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An oxide gold ore was subjected to chloride/hypochlorite leaching at room temperature. The effects of three factors, including Ca(OCl)2 vs. NaOCl, OCl− concentration, and HCl concentration on gold leaching performance were investigated. Due to formation of CaOCl+ complex in solution and hence less reactivity, calcium hypochlorite produces a sluggish gold leaching kinetics, taking twice the time (46 h) to achieve maximum gold recovery of 58% compared to sodium hypochlorite. 10 g/L of total initial hypochlorite species in solution produces reasonable gold recoveries. The amount of added HCl and hence the initial pH was found to have a major effect on gold leaching kinetics and maximum gold recovery. A high level of 9 g/L of added HCl causes HClO to be very reactive, producing very fast kinetics, reaching 67% gold extraction in 4 h. It also causes a faster consumption of hypochlorous acid, through catalytic decomposition (by NiO and CuO) and disproportionation. Hypochlorous acid reactions with sulfide and ferrous content of ore proceed very slowly in the pH range of 4–11. Gold–chloro complexes are strongly adsorbed on quartz component of ore. To minimize this undesirable adsorption of gold–chloro species, the aging time must be limited to a few hours only. 相似文献
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南极冬季威德尔海海冰物理结构与叶绿素a垂直分布特征 总被引:2,自引:1,他引:1
2006年8-10月极星号ANT/XXⅢ-7航次,对南极威德尔海西北海域浮冰区进行海冰综合考察,采用海冰物理学、海冰化学和海冰生态学等多学科现场同步观测取样与分析研究新方法。结果显示,测区21个冰站不同冰龄和不同结构类型的海冰冰芯,叶绿素a含量总平均值为16.56μg/dm3,范围为2.10~84.40μg/dm3,叶绿素a相对总量的R值均值为0.79~0.83。冰体叶绿素a含量与分布取决于海冰冰晶物理结构及其所处冰层部位,并和海冰生成环境、冰体发育和成冰过程密切相关。研究结果证实南极冬季海冰叶绿素a含量普遍处于较高水平,海冰冰藻具有较强活性,由此表明从整体上南极冬季海冰具有较高初级生产能力。这对正确分析估算冬季南极海洋生物生产,重新评估南大洋碳通量及其在全球气候变化中的贡献,具有重要科学意义。 相似文献
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本文对华北半叶紫菜丝状体细胞的凋亡过程进行了初步观察并对这一过程中细胞超微形态的变化进行了研究。结果表明 ,丝状体细胞的凋亡过程是由分枝的端部细胞发生老化开始的 ,老化细胞的细胞内壁增厚 ;细胞核内染色质凝缩 ,核膜溶解 ;色素体片层结构变形、溶解 ;红藻淀粉电子密度显著下降 ,逐渐解体 ;胞浆中出现不规则形态的囊泡、髓样结构和结构特殊的小体 ;随着细胞的趋于凋亡 ,核、色素体、线粒体等细胞器相继溶解消失 ,细胞结构崩溃 ,细胞内壁明显增厚。细胞中的囊泡和髓样结构参与了细胞内壁的形成。本研究首次报道紫菜中存在细胞凋亡 ,并对丝状体细胞凋亡过程的生物学意义及髓样结构的功能进行了讨论 相似文献
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