高放废物处置库天然类比及其有关的地球化学问题

介绍了高放废物处置库天然类比研究的主要内容,重点阐述了类比研究中涉及的地球化学问题,包括核素溶解度和化学形态研究、核素迁移速率研究、核素迁移影响因素研究,并总结相关问题研究取得的成果和认识.     

Physical and chemical environments of abnormal vitrinite reflectance evolution in the sedimentary basins

Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure is regarded as not the only factor to retard the increase of vitrinite reflectance (R _o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment (fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins. This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R _o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R _o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry. Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报]     

高温超高压模拟实验研究--Ⅱ.高温高压下烷烃产物的演化特征

对不成熟泥炭样品进行了高压（0.1～2 GPa) 、高温( 200 ℃～400 ℃）模拟实验,并对实验后样品的烷烃产物进行了分析。结果显示,同一压力条件下,温度升高,烷烃参数表现出更成熟的特征;温度较低时（200 ℃）,压力升高,烷烃参数表现出不成熟,温度较高时（400 ℃）,除个别特殊点之外,压力增大,烷烃参数愈来愈不成熟,说明温压条件都是影响有机质成熟的重要因素,压力的存在会抑制有机质的成熟作用。用模拟实验手段来探讨压力的作用和影响,具有重要的理论及实际意义。     

Differential retardation of organic matter maturation by overpressure

Thetraditionalhydrocarbongenerationmodeldoesnottakeintoaccounttheeffectofpressure[1].Astotheroleofpressureinorganicmattermaturationandpetroleumgeneration,threeconflictingopinionshaveeverbeenproposed:(1)Increasingpressurehasnodetectableeffectonorganic-mattermaturation[1,2];(2)increasingpressureenhanceshydrocarbon-thermaldestruction[3];(3)increasingpressuresignificantlyretardsorganic-mattermaturationandhydrocarbongeneration[4,5].Therearemorethan180overpressuredbasinsintheworld.Theroleofoverpress…     

黔西北普宜地区下三叠统嘉陵江组沉凝灰岩锆石LA-ICP-MS U-Pb年龄、微量元素特征及其地质意义

早三叠世时期频繁的火山事件是导致全球性气候和海洋环境异常的主要原因,前人对早三叠世重要界线时期的火山事件地层开展了大量研究,但对典型界线时期以外的其他火山事件地层却鲜有报道.本文以上扬子西南普宜地区嘉陵江组两件沉凝灰岩为研究对象开展了岩石学、岩相学、锆石年代学及微量元素组合特征等方面的研究.沉凝灰岩样品具有典型岩浆锆石...     

Impact of high water pressure on oil generation and maturation in Kimmeridge Clay and Monterey source rocks: Implications for petroleum retention and gas generation in shale gas systems

This study presents results for pyrolysis experiments conducted on immature Type II and IIs source rocks (Kimmeridge Clay, Dorset UK, and Monterey shale, California, USA respectively) to investigate the impact of high water pressure on source rock maturation and petroleum (oil and gas) generation. Using a 25 ml Hastalloy vessel, the source rocks were pyrolysed at low (180 and 245 bar) and high (500, 700 and 900 bar) water pressure hydrous conditions at 350 °C and 380 °C for between 6 and 24 h. For the Kimmeridge Clay (KCF) at 350 °C, Rock Eval HI of the pyrolysed rock residues were 30–44 mg/g higher between 6 h and 12 h at 900 bar than at 180 bar. Also at 350 °C for 24 h the gas, expelled oil, and vitrinite reflectance (VR) were all reduced by 46%, 61%, and 0.25% Ro respectively at 900 bar compared with 180 bar. At 380 °C the retardation effect of pressure on the KCF was less significant for gas generation. However, oil yield and VR were reduced by 47% and 0.3% Ro respectively, and Rock Eval HI was also higher by 28 mg/g at 900 bar compared with 245 bar at 12 h. The huge decrease in gas and oil yields and the VR observed with an increase in water pressure at 350 °C for 24 h and 380 °C for 12 h (maximum oil generation) were also observed for all other times and temperatures investigated for the KCF and the Monterey shale. This shows that high water pressure significantly retards petroleum generation and source rock maturation. The retardation of oil generation and expulsion resulted in significant amounts of bitumen and oil being retained in the rocks pyrolysed at high pressures, suggesting that pressure is a possible mechanism for retaining petroleum (bitumen and oil) in source rocks. This retention of petroleum within the rock provides a mechanism for oil-prone source rocks to become potential shale gas reservoirs. The implications from this study are that in geological basins, pressure, temperature and time will all exert significant control on the extent of petroleum generation and source rock maturation for Type II source rocks, and that the petroleum retained in the rocks at high pressures may explain in part why oil-prone source rocks contain the most prolific shale gas resources.     

异常压力对有机质的抑制作用及其石油地质意义

板桥凹陷异常压力发育,在板深35井中发现有机质的演化明显的受到了超压的抑制作用,具有和活化能、热导率、水动力等因素造成的热演化异常明显不同的特征。综合地质、地球化学分析表明,异常孔隙流体压力对有机质热演化的抑制作用是有条件的,在超压早期发育、高原始有机质丰度和高有机质热演化产物滞留的情况下超压对有机质的演化具有明显的抑制作用,超压对有机质演化的抑制作用在深层勘探方面具有重要的意义。     

地浸场地残余溶液对水环境影响中的水文地球化学问题讨论

溶质迁移的理论是水环境评价及其整治的科学基础。溶质迁移理论包括水动力弥散、分子扩散和水文地球化学的水岩作用。文章讨论了地浸场地残留溶液对环境影响的预测方法、围岩对污染水的自净和地下水环境恢复的功能，对三种预测污染水对环境影响方法的计算蛄果进行了对比。通过以上讨论，展示水文地球化学在水环境评价和整治工作中有不可忽略的作用和意义，并提出了在水环境评价和整治工作中正确确定弥散系数、阻滞系数、饱和阻留容量、阻滞速率、溶质迁移速度的重要性。文中通过实例介绍了饱和阻滞容量、阻滞速率、溶质迁移速度等参数的求测计算方法。     

The use of natural analogues to assess radionuclide transport

Predicting the long-term safety and performance of a repository for intermediate- to high-level radioactive wastes requires the evaluation of various scenarios which may influence the integrity of the repository system. One such scenario, radionuclide transport, is described, and some of the geochemical processes which serve to enhance or retard transport are illustrated with examples selected from natural analogue or natural system studies. These studies, as distinct from laboratory simulations, help considerably in understanding how near- and far-field radionuclide transport mechanisms work over geological timescales (thousands to hundreds of thousands of years), more in line with the anticipated lifespan of a repository.

Processes addressed include: stability of the spent fuel UO₂ matrix; bentonite backfill as a barrier to radionuclide diffusion; retention of radionuclides by absorption on fracture minerals; transport and diffusion of radionuclides controlled by interconnected bedrock porosity; geochemical influence and behaviour of repository construction materials on radionuclide transport.     

Effects of patterned Artemisia capillaris on overland flow velocity under simulated rainfall

Vegetation cover is an important factor for erosion control. Laboratory‐simulated rainfall experiments were conducted to quantify the effectiveness of patchy distributed Artemisia capillaris in retarding overland flow velocity. Simulated storms (60, 90, 120, and 150 mm h^?1) were applied on a bare plot (CK) and four different plant patterns, a banded pattern perpendicular to the slope direction (BP), a single long strip parallel to slope direction (LP), small patches distributed like a checkerboard (SP1), and small patches distributed like a letter “X” (SP2). All treatments had three replicates. Each plot underwent two sets of experiments, intact plant plots and root plots (the above‐ground parts were removed, only roots were reserved), respectively. Results showed that flow velocity increased with rainfall intensity, and the lower slope velocity (V_l) was higher than the upper slope velocity (V_u). The removal of grass shoots increased flow velocity. Compared with bare soil plot, intact plants reduced mean flow velocity by 14%–60%, whereas the reduction declined to <40% for the root plots. BP and both SP treatments performed more effectively than LP in retarding flow velocity, whereas no significant differences were identified between BP and SP. The contributions of A. capillaris shoots and roots to the reductions in flow velocity under different rainfall intensities were different. The shoots made greater contribution of 53%–97% at 60 and 90 mm h^–1, and the roots contributed more (51%–81%) at 120 and 150 mm h^–1. Runoff and sediment rate had significant (p < 0.05) linear correlations with mean flow velocity. Copyright © 2012 John Wiley & Sons, Ltd.