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排序方式: 共有205条查询结果,搜索用时 15 毫秒
1.
闽南近海常见鲨鳐类肝油的四种理化常数和角鲨烯含量 总被引:8,自引:0,他引:8
本文分析测定了闽南近海常见鲨鳐类肝油的理化常数和角鲨烯含量。尖头斜齿鲨肝油的碘值特别高,说明其中脂肪酸的不饱和程度很高;非皂化物含量很低,约占肝油重的38×10-3(m/m);角鲨烯含量极微,在肝油中仅占84×10-5(m/m)。闽南近海常见鲨鳐类肝油的角鲨烯含量均很低,变化在(31~116)×10-5(m/m)之间。在相同的气相色谱条件下,小孔沙条鲨和狭纹虎鲨肝油中没有检测到角鲨烯。 相似文献
2.
Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas 总被引:3,自引:0,他引:3
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters. 相似文献
3.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
4.
裂隙型单斜介质中弹性系数的计算及波的传播特性研究 总被引:3,自引:1,他引:3
根据Hudson等关于裂隙介质弹性系数计算的扰动理论及Bond变换矩阵原理,给出了各向同性介质中含多组垂直裂隙时等效弹性系数的计算方法。计算了含两组斜交的垂直裂隙形成的单斜各向异性介质中的等效弹性系数,并根据Christoffel方程推导、得出水平面内平面波传播的相速度和群速度随方位变化的特性。 相似文献
5.
Kusuma G. Rao V. N. Lykossov A. Prabhu S. Sridhar E. Tonkacheyev 《Journal of Earth System Science》1996,105(3):227-260
An attempt has been made here to study the sensitivity of the mean and the turbulence structure of the monsoon trough boundary
layer to the choice of the constants in the dissipation equation for two stations Delhi and Calcutta, using one-dimensional
atmospheric boundary layer model withe-ε turbulence closure. An analytical discussion of the problems associated with the constants of the dissipation equation is
presented. It is shown here that the choice of the constants in the dissipation equation is quite crucial and the turbulence
structure is very sensitive to these constants. The modification of the dissipation equation adopted by earlier studies, that
is, approximating the Tke generation (due to shear and buoyancy production) in theε-equation by max (shear production, shear + buoyancy production), can be avoided by a suitable choice of the constants suggested
here. The observed turbulence structure is better simulated with these constants. The turbulence structure simulation with
the constants recommended by Aupoixet al (1989) (which are interactive in time) for the monsoon region is shown to be qualitatively similar to the simulation obtained
with the constants suggested here, thus implying that no universal constants exist to regulate dissipation rate.
Simulations of the mean structure show little sensitivity to the type of the closure parameterization betweene-l ande-ε closures. However the turbulence structure simulation withe-ε. closure is far better compared to thee-l model simulations. The model simulations of temperature profiles compare quite well with the observations whenever the boundary
layer is well mixed (neutral) or unstable. However the models are not able to simulate the nocturnal boundary layer (stable)
temperature profiles. Moisture profiles are simulated reasonably better. With one-dimensional models, capturing observed wind
variations is not up to the mark. 相似文献
6.
为了实现地面稳定性降低时间与地点、持续作用时间与空间影响分布的全面跟踪监测,该文基于卫星定位连续运行站(CORS)站网观测数据,结合地表水、大气及海平面变化资料,提出了CORS站网时变重力场及负荷形变场精化的已知负荷移去恢复法,建立了基于时变重力场的确定性地面稳定性变化定量辨识准则。以丽水温州地区为例,利用2015-2017年CORS网及有关水文观测数据进行计算分析,根据40起已发生的历史地质灾害(险情)事件对结果进行验证:丽水温州地区的CORS网具备区域重力场变化与地面稳定性跟踪监测能力,具备地质灾害灾变过程追踪与前兆捕获能力,CORS站网的地质灾害前兆提前捕获率可达92.5%。 相似文献
7.
Pasquale Crea Concetta De Stefano Demetrio Milea Silvio Sammartano 《Marine Chemistry》2008,112(3-4):142-148
The results of a potentiometric investigation (by ISE-H+, glass electrode) on the speciation of phytate ion (Phy12−) in an ionic medium simulating the major components (Na+, K+, Ca2+, Mg2+, Cl− and SO42−) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca2+–Mg2+–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH3Phy5−, MgCaH4Phy4−, Mg2CaH3Phy3− and Mg2CaH4Phy2− species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X113 = 2.67 and log X114 = 1.37 for MgCaH3Phy5− and MgCaH4Phy4− (statistical value is log Xstat = 0.60), and log X213 = 6.11 and log X214 = 2.15 for Mg2CaH3Phy3− and Mg2CaH4Phy2− (log Xstat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand). 相似文献
8.
利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO3结构Cu3N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu3N的弹性常数,Poisson比等,并分析出Cu3N在零温零压下是稳定的. 通过准谐Debye模型计算Cu3N的热力学性质,得到了Cu3N的晶格常数、等压比热容、等容比热 相似文献
9.
This paper employs the highly accurate valence internally contracted multireference configuration interaction method to investigate the potential energy curves (PECs) for the ground state (X1Σ+) and two low-lying excited states (A1Π and D1Δ of phosphorus nitride (PN) radical with the correlation-consistent basis set, aug-cc-pV6Z, in the valence range. Relativistic effects are considered in these calculations. The spectroscopic constants of the X1Σ+ and A1Π states are calculated based on the PECs, and the results are in good accord with the available experimental data. The first 30 vibrational states for the A1Π state and the first 40 vibrational states for the A1Π state are determined when J=0. For each vibrational state, molecular constants G(υ), B(υ) and D(υ) are also attained. 相似文献
10.
利用小波分析函数多尺度逼近方法,将剪切型结构在地震作用下时变的阻尼和刚度用尺度函数的线性组合表示,将时变参数的辨识问题转化为由已知的正交尺度函数和系统的输入输出来估计线性组合中的时不变系数问题,用最小二乘法对剪切型框架结构在地震作用下时变的刚度和阻尼进行了有效的辨识。此方法无需事先假定系统参数的时变规律,在有噪声情况下可以用Tikhonov正则化方法减小识别方程的不适定性对识别结果的影响。数值算例表明了该方法的有效性。 相似文献