Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

隧道工程地质评价的内容和方法

结合工程隧道实际,首先阐述了隧道工程的基本地质环境和工程地质条件,然后针对隧道工程可能出现的不良地质现象和可采取的工程措施,从大气降水、围岩稳定、围岩压力、洞口稳定、隧道比选等角度探讨隧道工程地质评价的主要方法和一般内容,进行隧道工程地质评价,为隧道施工、支护提供了依据.     

济宁市嘉祥县石灰岩矿山地质环境评价与治理

在对嘉祥县石灰岩矿进行地质灾害危险性评估、矿山环境地质问题评价的基础上,建立了一套评价体系,其中地质灾害危险性评估分为2个评价指标,矿山环境地质问题评价分为2种要素3个指标,同时将矿山恢复治理难易程度也作为一个评价因子。评价过程中对各指标危害性大、中、小程度均单独赋值,然后将各指标的分值进行叠加,确定出矿山环境地质问题的等级,将概划出的13个评价单元分为极差、差、一般3个区。提出了强化矿山管理、植树造林、科学避让、修建拦水坝等保护与治理措施及建议。     

基于蚁群算法的城市可持续发展综合评价

在可持续发展体系分类的基础上，应用蚁群算法对可持续发展各分类指数公式和综合指数公式进行优化，建立可持续发展评价模型。将该模型应用于乌鲁木齐市可持续发展水平评价，评价结果与现状分析一敛。结果表明该模型简单适用、有良好的通用性。     

APPLICATION OF MAP AND FILE INFORMATIONVISUALIZATION SYSTEM TO COMPREHENSIVEDIVISION OF NATURAL DISASTERS- Takingthe ChangjiangValleg as an Example

In recent years，scholars at home and abroad have method，and that vanous disasters would be analyzed assynthetically studied natural dlsaste‘theoretically and an Integral．SHI Peilun（1991）putforwad a scientificmethodologlcally，as well as its cases analys。s（CND，term—regional disaster system，which Indicates that1987； MA et al，1990； MARBLE，1990； NE et al，the situation of a disaster（calamity loss）results from1999； PATAK et al，1982； SHI，1991；VAN et al，h…     

Sedimentary characteristics of tide-dominated estuary in Donghetang Formation（Upper Devonian）, central Tarim Basin

The Donghetang Formation （Upper Devonian） in central Tarim Basin has been thought an important oil and gas reservoir since the abundant oil and gas resources were found in the wells W16, W20, W34, and other fields. However, the sedimentary environment of the Donghetang Formation has been disputed because it suffered from both tidal and fluvial actions and there were not rich fossils in the sandstone. After the authors analyzed sedimentary features by means of drill cores, well logging data, paleosols, and with SEM obseruations, three kinds of sedimentary environments were distinguished： alluvial fan, tide-dominated estuary, and shelf. Particularly, the sedimentary features of tide-dominated estuary were studied in detail. Besides, the authors discussed sedimentary characteristics of the Donghetang Formation which was divided into two fourth-order sequences and five system tracts. At the same time, according to the forming process of five system tracts, the whole vertical evolution and lateral transition of tide-dominated estuary were illustrated clearly. Finally, the reservoir quality was evaluated based on porosity and permeability.     

FUZZY COMPREHENSIVE EVALUATION OF CONTAINER TRANSPORTATION MODES ALONG THE CHANGJIANG RIVER MAIN LINE AND ITS DELTA AREA

The Changjiang River (Yangtze) is one of the fastest growth areas of container transportation in Chi-na. Rail, road and water transportation have competed against each other for container transportation in the Chang-jiang River main line and its delta area. It is of significance to assess these different transportation modes scientifi-cally in order to organize container transportation efficiently in this area and make decision for integral plan and construction of transportation system in this area. This paper outlines application of fuzzy comprehensive evaluation to appraise different modes of typical direction of containers. Twelve assessment indexes were decided. Membership functions were formulated. Evaluation results indicated that road transportation was optimal mode in the Changjiang River delta area, however water transportation was the primary way in the Changjiang River main line.     

Sensitivity analysis of a deterministic water temperature model to forest canopy and soil temperature in Catamaran Brook (New Brunswick,Canada)

A coupled deterministic hydrological and water temperature model, CEQUEAU, was modified to include soil temperature and crown closure in its calculation of local advective terms in the heat budget. The modified model was than tested to verify its sensitivity to these modifications. An analysis of the heat budget of a small forested catchment in eastern Canada revealed that the advective term related to interflow plays a significant role in the daily water heat budget, providing on average 28% of the local advective budget (which also includes advective heat terms from surface runoff and groundwater) and nearly 14% of the total heat budget (which includes all radiative terms at the water surface, convection and evaporation, as well as the local advective terms). Relative sensitivity indices (RSIs) were used to verify the impact of the newly introduced parameters and variables. Among them, parameters related to the forest cover (crown closure and leaf area index) have a maximum RSI of ?0·6; i.e. a 100% increase in value produces a 60% decrease in the local advective term. Parameters with the greatest influence are the volume of water contributing to interflow and the amplitude of the net radiative flux at the soil surface, which, if doubled, would double the contribution of the local interflow advective term to the heat budget. Copyright © 2003 John Wiley & Sons, Ltd.     

甲醛标准储备液浓度的不确定度评定

讨论了影响甲醛标准溶液浓度标定值不确定的各种因素,并评定了甲醛标准溶液浓度标定值的不确定度。当甲醛标准溶液浓度为1058 mg/L时,它的相对标准不确定度为0.70%(K=2)。     

气相色谱法测定地下水中六六六结果的不确定度评定

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。