PALEOSOLS OF SANDY LANDS AND ENVIRONMENTAL CHANGES IN THE WESTERN PART OF NORTHEAST PLAIN OF CHINA WESTERN DURING HOLOCENE

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...     

Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.     

离子色谱分析在黄土和粉尘研究中的应用

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。     

水成沉积与风成沉积及古土壤的磁组构特征

晚第四纪水成沉积、风成沉积、古土壤等的磁组构研究表明,不同成因的沉积物具有明显不同的磁组构特征。一般地,水成沉积的体积磁化率Ｋ受物源和水动力因素控制,Ｐ和Ｆ均＞１．０２,ｑ＜０．５;风成沉积的Ｋ受物源控制,内陆黄土的Ｋ明显高于沿海黄土及海岸风沙Ｋ,Ｐ和Ｆ均＜１．０２,ｑ的平均值＞０．５５;古土壤的Ｋ受母质沉积类型和成土环境的氧化还原条件控制,内陆古土壤的Ｋ偏高,沿海古土壤的Ｋ偏低,内陆古土壤的Ｋ远高于沿海古土壤的Ｋ,Ｐ和Ｆ均＜１．０２,ｑ的平均值在０．５左右。运用典型沉积的磁组构特征对比分析未知沉积物,可以得到未知沉积物的物源、沉积过程和环境信息。     

陕西洛川黄土-古土壤剖面中伊利石结晶度——黄土物质来源和古气候环境的指示

伊利石是我国黄土和古土壤中最主要的粘土矿物。本文选择陕西洛川黄土-古土壤国际典型剖面为研究对象,通过测定伊利石的结晶度(Kubler指数)、Srodon峰强比值(Ir)和2M_1多型含量,发现黄土物质的起源与中高温(>280℃)地质环境有关;黄土样品中伊利石结晶度值为0.25°2θ(Cu Ka),古土壤样品中伊利石结晶度值大于0.27°2θ(Cu Ka);黄土和古土壤中伊利石结晶度值的差别,是由于古土壤中伊利石含少量的膨胀层,而黄土样品中的伊利石不含有膨胀层而引起的。古土壤中伊利石的膨胀层的成因,与伊利石     

陕西洛川黄土沉积物中稀土元素及其它微量元素的化学淋滤研究

本文采用化学淋滤的方法对洛川黄土沉积物的酸溶和酸不溶相中稀土元素以及其它微量元素的分布分配特征进行了系统的分析。     

Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.     

黄土高原古气候变化定量重建的新进展

中国黄土- 红黏土沉积是可与深海沉积媲美的陆相沉积载体,记录了晚新生代东亚大陆气候环境变化历史。基于中国黄土的多种理化指标,重建了黄土高原地区构造- 千年尺度东亚季风变化历史,为探讨区域与全球气候的联系提供了关键证据。近年来,黄土高原古气候变化研究逐步从定性描述拓展到定量重建,本文旨在回顾基于中国黄土定量重建古温度和古降雨变化取得的重要进展。首先,梳理了古气候要素定量重建的指标和方法,古温度重建指标包括植硅体、碳酸盐耦合同位素、微生物脂类代用指标等;古降水变化敏感指标包括磁化率、白云石/方解石含量、生物微钙体Sr/Ca比值、有机碳同位素以及10Be等。然后,汇总了典型黄土剖面定量重建的古气候变化序列,分别从构造、轨道及千年时间尺度上探讨了古温度和古降雨的变化特征。结果表明,基于生标重建的不同时间跨度的土壤古温度变化序列,在冰期—间冰期尺度上的波动特征基本一致,但在冰盛期—冰消期时段出现了增温超前现象,说明陆地植被对土壤温度变化有重要调制作用。然而,不同指标重建的降水变化幅度差异较大,主导周期也存在差异,说明定量重建降水变化仍有较大挑战。最后,简要总结了黄土高原古气候定量重建存在的问题,明确了区分温度和降水季节性变化的重要性,指出加强地质记录与模拟结果的对比同化,将有助深化对多尺度季风变化动力学的理解。     

江苏金坛和尚墩旧石器遗址地层的古地磁年代与磁化率研究

北方黄土研究中磁化率分析已越来越多运用到第四纪风尘堆积研究中。采用古地磁极性柱结合磁化率曲线比对定年的方法,初步确定江苏金坛和尚墩遗址750cm厚的地层年龄为330kaBP,对应磁化率曲线判断该区域分别经历了24kaBP左右、110kaBP左右、190—240kaBP左右、300kaBP左右的4个暖湿期,其中间隔有3个干冷时期,具有完整的3个气候旋回。对应地层发育的4个古土壤层、3个黄土层的风尘堆积—古土壤序列。研究表明,虽然古地磁极性定年的方法有一定的局限性,但在以磁化率信息为辅助的条件下,可在一定程度上消除这些局限,获得较为准确的地层年代,多种证据表明这种方法是可靠的。     

陆源碎屑岩中的古土壤在地层分析中的应用

对各种古土壤的分类标准进行比较之后,重点介绍了Mack的古土壤分类及其土壤的演变序列。Mack的古土壤分类主要依据稳定矿物和保存在土壤中的古地貌属性,将古土壤划分为9种。在地层序列中古土壤的识别标志主要包括颜色、粒度、生物成因构造（植物生长痕迹）、原生沉积构造退化特征、层次化和边界特征、宏观结构特征、矿物及地球化学特征等。可以通过野外观察、室内显微镜观察、实验室化验及地震、测井资料来进行鉴别。陆相盆地具有很强的分隔性,盆地相变又非常复杂,寻找区域性较稳定的层序界面比较困难。越来越多的研究证实用古土壤划分陆相成因地层层序、解决地区及全球对比具有重要的实用价值。