Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes. 相似文献
在真空条件下矿物粉末热导率的实验测量,可为我们研究月球及行星表面的热属性和热演化,解译热红外和微波探测数据,开展月球及行星探测载荷设计提供重要的数据参数。本研究主要采用改造后的Hot Disk TPS 2500S导热仪对辉石粉末的热导率进行测量。同时,分析了真空度、温度对辉石粉末热导率的影响。实验结果表明:1)热导率随着真空度的降低呈下降趋势,大气压力在1000Pa时,辉石粉末热传导机制发生明显改变。在低压条件下(1000Pa)热导率随真空度的变化趋于平缓;2)辉石粉末热导率随温度的升高而增大,但是增大的幅度在低压和常压条件下存在明显差异。根据实验结果,提出了低压条件下辉石粉末热导率随真空度和温度变化的关系式。本研究表明,在月球和火星表面热环境的研究中,温度和压力对热导率的影响程度是不同的。上述结果对未来开展地外样品的热导率测量提供了重要的参考。 相似文献
Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite
Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1
is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ),
and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and
Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during
stage 1, and (2) implies an increase of DVIlm during stage 2, most likely related to a shift in fO2. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation
of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates
is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus
magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite
saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive
postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite.
The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content.
The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO2 from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
An ESR experimental study of artificial optical bleaching of sedimentary quartz has shown that the aluminum center was maximally bleached after a 6-month illumination equivalent to natural light. This duration seems too long to apply in natural conditions. Nevertheless, the measurement of the ESR intensity of aluminum centers in quartz extracted from modern sediments and deposited in sandy bars shows that the maximum bleaching has effectively been reached.
In order to determine the relationship between the bleaching and the distance covered by a quartz grain in a river, samples were collected along the Creuse River (France) from its spring to about 170 km downstream, where maximum bleaching levels were observed in previous studies. The ESR intensities of the aluminum and titanium centers in quartz were measured, using X-band spectroscopy, before and after artificial bleaching. The difference measured between these sub-samples shows that the maximum bleaching level is obtained in the course of the first kilometer. Hence, the assumption that ESR dating of fluvial sediment is based on the optical bleaching was validated. 相似文献
Cyanoacetylene (HC3N) and diacetylene (C4H2) play an important role in the photochemistry of Titan's atmosphere, in part because of their strong absorption between 110 and 180 nm. Accurate photoabsorption cross-sections at temperatures representative of Titan's atmosphere are required to interprete Cassini observations and to calculate photolysis rates used in photochemical models. Using synchrotron radiation as a tunable vacuum ultraviolet (VUV) light source, we have measured absolute photoabsorption cross-sections of C4H2 and HC3N with a spectral resolution of 0.05 nm in the region between 80 and 225 nm and at different temperatures between 173 and 295 K. The measured cross-sections are used to model transmission spectra of Titan atmosphere in the VUV. 相似文献
We suggest a technique to determine the chemical and mineral composition of the lunar surface using artificial neural networks (ANNs). We demonstrate this powerful non-linear approach for prognosis of TiO2 abundance using Clementine UV-VIS mosaics and Lunar Soil Characterization Consortium data. The ANN technique allows one to study correlations between spectral characteristics of lunar soils and composition parameters without any restrictions on the character of these correlations. The advantage of this method in comparison with the traditional linear regression method and the Lucey et al. approaches is shown. The results obtained could be useful for the strategy of analyzing lunar data that will be acquired in incoming lunar missions especially in case of the Chandrayaan-1 and Lunar Reconnaissance Orbiter missions. 相似文献
An experimental investigation was carried out on the reconstituted Tunis soft soil (TSS) that was extracted from the centre of Tunis City at 35-m depth. Three series of consolidation tests were performed on TSS specimens. The first series included consolidation tests by preload. In the second series, vacuum consolidation tests were performed. The third series comprised a vacuum consolidation test combined with the preload. Excess pore water pressure and settlement were measured during the consolidation tests. Experimental results showed that for the same magnitude of preload and the vacuum pressure of 4, 8, 16 and 30 kPa, the settlement caused by the vacuum pressure is lower than that generated by the preload, while the settlements generated by preloads of 60 and 100 kPa are slightly lower than those caused by vacuum pressure of 60 and 100 kPa. A rapid dissipation of recorded excess pore water pressure around the geodrain was observed compared to that measured close to the cell border. 相似文献