The role of organic matter in the sorption capacity of marine sediments

Past studies have suggested that desiccation enhances hydrophobicity of salt marsh sediment, and that drying and rewetting sediment can be used to investigate sorption mechanisms of amino acids and other organic compounds [Liu, Z., Lee, C., 2006. Drying effects on sorption capacity of coastal sediment: The importance of architecture and polarity of organic matter. Geochim. Cosmochim. Acta 70, 3313–3324]. Here we further develop this technique to study sorption of hydrophobic and hydrophilic organic compounds in a wide range of marine sediments. Our results show that hydrophilic compounds sorb strongly to wet coastal sediments; in dried sediments, sorption of hydrophilic compounds decreases, while sorption of hydrophobic compounds is greatly enhanced. Small compounds with aromatic rings sorb more in dried than wet coastal sediments, suggesting that aromatic groups have a stronger effect on sorption than polar groups like amino and carboxyl moieties. Sorption of lysine, glutamic acid and putrescine decreases greatly when sediment is pretreated with KCl, indicating the importance of cation ion exchange. However, α-amino acids sorb much more than corresponding β- or γ-amino acids, and l-alanine sorbs more than d-alanine, suggesting that amino group location and chiral selectivity play an important role in sorption. Comparison of lysine and tyrosine sorption in different sediments indicates that source and diagenetic state of organic matter are important factors determining sorption capacity. Lysine sorbs much more to organic detritus from salt marsh sediment than to fresh Spartina root materials, marine particles, lignin or humic acids, indicating the importance of structural integrity in sorption. Desorption hysteresis of glutamic acid, putrescine and lysine (in dried sediment) suggests the presence of enzyme-type sorption sites of high sorption energy or multiple binding mechanisms. Taken together, these findings suggest that organic matter plays the major role in amino acid sorption in organic-rich sediments.     

Limits on the chirality of interstellar and intergalactic space

We raise the question of whether velocities of left and right circularly-polarized photons might be different (for reasons other than the well-known Faraday effect). Such a difference could manifest itself either in the time profiles of pulsed or bursting astronomical sources or in the rotation of the direction of polarization of linearly polarized radiation from them. The existing observations of pulsars, gamma ray bursters, and quasar jets are used to set limits to the difference in speed, between 10^-17and 10^-32     

Spiral Galaxies as Chiral Objects?

Spiral galaxies show axial symmetry and an intrinsic 2D-chirality. Environmental effects can influence the chirality of originally isolated stellar systems and a progressive loss of chirality can be recognized in the Hubble sequence. We point out a preferential modality for genetic galaxies as in microscopic systems like aminoacids, sugars or neutrinos. This feature could be the remnant of a primordial symmetry breaking characterizing systems at all scales.     

Chiral Property of Spiral and Barred Spiral Galaxies in the Local Supercluster

We present an analysis of the chiral property of 667 spiral and barred spiral galaxies in the Local Supercluster (radial velocity <3 000 km s⁻¹). The arms of a galaxy (spiral or barred spiral) can be distinguished according to their orientation (leading or trailing) relative to the direction of the rotation. We use environment of each galaxy as a subsample in order to study the chiral property of galaxies. In addition, equatorial position angle distributions of leading and trailing arm galaxies are studied. We classify our database according as their morphology, diameters, radial velocities, axial ratios and magnitudes. The distribution of trailing and leading arm galaxies in the Local Supercluster is found homogeneous. A significant dominance of either trailing or leading structures is noticed within the Virgo cluster region, suggesting that the aggregation of these structures might have already started there. The rotation axes of the galaxies in the Virgo cluster is found to lie in the equatorial plane. Chirality of galaxies is found strong for the subsamples that showed a random alignment in the equatorial position angle distribution. Possible explanations of the results will be presented.