全文获取类型
收费全文 | 463篇 |
免费 | 65篇 |
国内免费 | 144篇 |
专业分类
测绘学 | 1篇 |
大气科学 | 52篇 |
地球物理 | 144篇 |
地质学 | 241篇 |
海洋学 | 140篇 |
天文学 | 7篇 |
综合类 | 29篇 |
自然地理 | 58篇 |
出版年
2024年 | 9篇 |
2023年 | 8篇 |
2022年 | 19篇 |
2021年 | 24篇 |
2020年 | 26篇 |
2019年 | 24篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 18篇 |
2015年 | 28篇 |
2014年 | 25篇 |
2013年 | 52篇 |
2012年 | 20篇 |
2011年 | 24篇 |
2010年 | 25篇 |
2009年 | 17篇 |
2008年 | 25篇 |
2007年 | 31篇 |
2006年 | 39篇 |
2005年 | 24篇 |
2004年 | 22篇 |
2003年 | 22篇 |
2002年 | 19篇 |
2001年 | 12篇 |
2000年 | 20篇 |
1999年 | 19篇 |
1998年 | 17篇 |
1997年 | 13篇 |
1996年 | 7篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 1篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有672条查询结果,搜索用时 15 毫秒
1.
Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate 总被引:1,自引:0,他引:1
Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery. 相似文献
2.
Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong 总被引:1,自引:0,他引:1
QIAN Jianping LI Shuangli and CAO Chao Guilin University of Technology Guilin China 《中国地球化学学报》2008,(1)
Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model.. 相似文献
3.
本文对北京延庆(116.0°E,40.5°N)钠荧光激光雷达2018年11月—2019年12月夜间的数据以1 h和1 km的时空分辨率进行了分析.获得了当地钠层上边界可达到的高度范围、其相应的季节变化、夜间演化等:延庆顶部钠层可达到110 km、120 km和130 km的概率分别为99.94%、84.46%和40.34%,由此得出,顶部钠层在大多数情况下可以达到120 km,突破了顶部钠层在105 km(或者110 km)的传统观点;上边界高度范围的季节变化规律为5—6月份最高,2—3月份最低;后半夜顶部钠层密度会有所增加.我们比较了偶发钠层、温度和流星注入与上边界高度范围的相关性,推测出偶发钠层对钠层上边界拓展有很大贡献,流星注入次之,温度影响最低.后半夜流星注入量增多跟此时顶部钠层密度增加有一定的相关性.对顶部钠层能够提高到120 km的这项研究,可以为拓展风温的探测高度提供理论依据.
相似文献4.
喀斯特适生植物固碳增汇策略 总被引:5,自引:1,他引:4
通过分析喀斯特地区的土壤化学性质,明确了喀斯特地区植物的固碳增汇的限制因素为岩溶干旱、低营养、高pH、高重碳酸盐等.通过对喀斯特适生植物和非适生植物的无机碳源、氮源的利用以及对低营养的响应差异分析,总结出了喀斯特适生植物交替、高效利用碳酸氢根离子作碳源的开源固碳增汇策略,以较低的营养成本获取较高的光合固碳能力的低成本倍增固碳增汇策略,以及掠夺式吸收限制性的铵态氮和补偿式吸收硝态氮来实现固碳增汇作用的以氮增汇策略等;提出了喀斯特适生植物固碳增汇能力的利用途径,可最大限度挖掘出喀斯特地区植物的固碳增汇潜能. 相似文献
5.
Algal organic materials (AOMs) are one critical factor affecting the efficiency of modified clays used for the mitigation of harmful algal blooms (HABs). This study was conducted to develop a deeper understanding of the mechanisms and factors affecting the adsorption of AOMs onto modified clays. Sodium alginate (polysaccharide) and kaolinite modified with polyaluminium chloride (PACl) were used as AOMs and modified clay model substances, respectively, and the effects of modifier dosage, contact time, solution pH and ionic strength were investigated through batch adsorption experiments. Kinetics revealed that the alginate adsorption rate was described well by a pseudo-second order model. PACl effectively enhanced the adsorption capacity of kaolinite and increased the adsorption rate, and the optimum additive amount of PACl was 5%. The experimental data fitted both the Freundlich and Langmuir adsorption equations well. The adsorption thermodynamics for alginate onto modified clays suggests that alginate adsorption is a spontaneous process. The adsorption of alginate onto modified clays was highly dependent on pH, with a decrease in adsorption observed with increased pH to 9.48, but the opposite was true above pH 9.48. Finally, adsorption increased with increasing ionic strength. 相似文献
6.
7.
8.
本研究利用铵锌镉还原法将海水、湖水和自来水水体中硝酸盐转化为N2O气体测试氮、氧同位素, 结果表明当反应体系的pH值在6~8之间, NO3-还原为NO2-的转化率大于95%, NO2-还原为N2O的转化率大于99%。配置5种丰度的硝酸盐氮、氧同位素标样, 将实验结果与理论值绘制校准曲线, 氮同位素校准曲线斜率为0.48, 相关性良好(R2=0.999 8), 5种丰度δ15NN2O标准偏差在0.18‰~0.43‰之间(n=5);氧同位素校准曲线斜率为0.70, 相关性良好(R2=0.999 6), 5种丰度δ18ON2O标准偏差在0.27‰~0.46‰之间(n=5)。铵锌镉还原法与镉柱还原法测定硝酸盐氮、氧同位素结果的精密度和准确度一致, 同时海水、湖水和自来水3种不同类型水样的硝酸盐氮、氧同位素测试数据满足实验要求, 而且在实验流程的简洁性和高效性方面更具优势。 相似文献
9.
Wei JIANG Xinqing LEE 《中国地球化学学报》2006,25(B08):12-12
Nitrogen cycle is an important bio-geochemical process in the environment. Measurement of the total nitrogen (TN) is a routine experiment in agriculture, biology and environmental sciences. The Kjeldahl method (KM) and elemental analyzer method (EA) are both commonly used to determine TN. Total nitrogen by EA is the sum of nitrate (NO3), nitrite (NO2), organic nitrogen and ammonia. Total nitrogen by KM (TKN) is made up of both organic nitrogen and ammonia. A comparative study focused on the two methods is conducted by analysis of TN in 97 samples from the sediment sequence of Gouchi, a salt lake in North China. KM presents a higher degree of accuracy than EA with a standard deviation of 0.007 vs. 0.024. With the presence of nitrate and/or nitrite nitrogen, however, measurement by KM is considerably lower than that by EA. Therefore, for samples from lake sediment sequences or soils in North China, KM is inapplicable to determining TN because of usually high contents of nitrous salt. Despite the inconsistency, use of both methods to the same samples makes sense in reconstructions of climatic and environmental changes from lake sediments. In Lake Gouchi, the contents of nitrate and nitrite nitrogen vary from 1.40% in the lower part of the sequence to 14.77% in the uppermost part, suggesting a gradual evolution process from a fresh water lake to the present-day salt lake. 相似文献
10.