夏季东海西部表层海水中的pCO2及海-气界面通量

根据2001年夏季长江口及东海西部海域表层海水pCO     

南黄海夏季海水pCO2研究Ⅱ--下层海水涌升和长江冲淡水对海-气界面CO2通量的贡献

根据2001年7月对南黄海的大面积调查,研究了南黄海夏季pCO2的分布机制,着重讨论下层海水涌升和长江冲淡水对海-气界面CO2通量的贡献,并给出了南黄海海-气界面CO2通量。研究结果表明:夏季南黄海总体上是CO2的1个弱源,大约向大气中释放45.05×104t C。夏季南黄海表层海水pCO2分布表现出了极大的不均性,其汇区主要由长江冲淡水造成,影响区域占汇区吸收CO2的99.9%;而在源区,下层海水涌升虽然面积较小却占源区释放CO2的35.2%。可见陆架边缘海区源/汇格局的地域差异非常之特别。     

黄河河流水体二氧化碳分压及其影响因素分析

根据2003年秋季黄河河流水体二氧化碳分压(p(CO2))的实测数据，结合水文、化学和生物等要素的同步观测资料，对河流水体p(CO2)的影响因素进行了探讨。研究结果表明：生物好氧呼吸作用不是影响河流水体p(CO2)的主要因素，黄河河流p(CO2)的高低主要受水体碳酸盐系统的控制。     

2008年夏季加拿大海盆净二氧化碳吸收量评估

The third Chinese National Arctic Research Expedition(CHINARE) was conducted in the summer of 2008.During the survey,the surface seawater partial pressure of CO_2(pCO_2) was measured,and sea water samples were collected for CO_2 measurement in the Canada Basin.The distribution of pCO_2 in the Canada Basin was determined,the influencing factors were addressed,and the air-sea CO_2 flux in the Canada Basin was evaluated.The Canada Basin was divided into three regions:the ice-free zone(south of 77°N),the partially ice-covered zone(77°–80°N),and the heavily ice-covered zone(north of 80°N).In the ice-free zone,pCO_2 was high(320 to 368μatm,1 μatm=0.101 325 Pa),primarily due to rapid equilibration with atmospheric CO_2 over a short time.In the partially ice-covered zone,the surface pCO_2 was relatively low(250 to 270 μatm) due to ice-edge blooms and icemelt water dilution.In the heavily ice-covered zone,the seawater pCO_2 varied between 270 and 300 μatm due to biological CO_2 removal,the transportation of low pCO_2 water northward,and heavy ice cover.The surface seawater pCO_2 during the survey was undersaturated with respect to the atmosphere in the Canada Basin,and it was a net sink for atmospheric CO_2.The summertime net CO_2 uptake of the ice-free zone,the partially ice-covered zone and the heavily ice-covered zone was(4.14±1.08),(1.79±0.19),and(0.57±0.03) Tg/a(calculated by carbon,1Tg=10~(12) g),respectively.Overall,the net CO_2 sink of the Canada Basin in the summer of 2008 was(6.5±1.3) Tg/a,which accounted for 4%–10% of the Arctic Ocean CO_2 sink.     

Geochemical signatures of Mesoproterozoic siliciclastic rocks of the Kaimur Group of the Vindhyan Supergroup,Central India

The Upper Kaimur Group of the Vindhyan Supergroup in Central India, primarily consists of three rock types-DhandraulSandstone, Scarp Sandstone and Bijaigarh Shale. Mineralogically and geochemically, they are quartz arenite, sublitharenite to litharenite and litharenite to shale in composition, respectively. The A-CN-K ternary plot and CIA and ICV values suggest that the similar source rocks suffered severe chemical weathering, under a hot-humid climate in an acidic environment with higher P _{CO 2}, which facilitated high sediment influx in the absence of land plants. Various geochemical discriminants, elemental ratios like K₂O/Na₂O, Al₂O₃/TiO₂, SiO₂/MgO, La/Sc, Th/Sc, Th/Cr, Gd_N/Yb_N and pronounced negative Eu anomalies indicate the rocks to be of post-Archean Proterozoic granitic source, with a minor contribution of granodioritic input, in a passive margin setting. The sediments of the Upper Kaimur Group were probably deposited in the interglacial period in between the Paleoproterozoic and Neoproterozoic glacial epochs.     

低氧低分压环境下泡塑吸附-石墨炉原子吸收光谱法测定化探样品中的痕量金

针对西藏低氧低分压环境下痕量金的测定,探讨了溶矿介质、解脱时间、吸附温度、Fe3+加入量等对测定结果的影响。确定了最佳测定条件,并较详细讨论了Fe3+在溶矿和吸附过程中的重要作用。方法检出限为0.102 ng/g,测定范围为0.24~300 ng/g,准确度(ΔlgC,n=12)为0.01~0.03,精密度(RSD,n=12)为1.61%~7.33%,很好地解决了西藏地区低氧低分压低温环境下痕量金测定的技术难题。     

Distributions and air-sea fluxes of CO2 in the summer Bering Sea

The 3rd Chinese National Arctic Research Expedition(CHINARE–Arctic III) was carried out from July to September in 2008. The partial pressure of CO2(pCO2) in the atmosphere and in surface seawater were determined in the Bering Sea during July 11–27, 2008, and a large number of seawater samples were taken for total alkalinity(TA) and total dissolved inorganic carbon(DIC) analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 μatm(1 μatm = 1.013 25×10-1 Pa). The lowest pCO2 values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at-9.4,-16.3, and-5.1 mmol/(m2·d), respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.     

基于ST-ConvLSTM的南海海表面CO2分压的空间和时间序列预测

海表面二氧化碳分压(pCO₂)的未来变化趋势,对统计评估全球碳收支以及理解全球气候变化背景下的海洋酸化现象至关重要。目前传统的海面pCO₂预测方法大部分基于有限的实测数据,然而实测数据存在着时间和地理方面的制约,且计算成本较高。近年来,随着时空观测数据的爆炸性增长,基于深度学习的数据驱动模型在海表面pCO₂预测方面中表现出良好的潜力。然而,由于多种环境因素与海表面pCO₂之间的关系错综复杂,到目前为止尚无十分简单有效的相关模型来对海表面pCO₂进行预测。为应对这一挑战,利用时空卷积长短时记忆神经网络(ST-ConvLSTM)模型,通过海面温度(sea surface temperature, SST)、海面盐度(sea surface salinity, SSS)、叶绿素a浓度(chl a)和海面pCO₂数据,预测南海的海面pCO₂,并将2019年1～12月的数据作为测试集对模型的表现进行了验证。结果显示, ST-ConvLSTM模型...     

黄河口总碱度保守与非保守行为探讨

为了阐明黄河口TAlk（总碱度）的行为特征及主要影响因素,根据2004年4月黄河口TAlk实测数据,结合其它化学要素的同步观测资料对其进行了初步探讨.研究结果表明： 黄河口水体在S〈24的区域范围内TAlk呈现出非保守行为,其中 S〈5时TAlk非保守表现为净TAlk的“亏损”, 即水体TAlk低于理论混合TAlk,是由于水体中DIC的沉淀作用引起;在盐度为8～24之间,TAlk非保守表现为净TAlk的“增加”,即水体TAlk高于理论混合TAlk,主要是由于水体中颗粒碳酸盐溶解引起;水体中的CO2参与了颗粒碳酸盐的溶解,并且很可能是影响水体中碳酸盐溶解的主要因素.