The Ca-Eskola component in eclogitic clinopyroxene as a function of pressure, temperature and bulk composition: an experimental study to 15 GPa with possible implications for the formation of oriented SiO2-inclusions in omphacite

Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO₂–TiO₂–Al₂O₃–Fe₂O₃–FeO–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅ and SiO₂–TiO₂–Al₂O₃–MgO–CaO–Na₂O to investigate the Ca-Eskola (CaEs Ca_0.5□_0.5AlSi₂O₆) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO₂ ± TiO₂ ± kyanite as a function of P, T, and bulk composition. The results show that CaEs_ss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEs_ss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison, no significant increase in CaEs_ss with increasing P could be observed. If the formation of oriented SiO₂-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEs_ss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes are not necessarily restricted to ultrahigh pressure metamorphic conditions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

黄山东镁铁超镁铁杂岩中的辉石化学成分研究

通过对黄山东镁铁超镁铁杂岩的辉石化学成分研究，证明辉石的化学成分受寄主岩石类型的制约，从超镁铁岩相到角闪辉长岩相斜方辉石的化学成分由富ＭｇＯ、ＳｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３到富ＦｅＯ、ＴｉＯ＿２、ＣａＯ、ＭｎＯ；单斜辉石化学成分由富Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、Ｎａ＿２Ｏ、ＭｇＯ到富ＦｅＯ、ＭｎＯ、ＣｏＯ。在同一寄主岩石中，单斜辉石比斜方辉石富ＴｉＯ＿２、Ａｌ＿２Ｏ＿３、Ｃｒ＿２Ｏ＿３、ＣａＯ和Ｎａ＿２Ｏ，贫ＭｇＯ、ＳｉＯ＿２、ＭｎＯ和ＦｅＯ。根据辉石化学成分特征得出黄山东杂岩形成于岛弧环境，为上地幔石榴二辉檄榄岩部分熔融形成的拉斑玄武岩岩浆结晶分异作用的产物。     

冀东太平寨地区斜方辉石的地质特征和成因研究

冀东太平寨地区太古宙麻粒岩相变质杂岩中,含有岩浆成因和变质成因的两类斜方辉石,后者又可分为早、晚两期。在地质产状研究的基础上,据岩相学、矿物化学成分和温度、压力条件,阐明了斜方辉石的成因。研究结果为该区划分地质事件和探索早期地壳演化历史提供了重要的依据。     

辉石巨晶中的硫化物及其成因

我国一些地区玄武岩辉石巨晶中的硫化物球泡(0.02-0.05mm)呈点阵式、散布式、定向带状或微裂隙羽状分布。硫化矿物组合是磁黄铁矿-镍黄铁矿-黄铜矿,其中以磁黄铁矿为主(～90％)。根据硫化物的规则排布以及高温矿物组合推测点阵式、散布式硫化物形成于地幔。是由溶解了～1％S的硅酸盐熔体在减压上升过程中析出过饱和的硫所致。     

肇东陨石低钙辉石超微结构的研究

在肇东陨石低钙辉石中观察到各种堆垛缺陷,包括斜方-单斜辉石相转变、畴结构、2.7nm长周期结构以及自然界极为罕见的奇数倍八面体层堆垛缺陷——1.35nm等。高分辨像所揭示的1.35nm的新特征是可以重复两次。文中提出1.35nm的结构是“A+B+A-”型。1.35nm片晶仅见于3,4型球粒陨石,因而它可作为由原顽火辉石淬冷形成的、末遭受后期热变质的典型结构。奇数倍0.9nm宽度单斜辉石片晶在吉林陨石(H5)、安龙陨石(H5)及东台陨石(LL6)中均有出现,它表明这些陨石的辉石都曾由原顽火辉石转变而成。 肇东陨石低钙辉石中相当频繁的相变以及高能量的奇数倍0.45nm层堆垛缺陷的存在,可能表明该陨石形成于退变质过程。     

冀东迁安迁西群含铁变质岩系中的辉石及其与铁矿的成因联系

本文对冀东迁安麻粒岩及有关岩石中的辉石进行了研究，结果表明:辉石的含铁度 明显受寄主岩石化学成分的制约，寄主岩石的/Mg0和=(Fe203 ×0.8999 + Fa0) 值愈高，辉石的含铁度也愈高;共存辉石对的Fe2+ 一Mg分配系数(KD劝不仅受结晶温压条件 控制，同时也受辉石其它成分的影响。但Ca-Mg-Fe 三角图解等资料研究表明:共存的二辉 石对是平衡结晶的产物，其KD平均值也符合张儒媛等(1)统计的变质辉石平均值为1.85的规 律。通过二辉石温度计计算和矿物共生组合等资料的分析，得出辉石形成的温度为869±60ºC.压力为5 ×108-9 ×108 Pa。本区与铁矿体成过渡关系的辉石岩全铁含量与工业铁矿大致相等，铁矿的成因与其有着非常密切的关系。     

西藏班公湖地区晚白垩世构造体制由挤压向伸展的转换:来自岩浆岩的证据

班公湖蛇绿混杂岩带内分布着一系列小型斜长花岗斑岩和花岗闪长岩岩体,锆石U-Pb年龄分别为97.4±1.1Ma和91.94±0.78Ma,具埃达克质岩特征,高Si O2、Al2O3和Sr,低Y和Yb,Sr/Y35,轻重稀土分异明显,亏损Nb、Ta和Ti,Cr和Ni含量很低,推测为玄武质岩浆底侵加厚下地壳部分熔融形成。辉石闪长岩脉分布于南侧日土花岗岩内,推测年龄为80~76Ma,岩石地球化学显示亏损Zr、Hf、Ti、Y等高场强元素,富集大离子亲石元素,且具较高的Sc、Y、Cr、Co、HREE和Mg#值(40),源区为经过熔体交代的上地幔。结合前人资料,本文认为班公湖地区在97~92Ma仍处于持续碰撞造山、地壳加厚过程中;92Ma之后,构造体制从碰撞期的挤压转变为碰撞后的板内伸展;80~76Ma,板内的伸展进一步加剧。     

铜陵舒家店矿床年代学-地球化学特征及其意义

本文对铜陵舒家店辉石闪长岩开展了年代学和地球化学的系统研究。结果表明,舒家店辉石闪长岩的侵入年龄为140.5±1.4Ma,低于铜陵地区花岗闪长岩年龄。辉石闪长岩是矿床赋矿岩石,据此推测成矿时代也应该同为140.5Ma左右,或稍晚于岩浆岩侵位的时代。舒家店辉石闪长岩的地球化学特征表明其SiO2含量为50%左右,属于稍偏基性的岩类,并且具有大离子亲石元素(LILE:Ba,Sr,Th,Pb)的富集,而相对亏损高场强元素(HFSE:Zr,Nb,Hf),反映出该侵入岩的原始岩浆可能来源于受到了板片俯冲作用改造的富集地幔。舒家店岩体及铜金矿床形成的大地构造背景可能与古太平洋板块俯冲密切相关,位于大陆边缘岩浆弧的内陆一侧环境,它可能是俯冲洋壳部分熔融形成的熔体或流体交代地幔楔并使地幔楔发生部分熔融而形成的玄武质岩浆侵位到地壳浅部过程中混染了大量地壳物质而成。     

Pyrite–anhydrite–magnetite–pyroxene-type deposits and coexisting hydrothermal fluids in Mesozoic volcanic basins, Yangtze River Valley, China

Anhydrite–pyrite–magnetite–pyroxene–type deposits occur in the Mesozoic volcanic areas of the Middle–Lower Yangtze Valley in China. These deposits are hosted in alkaline basaltic rocks, and are generally accompanied by melanocratic and leucocratic alteration zones, both of which are characterized by a distinct vertical zonation pattern. Investigation of these zones indicates that the chemical compositions of solid solutions and polymorphs of various minerals vary spatially in the alteration profile, upwards from the lowest level, and outwards from the center.Here we report a case study on the Luohe deposit. In the melanocratic-alteration zone, the composition of magnetite (including trace elements Ti, V, Mg, Mn), pyroxene (Mg, Fe²⁺, Fe³⁺, Al₂O₃), plagioclase (An_xAb_{1 − x}), pyrite (Co, Ni) and apatite (F, CeO₂ + Y₂O₃ + La₂O₃) changes with depth. The isotherms of hydrothermal fluids determined from fluid inclusion data, including homogenization temperature and salinity, also vary with depth.Activity diagrams were constructed from mineral and isotherm analysis to estimate the chemical constraints on the alteration-mineral assemblages and the coexisting hydrothermal solutions for the Na₂O–K₂O–CaO–MgO–FeO–Fe₂O₃–A1₂O₃–SiO₂–H₂SO₄–H₂S–HCI–H₂O system at 350 to 600 °C and 500 bars (50 MPa), assuming that the major alteration mineral assemblages along the profile reflect the nature of the coexisting hydrothermal solutions. The activity diagrams adopted the major minerals as buffers to fix the activities of the aqueous species in the system, simulating the physicochemical conditions of the magnetite–anhydrite–pyroxene equilibrium and of solid solutions of diopside–hedenbergite, grossular–andradite and anorthite–albite found in the profile.This study provides an approach to modeling the chemical constraints of coexisting fluids in ore-alteration zones based on field observations.     

胜利油田火山岩辉石中岩浆包裹体成分及有关成因问题

对胜利油田火山岩中辉石及其中岩浆包裹体成分的研究表明：ＣＯ２气藏区和非ＣＯ２气藏区新生代火山岩辉石及其中岩浆包裹体成分有明显区别,前者中辉石为普通辉石,成分相对富ＳｉＯ２,而贫Ａｌ２Ｏ３、ＴｉＯ２、ＭｇＯ和挥发成分;而后者中辉石为透辉石,成分相对贫ＳｉＯ２和挥发份,而富Ａｌ２Ｏ３、ＴｉＯ２和ＭｇＯ。前者岩浆包裹体玻相中富含ＣＯ２,包裹体中的金属子矿物多为黄铁矿;而后者岩浆包裹体玻相中贫ＣＯ２;包裹