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1.
A detailed characterization of the site is crucial to designing an efficient method of managing the risks associated with
tailings from abandoned mines. Therefore, samples collected from various depths within tailings in Guryong mine, Korea, were
analyzed for their chemical, physical and mineralogical characteristics. All samples of the Guryong tailings had acid-generating
potential. However, in the oxidation zone, the net acid generation (NAG) was low (30 kg H2SO4 t−1) although the acid neutralization potential (ANP) was less than zero. The ANP values in the unoxidation zone were higher
(> −56.0 kg CaCO3 t−1) than in the other zones. As a result, the amount of alkali ions that are needed to neutralize the acid needs to be considered.
In this experiment G3, G4 and G6 drill cores containing fine tailings particles near the unoxidation zone were observed to
contain calcite (CaCO3) with acid-neutralizing capacity. A low pH (2−4) in the oxidation zone of the tailings changed to a neutral pH in the unoxidation
zone of the tailings. These results suggest that the acid-neutralizing capacity of the tailings was controlled by particle
and mineral composition of tailings. 相似文献
2.
This paper presents results of a small scale study that utilized particle-tracking techniques to evaluate transport of river
water through an alluvial aquifer in a bank infiltration testing site in El Paso, Texas, USA. The particle-tracking survey
was used to better define filtration parameters. Several simulations were generated to allow visualization of the effects
of well placement and pumping rate on flow paths, travel time, the size of the pumping influence zone, and proportion of river-derived
water and groundwater mixing in the pumping well. Simulations indicate that migration of river water into the aquifer is generally
slow. Most water does not arrive at the well by the end of an 18-day pumping period at 0.54 m3/min pumping rate for a well located 18 m from the river. Forty-four percent of the water pumped from the well was river water.
The models provided important information needed to design appropriate sampling schedules for bank filtration practices and
ensured meeting adequate soil-retention times. The pumping rate has more effect on river water travel time than the location
of the pumping well from the river. The examples presented in this paper indicate that operating the pumping well at a doubled
distance from the river increased the time required for the water to travel to the well, but did not greatly change the capture
zone. 相似文献
3.
Mi Ok Park 《Ocean Science Journal》2006,41(4):301-313
Abundance and distribution of phytoplankton in seawater at southwestern East/Japan Sea near Gampo were investigated by HPLC
analysis of photosynthetic pigments during summer of 1999. Detected photosynthetic pigments were chlorophyll a, b, c1+2 (Chl a, Chl b, Chl c1+2), fucoxanthin (Fuco), prasinoxanthin (Pras), zeaxanthin (Zea), 19’-butanoyloxyfucoxanthin (But-fuco) and beta-carotene (β-Car).
Major carotenoid was fucoxanthin (bacillariophyte) and minor carotenoids were Pras (prasinophyte), Zea (cyanophyte) and But-fuco
(chrysophyte). Chl a concentrations were in the range of 0.16-8.3/land subsurface chlorophyll maxima were observed at 0-10m
at inshore and 30–50 m at offshore. Thermocline and nutricline tilted to the offshore direction showed a mild upwelling condition.
Results from size-fraction showed that contribution from nano+picoplankton at Chl a maximum layer was increased from 18% at
inshore to 69% at offshore on average. The maximum contribution from nano+picoplankton was found as 87% at St. E4. It was
noteworthy that contribution from nano+picoplanktonic crysophytes and green algae to total biomass of phytoplankton was significant
at offshore. Satellite images of sea surface temperature indicated that an extensive area of the East/Japan Sea showed lower
temperature (<18 °C) but the enhanced Chl a patch was confined to a narrow coastal region in summer, 1999. Exceptionally high
flux of low saline water from the Korea/Tsushima Strait seemed to make upwelling weak in summer of 1999 in the study area.
Results of comparisons among Chl a from SeaWIFs, HPLC and fluorometric analysis showed that presence of Chl b cause underestimation
of Chl a about 30% by fluorometric analysis but overestimation by satellite data about 30-75% compared to HPLC data. 相似文献
4.
Intense studies of upper and deep ocean processes were carried out in the Northwestern Indian Ocean (Arabian Sea) within the framework of JGOFS and related projects in order to improve our understanding of the marine carbon cycle and the ocean’s role as a reservoir for atmospheric CO2. The results show a pronounced monsoon-driven seasonality with enhanced organic carbon fluxes into the deep-sea during the SW Monsoon and during the early and late NE Monsoon north of 10°N. The productivity is mainly regulated by inputs of nutrients from subsurface waters into the euphotic zone via upwelling and mixed layer-deepening. Deep mixing introduces light limitation by carrying photoautotrophic organisms below the euphotic zone during the peak of the NE Monsoon. Nevertheless, deep mixing and strong upwelling during the SW Monsoon provide an ecological advantage for diatoms over other photoautotrophic organisms by increasing the silica concentrations in the euphotic zone. When silica concentrations fall below 2 μmol l−1, diatoms lose their dominance in the plankton community. During diatom-dominated blooms, the biological pathway of uptake of CO2 (the biological pump) appears to be more efficient than during blooms of other organisms, as indicated by organic carbon to carbonate carbon (rain) ratios. Due to the seasonal alternation of diatom and non-diatom dominated exports, spatial variations of the annual mean rain ratios are hardly discernible along the main JGOFS transect.Data-based estimates of the annual mean impact of the biological pump on the fCO2 in the surface water suggest that the biological pump reduces the increase of fCO2 in the surface water caused by intrusion of CO2-enriched subsurface water by 50–70%. The remaining 30 to 50% are attributed to CO2 emissions into the atmosphere. Rain ratios up to 60% higher in river-influenced areas off Pakistan and in the Bay of Bengal than in the open Arabian Sea imply that riverine silica inputs can further enhance the impact of the biological pump on the fCO2 in the surface water by supporting diatom blooms. Consequently, it is assumed that reduced river discharges caused by the damming of major rivers increase CO2 emission by lowering silica inputs to the Arabian Sea; this mechanism probably operates in other regions of the world ocean also. 相似文献
5.
Hydrodynamic modeling of flushing time in a small estuary of North Bay, Florida, USA 总被引:1,自引:0,他引:1
Freshwater fraction method is popular for cost-effective estimations of estuarine flushing time in response to freshwater inputs. However, due to the spatial variations of salinity, it is usually expensive to directly estimate the long-term freshwater fraction in the estuary from field observations. This paper presents the application of the 3D hydrodynamic model to estimate the distributions of salinity and thus the freshwater fractions for flushing time estimation. For a case study in a small estuary of the North Bay in Florida, USA, the hydrodynamic model was calibrated and verified using available field observations. Freshwater fractions in the estuary were determined by integrating freshwater fractions in model grids for the calculation of flushing time. The flushing time in the North Bay is calculated by the volume of freshwater fraction divided by the freshwater inflow, which is about 2.2 days under averaged flow conditions. Based on model simulations for a time series of freshwater inputs over a 2-year period, a power regression equation has been derived from model simulations to correlate estuarine flushing time to freshwater inputs. For freshwater input varying from 12 m3/s to 50 m3/s, flushing time in this small estuary of North Bay changes from 3.7 days to 1.8 days. In supporting estuarine management, the model can be used to examine the effects of upstream freshwater withdraw on estuarine salinity and flushing time. 相似文献
6.
Th sorption and export models in the water column: A review 总被引:2,自引:3,他引:2
Nicolas Savoye Claudia Benitez-Nelson Adrian B. Burd J. Kirk Cochran Matthew Charette Ken O. Buesseler George A. Jackson Matthieu Roy-Barman Sabine Schmidt Marc Elskens 《Marine Chemistry》2006,100(3-4):234
Over the past few decades, the radioisotope pair of 238U / 234Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to 234Th. It is focused on the models associated with 234Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / 234Th ratios (Buesseler et al.), 234Th speciation (Santschi et al.) and present and future applications of 234Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of 234Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current 234Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate 234Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of 234Th export, especially during high flux events (> ca. 800 dpm m− 2 d− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of 234Th as a tracer of particle dynamics and flux in more complicated regimes. 相似文献
7.
Changing grading of soil: effect on critical states 总被引:6,自引:3,他引:3
Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles
leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine
material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical
states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the
dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state
conditions as the grading changes. 相似文献
8.
An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd,
Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and
the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point
source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations
of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and
POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g−1) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC
concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations
suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture,
sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM
metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between
metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William
series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved
Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport. 相似文献
9.
10.
A. Ankilov A. Baklanov M. Colhoun K. -H. Enderle J. Gras Yu. Julanov D. Kaller A. Lindner A. A. Lushnikov R. Mavliev F. McGovern T. C. O'Connor J. Podzimek O. Preining G. P. Reischl R. Rudolf G. J. Sem W. W. Szymanski A. E. Vrtala P. E. Wagner W. Winklmayr V. Zagaynov 《Atmospheric Research》2002,62(3-4)
During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles. 相似文献