碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

几丁糖酯原料药稳定性研究

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好     

真鲷早期发育阶段行为生态学研究

真鲷Pagrosomus major Temminck et Schlegel早期发育阶段游泳行为的发育可以分为:(1)旋转式运动;(2)阶梯型运动;(3)间断式水平运动和滑翔;(4)巡游以及(5)疾游五种类型。前期仔鱼的摄食方式主要是伴有甩头动作的前冲摄食;后期仔鱼的摄食主要有两种类型:一种是身体弯成S形的“S攻击型”;另一种为不作摄食姿势的“咬食攻击型”。摄食方式随着发育水平和饵料种类的不同而异。文中对发育过程中出现的攻击行为、护食行为、互食行为、猝死现象亦进行了描述。并对游泳、摄食以及各种行为的生态意义和实际意义进行了讨论。     

Jason-1: Assessment of the System Performances

On 7 December 2001, Jason-1 was successfully launched by a Boeing Delta II rocket from the Vandenberg Air Force Base, California. The Jason-1 satellite will maintain the high accuracy altimeter service provided since 1992 by TOPEX/Poseidon (T/P), ensuring the continuity in observing and monitoring the Ocean Dynamics (intraseasonal to interannual changes, mean sea level, tides, etc.). Despite one-fourth the mass and power, the Jason-1 system has been designed to have basically the same performance as T/P, measuring sea surface topography at a centimetric level. This new CNES/NASA mission also provides near real-time data for sea state and ocean forecast. The first two months of the Jason-1 mission have been dedicated to the assessment of the overall system. The goals of this assessment phase were:

1. To assess the behavior of the spacecraft at the platform and payload levels (Jason-1 being the first program to call on the PROTEUS versatile multimission platform for Low and Medium Earth Orbit Missions developed in partnership between Alcatel Space and CNES);

2. To verify that platform performance requirements are met with respect to Jason-1 requirements;

3. To verify that payload instruments performance requirements evaluated at instrument level are met;

4. To assess the performance of the Jason-1 Ground System.

This article will display the main outputs of the assessment of the system. It will demonstrate that all the elements of the onboard and ground systems are within the specifications. Provision of data to the Jason-1 Science Working Team started at the end of March 2002. This is the goal of a six-month phase after closure of the initial assessment phase to derive the error budget of the system in terms of altimetry user products.     

大亚湾水域两种拟菱形藻的形态学鉴定及毒素分析

对2005年分离自广东大亚湾的两种潜在产毒拟菱形藻进行了形态学观察和毒性分析.通过透射电子显微镜(TEM)观察确认藻种为细弱拟菱形藻(Pseudo-nitzschia cuspidata)和多纹拟菱形藻(P.multistriata).采用高效液相色谱法(HPLC)对这两种藻的常规培养样进行软骨藻酸毒素检测,结果均未检测到软骨藻酸.鉴于以上两种拟菱形藻存在着潜在产毒特性,不同培养条件的诱导实验尚需继续.     

An Electronic Chart Display and Information System

This article introduces the most advanced form of electronic chart display and information systems (ECDIS) which complies with the performance standards for ECDIS established by the International Maritime Organization (IMO) and International Hydrographic Organization (IHO). It also describes the key features and the important functions of ECDIS, which we developed. This system is different from the productions developed by C-map, Seven-cs, offshore, and others. It is more suitable for China Marine Safety Administration Bureau to manage the navigation marks real-time. Using this system charts were located and accessed rapidly, and displayed smoothly. This article also discusses in ECDIS application system how to dynamically access and desert charts data in a limited memory (limited computer memory and resource). We constructed a tridimensional structure to manage a large amount of charts data. Vertically, according to the scale range, all charts were divided into eight levels, and a data structure called as “Multiple Scale Quad-tree” was constructed. And horizontally, a grid (every unit has a fixed size) was given to a certain scale level. We call this data structure a “Regular Page.” We explore the implementation of such a structure on the worldwide charts management utilizing quad-trees. Then we discuss the future development of ECDIS and its application system in marine agencies in China.