华南石炭纪中期白云岩地层分布及其形成模式

石炭纪是地质演化历史上重要的时期,发生了全球规模的海西造山运动,晚古生代大冰期（LPIA）达到峰值,全球海平面频繁波动,导致古气候和古环境的剧烈变化。在华南,石炭纪中期,浅水碳酸盐岩台地相区广泛发育一套白云岩沉积。本文系统总结华南3个主要碳酸盐台地内白云岩的厚度及时代,识别出白云岩时空分布的差异性。结合石炭纪中期全球气候环境特征,认为冰期兴盛引发了全球海平面下降,导致华南各沉积盆地形成利于白云岩化的环境,白云岩得以发育。而白云岩时空分布的差异性可能与各沉积盆地独特的构造演化以及不同成岩模式有关。中下扬子碳酸盐岩台地白云岩的形成模式主要为萨勃哈模式和成岩早期浅埋藏的渗透回流模式,形成相对较薄的白云岩沉积;中南部和西南部碳酸盐岩台地白云岩的形成模式为渗透回流模式,成岩规模较大,沉积较厚。     

白云岩成因相关问题及主要形成模式

在综述白云岩成因研究历程和最新成果的基础上,总结阐述了与之相关的4个方面的问题:①尽管白云岩原生沉淀与次生交代成因分歧依旧,但越来越多的证据表明白云岩的形成以次生交代为主;②白云石难以直接沉淀的原因是受结晶动力学条件制约,而非热力学因素;③控制次生交代强度和规模的关键条件是富Mg流体的来源及其量的大小;④微生物活动很可能有助于白云岩的形成。关于白云岩化模式,其核心是构建富Mg流体与先成钙质碳酸盐岩相互作用的条件与场所,其中浓缩正常海水模式、萨布哈模式、混合水模式和埋藏白云岩化模式等具有一定的普遍性。理清白云岩成因问题,对于认识以白云岩及其相关的碳酸盐岩为储层的油气勘探工作尤为重要。     

川中地区中二叠统栖霞组滩控岩溶型白云岩储层特征及主控因素

四川盆地中部地区栖霞组的白云岩是该区主要储层,储层成因的主流观点是热液白云岩化.目前勘探实践发现,优质储渗体形成与早期相控岩溶作用有关.通过取芯及测录井资料进行了详细分析,研究结果表明,该类白云岩储层主要位于栖霞组中上部颗粒滩发育的地层中,按其宏微观产出状态可分为溶斑状云岩、溶洞充填云岩、针孔状基质云岩和致密基质云岩....     

江西修水二叠系-三叠系界线地层树枝状微生物岩状岩石成因初解

江西修水二叠系-三叠系界线地层有一段特殊构造的地层，下部为灰色部分和红色部分组成的斑状构造，上部为灰色部分和黄色部分组成的树枝状构造。这种树枝状构造的岩石与前人报道自重庆老龙洞剖面的微生物岩非常相似。岩石薄片观察表明，树枝状构造的暗色部分为残留的灰泥岩；浅色部分为灰岩经过重结晶、白云石化去白云石化作用改造而成。在暗色的残留灰岩里有保存很好的丰富的球状微生物化石。研究认为，岩石中暗色部分和浅色部分的原始组分是同时沉积的；是成岩作用控制了浅色部分的形成。这一成果应当对认识老龙洞剖面树枝状微生物岩的成因有借鉴作用。     

Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.     

Application of numerical modelling to a case of compaction-driven dolomitization: a Jurassic palaeohigh in the Po Plain, Italy

Dolomitization of a carbonate platform can occur at different times and in different diagenetic environments, from synsedimentary to deep burial settings. Numerical simulations are valuable tools to test and select the model that, among different hypotheses compatible with field and geochemical data, best honour mass balance, kinetic and thermodynamic constraints. Moreover, the simulation can predict the distribution of the dolomitized bodies in the subsurface and evaluate porosity changes; valuable information for the oil industry. This study is the first attempt to reproduce and investigate the compaction dolomitization model. The diagenetic study of the Jurassic carbonate basin and palaeohigh system of the Po Plain indicates that the carbonates of the palaeohighs were dolomitized by basin compaction fluids. The main goal of the simulations is to evaluate the origin and evolution of the dolomitizing fluids and to provide insights regarding the distribution of the potential reservoir‐dolomitized bodies in the Po Plain. The modelling process is subdivided into two steps: basin modelling and reactive transport modelling. The SEBE3 basin simulator (Eni proprietary) was used to create a three‐dimensional model of the compacting system. The results include compaction fluid flow rate from the basin to the palaeohigh, compaction duration and a determination of the total amount of fluid introduced into the palaeohigh. These data are then used to perform reactive transport modelling with the TOUGHREACT code. Sensitivities on dolomite kinetic parameters suggest that dolomitization was an efficient process even at low temperatures, with differences mainly related to the dynamics of the process. Fluid composition is one of the main constraints, the sea water derived compaction fluid is proven to be efficient for dolomitization due to its relatively high Mg content. Simulations also confirmed that permeability is the most important factor influencing fluid flow and, consequently, the dolomite distribution in the formation. Permeable fractured zones have a strong influence, diverting the dolomitizing fluids from their normal path towards overlying or lateral zones. Moreover, the simulations showed that, after dolomite replacement is complete, the dolomitizing fluids can precipitate dolomite cement, causing over‐dolomitization, with related localized plugging effects in the zone of influx. Mass balance calculations indicate that in the dolomitization compaction model, the amount of compaction water fluxed from the basin to the carbonate is the main constraint on dolomitization efficiency. This observation implies that the ratio between the volume of the basin undergoing compaction and the volume of the palaeohigh is a limiting factor on the final size of the dolomitized bodies. An isolated palaeohigh could be an ideal site for pervasive replacement dolomitization due to the large volume of compaction fluids available compared with the carbonate rock volume. In the case of large platforms, the more permeable margin lithofacies are the most likely sites for compaction model dolomitization. The combined use of a basin simulator and reactive transport modelling has proved to be a successful method to verify model reliability and it provides insights into the volumetric distribution of diagenetic products.     

塔里木盆地东部地区寒武系-奥陶系白云岩特征及成因

通过对塔东低凸起带寒武系-奥陶系白云岩的岩石学特征、碳氧同位素特征、锶同位素比值特征、有序度等的分析,认为塔东地区带寒武系-奥陶系准同生阶段的泥-粉晶白云岩由受潮汐作用的海水泵汲作用形成;成岩阶段的细-中晶白云岩、粗-巨晶白云岩是在埋藏成岩环境中经过调整白云岩化以及成岩后期的外来热液作用引起的埋藏热液白云岩化作用形成。     

全球二叠系顶部白云岩与沉积相关系统计及其白云石化机制的意义

本文对全球范围内23个典型的研究程度较高的晚长兴期露头进行了研究,逐一检查了晚长兴期白云岩前身沉积的沉积相,结果发现所有白云岩的前身都是浅水相的(除汉中梁山一个剖面外)。相反,目前已经研究的深水相上二叠统碳酸盐沉积物都没有发生白云岩化。这一结果表明,世界范围内上二叠统顶部白云岩的形成机制可能都与海平面下降有关,很可能是蒸发成因的浓缩卤水使沉积物发生白云岩化。据此推断,四川盆地东北部长兴组白云岩也应当是此种成因。     

四川宣汉盘龙洞长兴组白云岩组构定向与统计特征及其成因意义

四川盆地东北部发育的长兴组礁滩相白云岩层是油气勘探的重点对象,盘龙洞剖面是四川盆地发育最好的长兴组露头,其成岩作用研究对于认识川东北长兴组储层的形成演化控制因素具有很强的借鉴作用。白云岩的组构和产状包含了成因信息,笔者根据薄片观察发现白云石交代结构可分为"均一"与"不等晶"交代两种类型,过渡关系与阴极发光观察结果均表明细中晶是由粉晶发育而来的,且细中晶白云石具"组构定向"现象。首次对该地区白云岩的组构进行了定量统计。统计结果表明,细中晶白云石粒径大小和含量在纵向上有明显的变化规律,含量自上而下减少、粒径变小。结合成岩作用、流体包裹体、阴极发光研究结果综合分析后认为:白云石化作用开始于成岩早期,白云化流体具有低温、高盐度的特点,白云化流体自上而下运移。     

鄂尔多斯盆地南部奥陶系马六段白云岩特征及形成机制研究

鄂尔多斯盆地马六段在盆地大部分地区被剥蚀,仅在盆地周缘地区分布,因此,有关该盆地马六段白云岩成因研究较少。本文通过对马六段白云岩岩石学特征、阴极发光特征、微量元素特征以及碳氧同位素地球化学特征进行分析,对鄂尔多斯盆地南部马六段白云岩特征及形成机制进行了研究。研究结果表明,盆地南部马六段白云岩主要由细—中晶白云岩组成,白云石具"雾心亮边"结构,阴极发光呈暗红色光。微量元素总体上具有较低的Fe、Mn值,平均值分别为447×10~(-6)和62×10~(-6),较高的K、Na值,平均值分别为517×10-6和252×10~(-6),以及中等含量的Sr元素值,平均值为155×10~(-6)。δ~(13)C值平均为-0.617‰,δ~(18)O值平均为-7.6‰,以上特征均反映出海源流体特征。白云石的"雾心"和"亮边"结构中微量元素含量相差不大,认为是在相同成岩环境的不同成岩阶段形成,其中"雾心"形成于浅埋藏环境的渗透回流白云石化作用,而"亮边"是在深埋藏环境下对早期白云石的调整和加强。