Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Understanding the behavior of Prometheus and Pandora

We revisit the dynamics of Prometheus and Pandora, two small moons flanking Saturn's F ring. Departures of their orbits from freely precessing ellipses result from mutual interactions via their 121:118 mean motion resonance. Motions are chaotic because the resonance is split into four overlapping components. Orbital longitudes were observed to drift away from predictions based on Voyager ephemerides. A sudden jump in mean motions took place close to the time at which the orbits' apses were antialigned in 2000. Numerical integrations reproduce both the longitude drifts and the jumps. The latter have been attributed to the greater strength of interactions near apse antialignment (every 6.2 yr), and it has been assumed that this drift-jump behavior will continue indefinitely. We re-examine the dynamics of the Prometheus-Pandora system by analogy with that of a nearly adiabatic, parametric pendulum. In terms of this analogy, the current value of the action of the satellite system is close to its maximum in the chaotic zone. Consequently, at present, the two separatrix crossings per precessional cycle occur close to apse antialignment. In this state libration only occurs when the potential's amplitude is nearly maximal, and the “jumps” in mean motion arise during the short intervals of libration that separate long stretches of circulation. Because chaotic systems explore the entire region of phase space available to them, we expect that at other times the Prometheus-Pandora system would be found in states of medium or low action. In a low action state it would spend most of the time in libration, and separatrix crossings would occur near apse alignment. We predict that transitions between these different states can happen in as little as a decade. Therefore, it is incorrect to assume that sudden changes in the orbits only happen near apse antialignment.     

Origin of chaos in the Prometheus-Pandora system

We demonstrate that the chaotic orbits of Prometheus and Pandora are due to interactions associated with the 121:118 mean motion resonance. Differential precession splits this resonance into a quartet of components equally spaced in frequency. Libration widths of the individual components exceed the splitting, resulting in resonance overlap which causes the chaos. Mean motions of Prometheus and Pandora wander chaotically in zones of width 1.8 and 3.1 deg yr⁻¹, respectively. A model with 1.5 degrees of freedom captures the essential features of the chaotic dynamics. We use it to show that the Lyapunov exponent of 0.3 yr⁻¹ arises because the critical argument of the dominant member of the resonant quartet makes approximately two separatrix crossings every 6.2 year precessional cycle.     

Microwave observations of Saturn's rings: anisotropy in directly transmitted and scattered saturnian thermal emission

We present a new Very Large Array (VLA) image of Saturn, made from data taken in October 1998 at a wavelength of λ3.6 cm. The moderate ring opening angle (B≈15°) allows us to explore direct transmission of microwave photons through the A and C rings. We find a strong asymmetry of photons transmitted through the A ring, but not in the C ring, a new diagnostic of wake structure in the ring particles. We also find a weak asymmetry between east and west for the far side of the ansae. To facilitate quantitative comparison between dynamic models of the A ring and radio observations, we extend our Monte Carlo radiative transfer code (described in Dunn et al., 2002, Icarus 160, 132-160) to include idealized wakes. We show the idealized model can reproduce the properties of dynamic simulations in directly transmitted light. We examine the model behavior in directly transmitted and scattered light over a range of physical and geometric wake parameters. Finally, we present a wake model with a plausible set of physical parameters that quantitatively reproduces the observed intensity and asymmetry of the A ring both across the planet and in the ansae.     

The Magnetospheric cusps: A Summary

The polar cusps of the magnetosphere are key regions for the transfer of mass, momentum, and energy from the solar wind into the magnetosphere. Understaning these key regions and the dynamical interactions that occur there are fundamentally important to determining the physical nature of the magnetosphere. In this paper we try to summarize many of the conclusions reached in the papers of this special issue emphasizing the present concepts and definition of the cusp, what variations could be temporal structures and what could be spatial structures. We address the need for further measurements and the role of present and planned projects to address these needs.     

High-Altitude CUSP: The Extremely Dynamic Region in Geospace

The high-altitude dayside cusps (both northern and southern) are extremely dynamic regions in geospace. Large diamagnetic cavities with significant fluctuations of the local magnetic field strength have been observed there. These cusp diamagnetic cavities are always there day after day and are as large as 6 R_E Associated with these cavities are charged particles with energies from 20 keV up to 10 MeV. The intensities of the cusp energetic ions have been observed to increase by as much as four orders of the magnitude when compared with regions adjacent to the cusp which includes the magnetosheath. Their seed populations are a mixture of ionospheric and solar wind particles. The measured energetic ion fluxes in the high-altitude cusp are higher than that in both the regions upstream and downstream from the bow shock. Turbulent electric fields with an amplitude of about 10 mV/m are also present in the cusp, and a cusp resonant acceleration mechanism is suggested. The observations indicate that the dayside high-altitude cusp is a key region for transferring the solar wind mass, momentum, and energy into the Earth’s magnetosphere.     

Very quiet intervals of geomagnetic activity and the solar wind structure

Extended periods of very low geomagnetic activity as described by very quiet intervals (VQI's) occur only at those times when the solar wind velocityV has a generally decreasing trend, i.e., they mainly occur either after the velocity peak of a high speed solar stream has passed the Earth, or at times when the Earth is immersed in a low speed solar plasma provided that the daily mean value ofdV/dt is negative. The VQI's most frequently start whendV/dt<0 anddB _Z/dt>0 (B _Z is the geocentric solar magnetrospheric-GSMZ-component of the IMF) and end most likely whendV/dt>0 anddB _Z/dt<0. The temporal trends of the solar wind (SW) velocity affect the variation of thea _p index only when the level of geomagnetic activity is generally low.It is suggested that a gradual expansion or contraction of the magnetosphere, associated with a slow variation of the SW pressure, plays a role in the modification of the reconnection-driven magnetohydrodynamic (MHD) fluctuations in the magnetosphere.     

延庆、怀来地区地壳深部磁性构造与地震的研究

应用三维磁性层反演理论和方法，对延庆、怀来地区航磁资料进行了数据处理，反演计算了该区磁性基底埋深、居里等温面埋深和视磁化强度分布。揭示了延庆盆地、矾山盆地、怀来盆地、涿鹿盆地等四个相互联通盆地的磁性基底的定量特征。对该区地震发生的深部原因和地壳内不同特性块体与地震的关系进行了探讨；对该区地震分布的特点进行了研究；初步提出了该区地震的危险区划和今后的重点监测区。     

1998年5月磁暴磁层电流体系的地磁效应分析

低纬度地区地磁场的短时变化主要由以下电流体系产生:电离层发电机电流(IDC)、对称环电流(SRC)以及由部分环电流和Ⅱ区场向电流及其电离层回路组成的内磁层三维电流体系(PRFI).此外,由Ⅰ区场向电流及其电离层回路组成的电流体系(FACI)所产生的低纬地磁场也是不可忽略的.本文针对1998年5月1-6日的大磁暴,首先利用多个同子午线台站对的数据分离并消去由IDC电流产生的Sq场.然后,通过线性建模分离其他电流体系产生的磁场成分.结果表明:(1)发生在5月1-6日的磁暴可以分为两个过程,PRFI和FACI电流体系在1-3日不明显,在4-5日伴随着亚暴强烈发生.(2)SRC的变化情况在第一阶段同Dst指数相似,在第二阶段明显滞后于Dst指数.(3)在5月4-5日,PRFI在SRC之前增强,随着PRFI和FACI的恢复,SRC开始增强.这一结果为我们了解环电流和场向电流的形成以及它们的关系提供线索.     

Naturally Enhanced Ion-Acoustic Spectra And Their Interpretation

Incoherent scatter radars are designed to detect scatter from thermalfluctuations in the ionosphere. These fluctuations contain, among other things,features associated with ion-acoustic waves driven by random motions within theplasma. The resulting spectra are generally broad and noisy, but neverthelessthe technique can, through a detailed analysis of spectra, be used to measure arange of physical parameters in the Earth's upper atmosphere, and provides apowerful diagnostic in studies of magnetosphere-ionosphere coupling,thermosphere dynamics and the geospace environment in general. In recent yearsthere has been much interest in naturally occurring (as opposed to artificiallystimulated) enhanced ion-acoustic spectra seen in the auroral zone andcusp/cleft region. A study of the plasma instability processes that lead tosuch spectra will help us to better understand auroral particle acceleration,wave-particle and wave-wave interactions in the ionosphere, and theirassociation with magnetospheric processes. There is now a substantial body ofliterature documenting observations of enhanced ion-acoustic spectra, but thereremains controversy over generation mechanisms. We present a review ofliterature documenting observations of naturally enhanced ion-acoustic spectra,observed mainly along the geomagnetic field direction, along with a discussionof the theories put forward to explain such phenomena.