纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

航空重力测量数学模型及其测量精度分析

基于数学和分析力学角度分别推导了航空矢量重力测量的数学模型,得到了一致的模型公式;给出了矢量模型的3个分量形式,其中垂直方向的分量就是标量重力测量的数学模型;简要介绍了我国研制成功的航空标量重力测量系统CHAGS的数据处理的过程,分析了标量重力测量中测线交叉点和重复测线的重力异常的精度;根据实测数据计算的结果表明:测线交叉点重力异常不符值的标准差约为5×10-5ms-2左右,重复测线的内符合精度优于5×10-5ms-2,达到了预期的要求。     

丽江7.0级地震重力前兆模式研究<

为了研究1996年丽江MＳ7.0地震前地震孕育过程或前兆表现，利用滇西地震实验场内高精度重复重力观测数据，结合地质调查和地球物理推断结果，并考虑到观测数据和模型粗差， 采用稳健或抗差-贝叶斯最小二乘算法和多断层位错模型，首次初步反演获得了研究区主要活动断裂滑动的时间变化分布．结果表明，1990～1997年断层运动的时间变化，较好地反映了1996年丽江MＳ7.0地震孕育过程．其主要前兆模式图象具有主震余震型特征，遵循地壳内部密度和地壳形变耦合运动模式（简称DD耦合运动模式）．      

Population genetic diversity and structure of a dominant tropical seagrass,Cymodocea rotundata,in the Western Pacific region

Cymodocea rotundata is an ecologically important tropical pioneer seagrass species distributed in the Indo‐Pacific region. The population genetic diversity and structure of this species were analysed at 46 sites spanning the Philippines, Ryukyu Islands (northern limit) and Hainan Island, by using microsatellite simple sequence repeat (SSR) markers. Analyses revealed the persistence of C. rotundata likely relies on local population dynamics and fitness influenced by environmental gradients, with sexual reproduction prevalent in the Philippines while the Ryukyu and Hainan populations were predominantly established by clonal spread. Analysis of molecular variance showed significant genetic differentiation (P < 0.001) among three geographic regions: the Philippines, Ryukyu and Hainan. Furthermore, the mean fixation index value was very high (F_ST = 0.36), indicating poor dispersal potential or limited gene flow. Allelic richness and heterozygosity of C. rotundata was comparable in the Philippines and Ryukyu Islands populations. More private alleles were found in the Philippines and excess heterozygotes in the Ryukyu Islands. STRUCTURE analysis revealed that the Ryukyu and Hainan populations were mosaics of admixed alleles of individuals from the Philippines. An assignment test suggested that recruitment occurs from the Northeast Philippines to Ryukyu Islands. These results suggest that the Philippine populations are tropical seagrass hotspots and perhaps the origin of the populations in the Ryukyu and Hainan Islands. This scenario is most likely driven by the Kuroshio Current and island integration events during plate tectonic activities. The Philippine Archipelago is considered of high importance for conservation objectives and management plan of seagrasses. Likewise, the Ryukyu Islands are also important in terms of conserving regional diversity because locally adapted genotypes have important evolutionary potential in the face of environmental change.     

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特种监测网解算中IGS站选取的探讨

利用GAMIT/GLOBK软件处理2011年特种监测网的观测数据,将IGS站的选取分10种方案进行试验,计算结果从基线长度变化、测站坐标、NRMS、基线重复率等方面进行了比较。得出利用GAMIT/GLOBK软件处理该特种监测网时的几点建议:建议选取IGS站为GPS网提供参考框架;IGS站选取的数量不一定最多,但空间上应尽量均匀分布;选取7个IGS站时得到较高精度的结果。在日后处理此类型的特种监测网时对IGS站选取具有一定的参考价值。     

太平洋鳕鱼脑中硫苷脂的分离纯化和分析

以太平洋鳕鱼为原料,从鳕鱼脑中分离硫苷脂,确立了提取及纯化的条件,并对硫苷脂的纯度和分子种进行分析。首先,采用氯仿/甲醇(2∶1,v/v)提取总脂。然后,依次采用氯仿/甲醇/水(7∶3∶0.3,v/v/v)洗脱硅胶柱层析,含0.2mol/L乙酸铵的氯仿/甲醇/水(30∶60∶8,v/v/v)洗脱DEAE Sephadex-A25离子交换柱层析,40%甲醇脱盐和100%甲醇洗脱反相C8柱层析,获得硫苷脂纯品。最后,利用500YMC Diol液相色谱柱(3.0mm×250mm,5μm)分离,以正己烷/异丙醇(70∶30,v/v),异丙醇/水/甲酸/氨水(100∶13∶1∶0.14,v/v/v/v)为流动相梯度洗脱,采用负电喷雾电离(ESI)和母离子扫描模式,用液相色谱-串联质谱(LC-MS/MS)法分析了鳕鱼脑硫苷脂的纯度和分子种组成,并比较了其与哺乳动物脑中硫苷脂分子种组成的异同。结果表明,本实验制得的鳕鱼脑硫苷脂纯度为90.74%,与哺乳动物类似,鳕鱼脑硫苷脂的长链碱基以鞘氨醇为主,主要分子种为d18∶1-C24∶1,但脂肪酸的羟基化程度略低,且含少量独特的分子种,如d18∶1-22∶1和d18∶2-25∶2。     

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基于星载激光测高估计南极冰盖高程变化

利用NSIDC公布的ICESat运行期间的19个任务期的观测数据, 采用重复轨迹分析方法估计近年来南极冰盖高程的时空变化。结果表明,南极大陆冰盖整体上呈现消融趋势,基于不同的GIA模型和ICESat激光测高数据的南极大陆冰盖高程变化的趋势约为 -1.17~-1 cm/a。     

Numerical study of an oscillating smaller cylinder in the wake of an upstream larger cylinder

A numerical study of flow around two tandem cylinders with unequal diameters was carried out. The upstream larger cylinder was fixed and the downstream smaller cylinder was allowed to oscillate in the transverse direction only. Comparisons of the experimental and numerical results were made to investigate the effects of the gap ratio on the maximum vibration amplitude and vortex shedding frequency. The results showed that the vibration response of the smaller cylinder was significantly affected by the presence of the upstream larger cylinder, and resulted in greatly reduced vibration amplitudes. With an increasing gap ratio, the vibration amplitude increased. However, the magnitude was lower than that corresponding to a single cylinder (with the same diameter as that of the downstream smaller cylinder) under the same flow conditions.