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1.
Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for
total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability
of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8
(1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg−1, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were
not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%,
respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb
(39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated
soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3,
40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably
decline in the following order: Cd = Pb > Ni > Cu > Zn. 相似文献
2.
Regional distribution pattern of groundwater heavy metals resulting from agricultural activities 总被引:18,自引:0,他引:18
Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study
was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural
activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions
of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely
used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km2 between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions
A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004.
The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples
and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that
in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However,
the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were
more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural
activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the
environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and
groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of
the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants. 相似文献
3.
4.
5.
R. Danovaro N. Della Croce A. DellAnno A. Pusceddu 《Deep Sea Research Part I: Oceanographic Research Papers》2003,50(12):1411-1420
The Atacama trench, the deepest ecosystem of the southern Pacific Ocean (ca. 8000 m depth) was investigated during the Atacama Trench International Expedition. Sediments, collected at three bathyal stations (1040–1355 m depth) and at a hadal site (7800 m) were analyzed for organic matter quantity and biochemical composition (in terms of phytopigments, proteins, carbohydrates and lipids), bacterial abundance, biomass and carbon production and extracellular enzymatic activities. Functional chlorophyll-a (18.0±0.10 mg m−2), phytodetritus (322.2 mg m−2) and labile organic carbon (16.9±4.3 g C m−2) deposited on surface sediments at hadal depth (7800 m) reached concentrations similar to those encountered in highly productive shallow coastal areas. High values of bacterial C production and aminopeptidase activity were also measured (at in situ temperature and 1 atm). The chemical analyses of the Atacama hadal sediments indicate that this trench behaves as a deep oceanic trap for organic material. We hypothesize that, despite the extreme physical conditions, benthic microbial processes might be accelerated as a result of the organic enrichment. 相似文献
6.
黑河流域水资源系统演变和人类活动影响 总被引:4,自引:0,他引:4
黑河流域降水集中于山区,平原稀少。50多年来,除了20世纪70—80年代上游的中东部地区降水偏多外,其它区域为正常变化;蒸发量从山区向平原逐渐增大,除了中游蒸发量显示稳定变化外,山区和下游区表现为减少趋势;黑河多年出山径流量呈现稳定变化,但在中下游盆地间的正义峡水文站,径流量自20世纪80年代中期以来,出现了非常明显的减少过程:这是受到中游地区地下水开采量增加、补给量减少和水位下降的影响,主要是中游地区人口数量增多、大规模扩耕灌溉和水工建设作用的结果。计算表明,人类活动影响强度:20世纪50年代占18%,60—70年代占28%,80—90年代占54%;上游占1%,中游占87%,下游占12%。这说明黑河中游80—90年代是人类活动影响强度达到最大的地区。因此,提出了充分认识流域水资源系统演变规律性,约束人类活动的影响,均衡保护利用流域水资源的有关建议。 相似文献
7.
Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted,
we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental
changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive
eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago.
The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass
mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China.
__________
Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报] 相似文献
8.
Environmental and health risk assessment in abandoned mining area, Zlata Idka, Slovakia 总被引:1,自引:0,他引:1
The Zlata Idka village is a typical mountainous settlement. As a consequence of more than 500 years of mining activity, its environment has been extensively affected by pollution from potentially toxic elements. This paper presents the results of an environmental-geochemical and health research in the Zlata Idka village, Slovakia. Geochemical analysis indicates that arsenic (As) and antimony (Sb) are enriched in soils, groundwater, surface water and stream sediments. The average As and Sb contents are 892 mg/kg and 818 mg/kg in soils, 195 mg/kg and 249 mg/kg in stream sediments, 0.028 mg/l and 0.021 mg/l in groundwater and 0.024 mg/l and 0.034 mg/l in surface water. Arsenic and Sb concentrations exceed upper permissible limits in locally grown vegetables. Within the epidemiological research the As and Sb contents in human tissues and fluids have been observed (blood, urine, nails and hair) in approximately one third of the village’s population (120 respondents). The average As and Sb concentrations were 16.3 μg/l and 3.8 μg/l in blood, 15.8 μg/l and 18.8 μg/l in urine, 3,179 μg/kg and 1,140 μg/kg in nails and 379 μg/kg and 357 μg/kg in hair. These concentrations are comparatively much higher than the average population. Health risk calculations for the ingestion of soil, water, and vegetables indicates a very high carcinogenic risk (>1/1,000) for as content in soil and water. The hazard quotient [HQ=average daily dose (ADD)/reference dose (RfD)] calculation method indicates a HQ>1 for groundwater As and Sb concentrations. 相似文献
9.
10.
人类活动对黄河中游高含沙水流的影响 总被引:7,自引:2,他引:7
以黄河中游干流和渭河、无定河的资料研究了人类活动对黄土高原河流高含沙水流的发生频率的影响。人类破坏森林植被,大量拦截黄河上游清水来源区的清水基流,使得高含沙水流发生频率增大,大规模水土保持措施的实施则使高含沙水流发生频率迅速减小。近50年来黄河干流和一些支流的高含沙水流随时间的变化可以用一个三阶段模式来概括,即20世纪50-60年代,由于人类破坏植被,使高含水流频率增大;20世纪60年代末至80年代中期,大规模水土保持措施的实施使高含沙水流发生的频率减小;20世纪80年代末期以来,人类大量拦截利用清水资源,使高含沙水流的发生频率又复增大。 相似文献