignition analysis: Implications for studies of estuarine and coastal waters

The standard technique of determining the concentrations of total suspended solids (TSSs), particulate inorganic matter (PIM), and particulate organic matter (POM) by filtration with glass fiber filters is subject to an error or bias from sea salt plus water of hydration retention, when applied to saline waters. The sea salt plus water of hydration retention by the filters occurs even after washing the filter with 300 ml of deionized water, a greater volume than any wash recommended in the literature. We determined that the mass retention on a glass fiber filter, at a given salinity, is essentially constant, no matter the volume of seawater passed through the filter. We also determined that the sea salt plus water of hydration retention on glass fiber filters is directly proportional to the salinity of the seawater filtered. Sea salt plus water of hydration retention causes an overestimate of TSS; sea salt retention causes an overestimate of PIM; volatilization of water of hydration causes an overestimate of POM. Thus a correction curve is required for sea salt and water of hydration errors in the determination of TSS and PIM. Corrected POM comes from the difference between the two. Also, filter blanks (procedural control filters), run with deionized (DI) water rather than the seawater sample, are required to correct for possible filter mass loss during the analysis. We demonstrate correction curves for sea salt plus water of hydration retention for Whatman GF/F filters, 47 mm diameter, utilizing the methods of the APHA Manual, Standard Methods for the Examination of Water and Wastewater. Application of other glass fiber filter types or an analytical technique differing significantly from that employed here requires a different correction curve for retention of sea salt and water of hydration. These methods can be used to reanalyze older data on PIM, POM, and TSS.We apply these corrections to PIM and POM data from the northern Gulf of Mexico and examine the interactions of these filter corrections with corrections for structural water volatilization from suspended clay minerals in the determinations of PIM and POM. We analyze published data on PIM and POM determinations and their application to remote sensing. We conclude that sea salt and water of hydration retention on filters has an adverse effect on remote-sensing algorithms inverting radiance reflectance to estimate concentrations of suspended matter.     

Geospatial method for computing supplemental multi-decadal US coastal land use and land cover classification products,using Landsat data and C-CAP products

This paper discusses the development and implementation of a method that can be used with multi-decadal Landsat data for computing general coastal US land use and land cover (LULC) maps consisting of seven classes. With Mobile Bay, Alabama as the study region, the method that was applied to derive LULC products for nine dates across a 34-year time span. Classifications were computed and refined using decision rules in conjunction with unsupervised classification of Landsat data and Coastal Change and Analysis Program value-added products. Each classification’s overall accuracy was assessed by comparing stratified random locations to available high spatial resolution satellite and aerial imagery, field survey data and raw Landsat RGBs. Overall classification accuracies ranged from 83 to 91% with overall κ statistics ranging from 0.78 to 0.89. Accurate classifications were computed for all nine dates, yielding effective results regardless of season and Landsat sensor. This classification method provided useful map inputs for computing LULC change products.     

Hydrographic variability on a coastal shelf directly influenced by estuarine outflow

Hydrographic variability on the Alabama shelf just outside of Mobile Bay, a major source of river discharge into the Gulf of Mexico, is examined using time series of water column temperature and surface and bottom salinity from a mooring site with a depth of 20 m in conjunction with a series of across-shelf CTD surveys. The time series data show variability in a range of time scales. The density variation is affected by both salinity and temperature, with its relatively strong annual signal mostly determined by temperature and its year to year variability mostly determined by salinity. Seasonal mean structures of temperature, salinity, and density show a transition from estuarine to shelf conditions in which three regions with distinct seasonal characteristics in their horizontal and vertical gradient structures are identified. Correlation analysis with the available forcing functions demonstrates the influence of Mobile Bay on the variability at the mooring site. At low frequencies, river discharge from Mobile Bay has a varying influence on salinity, which is absent during the periods with unusually low discharge. At shorter synoptic time scales, both the estuarine response to the across-shelf wind stress and the shelf response to the along-shelf wind stress are significantly correlated with temperature/salinity variability: the former becoming important for the surface layer during winter whereas the latter for the bottom layer during both winter and summer. These forcing functions are important players in determining the estuarine-shelf exchange, which in turn is found to contribute to the shelf hydrographic structure.