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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
利用内蒙古西部12个台站的地脉动噪声数据,采用噪声谱比法研究台站的场地响应情况。分析表明,台站场地响应按曲线形态可分为3类,且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现,场地响应曲线形态基本一致,只有极少数台站存在明显差异。结果表明,内蒙古西部区域大部分台站的台基状况总体较好,场地响应曲线较为平坦,无明显频率放大点。 相似文献
3.
Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation. 相似文献
4.
A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars. 相似文献
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6.
GPS/LEO掩星观测的变分同化技术 总被引:6,自引:0,他引:6
在简单介绍GPS/LEO掩星探测大气的发展历史和科学意义之后,详细阐述了反演的基本原理;分析了标准反演中存在的问题,并说明一维变分同化(1DVAR)在反演方法中的重要性;给出了一维变分同化中价值函数的求解,以及各种同化因子;简单介绍了对当前气象学中普遍使用的四维变分同化(4DVAR);重点讨论了各种同化方法,以及使用各种同化因子的优缺点。最后,通过CHAMP卫星的观测实例分析,验证了GPS数据在数值天气预报(NWP)中的作用,以及相对于标准反演法一维变分对气象要素的改进。 相似文献
7.
In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K2 O, Ca/(Ca + Na)rock and FeOtot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H2 O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB. 相似文献
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H
8.
D. Montes M. C. Gálvez M. J. Fernández-Figueroa I. Crespo-Chacón 《Astrophysics and Space Science》2006,304(1-4):367-369
High resolution echelle spectroscopic observations taken with the FEROS spectrograph at the 2.2 m telescope ESO confirm the binary nature of the flare M3.5V star LU Vel (GJ 375, RE J0958-462) previously reported by Christian and Mathioudakis (2002). Emission of similar intensity from both components is detected in the Balmer, Na i D1&D2, He i D3, Ca ii H&K, and Ca ii IRT lines. We have determined precise radial velocities by cross correlation with radial velocity standard stars, which have allowed us to obtain for the first time the orbital solution of the system. The binary consists of two near-equal M3.5V components with an orbital period shorter than 2 days. We have analyzed the behaviour of the chromospheric activity indicators (variability and possible flares). In addition, we have determined its rotational velocity and kinematics. 相似文献
9.
The SAS® computer software system, widely used and respected for its capabilities in statistical analysis and data base management, now includes a new set of graphic and cartographic procedures called SAS GRAPH?. We have used these cartographic procedures in research on mapping ethno-cultural census data from metropolitan areas in Ontario and in undergraduate and graduate courses in computer cartography. On the basis of that experience, we describe and evaluate SAS/GRAPH'S cartographic capabilities and illustrate with maps drawn by various devices. 相似文献
10.
针对多通道滤光器太阳磁场望远镜的磁场观测定标及掌握(所采用的)谱线特征之需要,取VAL宁静太阳大气模型计算了7条Fel光球线的Stokes轮廓、形成深度、贡献函数分布,从而较为系统地对多条反常及正常Zeeman线的特征及性质作出了分析与总结,解释了在磁光效应影响下Stokes Q,U参量的形成深度曲线在近线心区域处出现陡峭峰值的原因。 相似文献