Effect of emersion and immersion on the porewater nutrient dynamics of an intertidal sandflat in Tokyo Bay

Porewater nutrient dynamics during emersion and immersion were investigated during different seasons in a eutrophic intertidal sandflat of Tokyo Bay, Japan, to elucidate the role of emersion and immersion in solute transport and microbial processes. The water content in the surface sediment did not change significantly following emersion, suggesting that advective solute transport caused by water table fluctuation was negligible. The rate of change in nitrate concentration in the top 10 mm of sediments ranged from −6.6 to 4.8 μmol N l⁻¹ bulk sed. h⁻¹ during the whole period of emersion. Steep nutrient concentration gradients in the surface sediment generated diffusive flux of nutrients directed downwards into deeper sediments, which greatly contributed to the observed rates of change in porewater nutrient concentration for several cases. Microbial nitrate reduction within the subsurface sediment appeared to be strongly supported by the downward diffusive flux of nitrate from the surface sediment. The stimulation of estimated nitrate production rate in the subsurface layer in proportion to the emersion time indicates that oxygenation due to emersion caused changes in the sediment redox environment and affected the nitrification and/or nitrate reduction rates. The nitrate and soluble reactive phosphorus pools in the top 10 mm of sediment decreased markedly during immersion (up to 68% for nitrate and up to 44% for soluble reactive phosphorus), however, this result could not be solely explained by molecular diffusion.     

Numerical study of the meridional overturning circulation with “mixing hotspots” in the Pacific Ocean

Using an idealized ocean general circulation model, we examine the effect of “mixing hotspots” (localized regions of intense diapycnal mixing) predicted based on internal wave-wave interaction theory (Hibiya et al., 2006) on the meridional overturning circulation of the Pacific Ocean. Although the assumed diapycnal diffusivity in the mixing hotspots is a little larger than the predicted value, the upwelling in the mixing hotspots is not sufficient to balance the deep-water production; out of 17 Sv of the downwelled water along the southern boundary, only 9.2 Sv is found to upwell in the mixing hotspots. The imbalance as much as 7.8 Sv is compensated by entrainment into the surface mixed layer in the vicinity of the downwelling region. As a result, the northward transport of the deep water crossing the equator is limited to 5.5 Sv, much less than estimated from previous current meter moorings and hydrographic surveys. One plausible explanation for this is that the magnitude of the meridional overturning circulation of the Pacific Ocean has been overestimated by these observations. We raise doubts about the validity of the previous ocean general circulation models where diapycnal diffusivity is assigned ad hoc to attain the current magnitude suggested from current meter moorings and hydrographic surveys.     

Screening Effect of the Diffusive Boundary Layer in Sediments of Lake Aha in the Suburbs of Guiyang City,Guizhou Province

The redox cycle of iron and manganese is a major geochemica process at the boundary layers of lake sediments.Lake Aha,which lies in the suburbs of Guiyang City,Guizhou Province,China,is a medium-sized artificial reservoir with seasonally anoxic hypolimnion,Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments,In the anoxic season,Fe^2 and Mn^2 ,formed by diological oxidation,would diffuse up to overlying waters from sediments.However,the concentration of oxidation,would diffuse up to overlying waters from sediments,However,the concentration of Fe^2 increased later and decreased earlier than that of Mn^2 .Generally,sulfate reduction occurred at 6 cm below the sediment-water interface.Whereas,in the anoxic season.the reduction reached upper sediments,inhibiting the release of Fe^2 ,The Fe concentration of anoxic water is quickly decreased from high to low as a result of reduction of the suplhur system.     

Hydrogen sulfide measurements in air by passive/diffusive samplers and high-frequency analyzer: A critical comparison

In this study, hydrogen sulfide (H₂S) measurements in air carried out using (a) passive/diffusive samplers (Radiello^® traps) and (b) a high-frequency (60 s) real-time analyzer (Thermo^® 450i) were compared in order to evaluate advantages and limitations of the two techniques. Four different sites in urban environments (Florence, Italy) and two volcanic areas characterized by intense degassing of H₂S-rich fluids (Campi Flegrei and Vulcano Island, Italy) were selected for such measurements. The concentrations of H₂S generally varied over 5 orders of magnitude (from 10⁻¹–10³ μg/m³), the H₂S values measured with the Radiello^® traps (H₂S_R) being significantly higher than the average values measured by the Thermo^® 450i during the trap exposure (H₂S_Ta), especially when H₂S was <30 μg/m³. To test the reproducibility of the Radiello^® traps, 8 passive/diffusive samplers were contemporaneously deployed within an 0.2 m² area in an H₂S-contaminated site at Mt. Amiata (Tuscany, Italy), revealing that the precision of the H₂S_R values was ±49%. This large uncertainty, whose cause was not recognizable, is to be added to that related to the environmental conditions (wind speed and direction, humidity, temperature), which are known to strongly affect passive measurements. The Thermo^® 450i analyzer measurements highlighted the occurrence of short-term temporal variations of the H₂S concentrations, with peak values (up to 5732 μg/m³) potentially harmful to the human health. The Radiello^® traps were not able to detect such temporal variability due to their large exposure time. The disagreement between the H₂S_R and H₂S_Ta values poses severe concerns for the selection of an appropriate methodological approach aimed to provide an accurate measurement of this highly toxic air pollutant in compliance with the WHO air quality guidelines. Although passive samplers may offer the opportunity to carry out low-cost preliminary surveys, the use of the high-frequency H₂S analyzer is preferred when an accurate assessment of air quality is required. In fact, the latter provides precise real-time measurements for a reliable estimation of the effective exposure to hazardous H₂S concentrations, giving insights into the mechanisms regulating the dispersion of this air pollutant in relation to the meteorological parameters.     

ANALYTICAL HAYAMI SOLUTION FOR THE DIFFUSIVE WAVE FLOOD ROUTING PROBLEM WITH LATERAL INFLOW

The diffusive wave equation is generally used in flood routing in rivers. The two parameters of the equation, celerity and diffusivity, are usually taken as functions of the discharge. If these two parameters can be assumed to be constant without lateral inflow, the diffusive wave equation may have an analytical solution: the Hayami model. A general analytical method, based on ‘Hayami’s hypothesis, is developed here which resolves the diffusive wave flood routing equation with lateral inflow or outflow uniformly distributed over a channel reach. Flood routing parameters are then identified using observed inflow and outflow and the Hayami model used to simulate outflow. Two examples are discussed. Firstly, the prediction of the hydrograph at a downstream section on the basis of a knowledge of the hydrograph at an upstream section and the lateral inflow. The second example concerns lateral inflow identification between an upstream and a downstream section on the basis of a knowledge of hydrographs at the upstream and downstream sections. The new general Hayami model was applied to flood routing simulation and for lateral inflow identification of the River Allier in France. The major advantages of the method relate to computer simulation, real-time forecasting and control applications in examples where numerical instabilities, in the solution of the partial differential equations must be avoided.     

Element diffusion ability in metasomatic agents and its effect on chemical characteristics of metasomatized peridotites

The partial melting and metasomatism are two most important geological processes of changing chemical compositions of mantle. Extracting partial melt from primitive mantle leads residual mantle to deplete in- compatible elements, whereas the metasomatism …     

Ion acceleration and Alfvén wave generation at the Earth’s bow shock

The processes of ion acceleration and Alfvén wave generation by accelerated particles at the Earth’s bow shock are studied within a quasi-linear approach. Steady-state ion and wave spectra are shown to be established in a time of 0.3–4 h, depending on the background level of Alfvénic turbulence in the solar wind. The Alfvén waves produced by accelerated ions are confined within the frequency range 10^?2–1 Hz and their spectral peak with a wave amplitude βB ～ B comparable to the interplanetary magnetic field strength B corresponds to the frequency v = (2–3) × 10^?2 Hz. The high-frequency part of the wave spectrum (v > 0.2 Hz) undergoes damping by thermal ions. The calculated spectra of the accelerated ions and the Alfvén waves generated by them reproduce the main features observed in experiments.     

长江口沉积物-水界面砷的迁移转化机制与微生物调控分析

为探析长江口沉积物-水界面砷的迁移转化机制,本文分析了2019年夏季长江口4个站位上覆水和间隙水中总As浓度及形态的剖面变化特征,耦合氧化还原敏感元素(Fe、Mn和S)的剖面变化剖析了沉积物-水界面砷循环的Fe-Mn-S控制机制,同时结合砷相关功能基因探讨了沉积物-水界面砷迁移转化的微生物调控过程,估算了沉积物-水界面总As的扩散通量。结果表明,除A7-4站位外,长江口其他3个站位间隙水总As以As³⁺为主要存在形态,且总As浓度均在上覆水中为最低值(0.748~1.57 μg·L^-1),而在间隙水中随着深度增加而逐渐增加并在6~9 cm深度达到峰值(7.14~26.9 μg·L^-1)。间隙水总As及As³⁺浓度的剖面变化趋势与溶解态Fe²⁺、Mn²⁺相似,其均在中间层出现高值,说明沉积物Fe/Mn还原带砷的释放可能是随固相Fe(Ⅲ)或Mn(Ⅳ)的还原而转移到间隙水中的。氧化层和Fe/Mn还原带过渡区间隙水砷浓度与砷异化还原菌功能基因arrA和arsC丰度存在对应关系(除A1-3站外),说明砷异化还原菌将溶解As⁵⁺或固相As⁵⁺还原为溶解As³⁺可能是该过渡层砷迁移转化的另一重要过程。硫酸盐还原带的间隙水总As和As³⁺浓度降低,但由于间隙水的低S^2-浓度不利于砷硫化物生成,因此深层间隙水砷可能与铁硫矿物结合而被移除。底层环境氧化还原条件是影响沉积物-水界面砷迁移转化的重要因素,随底层水DO浓度的降低,砷迁移转化更倾向于微生物还原控制。长江口沉积物-水界面总As的扩散通量为1.18×10^-7~2.07×10^-7 μmol·cm^-2·s^-1,均表现为沉积物间隙水中总As向上覆水释放,即沉积物是研究区域水体总As的来源之一。     

Long‐term annual surface heat and water balances over Canada and the United States South of 60°N: Reconciliation of precipitation,run‐off and temperature fields

Abstract

The analysis compares the observed field of run‐off (assumed correct) with adjusted precipitation over North America (as amended by den Hartog and LeDrew over Canada) and derives the principal hydroclimatological ratios for each five‐degree latitude‐longitude square. The amended precipitation field yields values of the Budyko dry ness index close to values suggested by the vegetation distribution. The Priestley‐Taylor parameter, α, lies between unity (equilibrium) and potential (1.26) values over much of humid North America, but exceeds these values in the northwest Pacific squares, where advective heating may be the cause. Other regions of strong seasonal advective heating (e.g. the Great Plains) do not appear to influence the distribution strongly. A weighted convective forcing temperature is derived, varying from 298 K in the extreme south to below 285 K in the north. This function (and the Bowen ratio) achieve improbable values in northern Labrador‐ Ungava. The precipitation, run‐off and net radiation régimes appear still to be out of balance in these squares. An adjustment of either precipitation or net radiation by about a tenth corrects the imbalance, but the method is not capable of deciding which field (or both) is in error. Over the rest of the continent the adjusted precipitation field now appears to be in balance with observed run‐off and temperature distributions.     

中天山坡地冰缘地貌的若干问题

由 1985—1989年野外调查结果和定位重复观测资料可知,本区坡地冰缘地貌的分布特征为:1.各类坡地冰缘形态彼此具有成因联系;2.不同序次的冰缘地貌类型具有各自的时空分异;3.不同的坡地冰缘地貌类型在一定条件下可有所转化。再则,本区风化以寒冻剥裂和寒冻楔入为主,呈现在时空和状态上为不可逆过程的耗散结构。