X-ray synchrotron emission from the oblique shock in the jet of the powerful radio galaxy 3C 346

We report the first detection, with Chandra , of X-ray emission from the jet of the powerful narrow-line radio galaxy 3C 346. X-rays are detected from the bright radio and optical knot at which the jet apparently bends by approximately 70°. The Chandra observation also reveals a bright galaxy-scale atmosphere within the previously known cluster and provides a good X-ray spectrum for the bright core of 3C 346. The X-ray emission from the knot is synchrotron radiation, as seen in lower-power sources. In common with these sources, there is evidence of morphological differences between the radio/optical and X-ray structures, and the spectrum is inconsistent with a one-component continuous-injection model. We suggest that the X-ray-bright knot is associated with a strong oblique shock in a moderately relativistic, light jet, at ∼ 20° to the line of sight, and that this shock is caused by the jet interacting with the wake in the cluster medium behind the companion galaxy of 3C 346. The general jet curvature can result from pressure gradients in the cluster atmosphere.     

A Chandra detection of the radio hotspot of 3C 123

Chandra X-ray Observatory observations of the powerful, peculiar radio galaxy 3C 123 have resulted in an X-ray detection of the bright eastern hotspot, with a 1-keV flux density of ∼5 nJy. The X-ray flux and spectrum of the hotspot are consistent with the X-rays being inverse-Compton scattering of radio synchrotron photons by the population of electrons responsible for the radio emission ('synchrotron self-Compton emission') if the magnetic fields in the hotspot are close to their equipartition values. 3C 123 is thus the third radio galaxy to show X-ray emission from a hotspot which is consistent with being in equipartition. Chandra also detects emission from a moderately rich cluster surrounding 3C 123, with L _X(2–10 keV)=2×10⁴⁴ erg s⁻¹ and kT ∼5 keV, and absorbed emission from the active nucleus, with an inferred intrinsic column density of 1.7×10²² cm⁻² and an intrinsic 2–10 keV luminosity of 10⁴⁴ erg s⁻¹.     

Nature of microstructure in pulsar radio emission

We present a model for microstructure in pulsar radio emission. We propose that micropulses result from alteration of the radio wave generation region by nearly transverse drift waves propagating across the pulsar magnetic field and encircling the bundle of the open magnetic field lines. It is demonstrated that such waves can modify the curvature of the field lines significantly. This, in turn, affects strongly fulfilment of the resonance conditions necessary for the excitation of radio waves. The time-scale of micropulses is therefore determined by the wavelength of the drift waves. The main features of the microstructure are naturally explained within the framework of this model.     

The klein–nishina Effects in Blazar Jets

Blazars are the only (with one or two exceptions) extragalactic objects which were detected and identified at gamma-ray energies so far. It is suspected that most of the unidentified gamma-ray sources may be the blazars as well. Because the entire electromagnetic spectrum of these objects is dominated by non-thermal radiation from relativistically moving jets, the effects such as the Klein–Nishina regime in the Compton scattering may play a major role in shaping some parts of the blazar spectrum. Within the framework of external radiation Compton model, we present how these effect influence the spectra of blazars for which the production of gamma rays is dominated by Comptonization of external radiation.     

The brightness temperature problem in extreme intra-day variable quasars: a model for PKS 0405-385

I re-examine the brightness temperature problem in PKS 0405-385, which is an extreme intra-day variable radio quasar with an inferred brightness temperature of  ∼5 × 10¹⁴ K  at 5 GHz, well above the Compton catastrophe limit of  ∼10¹¹ K  that is reached when the synchrotron photon energy density exceeds the energy density of the magnetic field. If one takes into account the uncertainty in the distance to the ionized clouds responsible for interstellar scintillation causing rapid intra-day variability in PKS 0405-385, it is possible that the brightness temperature could be as low as  ∼10¹³ K  at 5 GHz, or even lower. The radio spectrum can be fitted by optically thin emission from mono-energetic electrons, or an electron spectrum with a low-energy cut-off such that the critical frequency of the lowest energy electrons is above the radio frequencies of interest. If one observes optically thin emission along a long narrow emission region, the average energy density in the emission region can be many orders of magnitude lower than calculated from the observed intensity if one assumed a spherical emission region. I discuss the physical conditions in the emission region and find that the Compton catastrophe can then be avoided using a reasonable Doppler factor. I also show that MeV to 100-GeV gamma-ray emission at observable flux levels should be expected from extreme intra-day variable sources such as PKS 0405-385.     

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.