Chemical oceanographic influences on sediment accumulations of a carbonate ramp: Holocene Yucatan Shelf,Mexico

Global controls on the oceanographic influences on the nature of carbonate factories are broadly understood. The details of the influences of changes in temperature and nutrients across individual carbonate shelves are less well constrained, however. This study explores spatial and temporal variations in chemical oceanography along and across the Yucatan Shelf, a modern carbonate ramp, and how these factors relate to variable bottom character, sediment and sediment geochemistry. In‐situ sensors and remote‐sensing data indicate the sporadic presence of cool, upwelled water with low dissolved oxygen and elevated Chlorophyll‐a. This current‐driven, westward flow of upwelled water is most evident in a zone just offshore of the northern peninsular shoreline, but its influence wanes ca 75 km offshore and as the shore turns southward. The impacts of this water mass include a transitional photozoan–heterozoan assemblage with biosiliceous components, relict grains and common thin Holocene sediment accumulations nearshore; further offshore are coralgal reefs and expansive sand plains. Geochemical proxies of bulk sediment, including high δ¹⁸O and elevated HREE/LREE (heavy rare‐earth element/light rare‐earth element) ratios near, and downcurrent of, the upwelling source, are interpreted to represent the signal of nearshore, westward movement of the cool and nutrient‐rich, upwelled water. Collectively, these data emphasize how local processes such as upwelling and longshore transport can variably influence carbonate sediment accumulations and their geochemical signatures, both along and across individual shelves. These data and insights provide an analogue for the influences of spatial variability of water masses in the geological record, and for accurate interpretation of stratigraphic changes of sedimentary and geochemical proxy data in carbonate archives.     

Post-drilling destabilization of temperature profile in borehole Yaxcopoil-1, Mexico

As part of the International Continental Scientific Drilling Program (ICDP), the 1.5-km-deep borehole Yaxcopoil-1, located in the Chixculub meteor impact structure in Mexico, has undergone further study after drilling operations ceased. Temperature logs were repeated ten times at intervals 0.3–0.8, 15, 24 and 34 months after borehole shut-in. The logs bear a distinct signature of transient heat transfer by groundwater flow manifested by a gradual distortion of the linear temperature profile when a cold wave of 0.8–1.6°C amplitude was detected propagating downward from 145 to 312 m at a rate of 4–6 m/month. To understand the nature of this moving anomaly, a 20-day monitoring of the cold wave was carried out at a depth of 307 m that showed further cooling of 0.6°C during the first 16 days of the passage followed by temperature stabilisation. As an explanation of this unusual phenomenon, a theory is proposed, whereby the drilling mud has accumulated within the overlying and cooler highly porous and permeable karstic rocks during the drilling and migrates downward. The observed migration rate suggests a permeability higher than 10^?11 m². This indicates a high vulnerability to contamination of the only freshwater aquifer in the Yucatan region.     

Dynamic of the freshwater–saltwater interface in a karstic aquifer under extraordinary recharge action: the Merida Yucatan case study

A hydraulic analysis of the interface between freshwater–saltwater behavior was done in the Merida Yucatan zone, two machines that constantly register the groundwater levels were installed, and three electric conductivity logs were taken from wells. When comparing the measured results with the ones obtained using theoretical equations developed to calculate the freshwater–saltwater interface position, it was proved that in some cases these equations can be applied, and in others not. Two effects that rule the behavior of karst aquifers in extraordinary conditions were found.     

Dispersion in the Yucatan coastal zone: Implications for red tide events

The mechanisms governing dispersion processes in the northern Yucatan coast are investigated using a barotropic numerical model of coastal circulation, which includes wind-generated and large scale currents (i.e. Yucatan Current). This work provides the foundations for studying the dispersion of harmful algal blooms (HABs) in the area. Modelling experiments include effects of climatic wind (from long term monthly mean NCEP reanalysis), short term wind events (from in situ point measurements), and Yucatan Current (YC) characteristics. Its magnitude was approximated from published reports, and its trajectory from geostrophic current fields derived from altimeter data. These provided a range of real and climatic conditions to study the routes in which phytoplankton blooms may travel. The 2-D model results show that a synthetic and conservative bloom seeded in the Cabo Catoche (CC) region (where it usually grows), moves along the coast to the west up to San Felipe (SF), where it can either move offshore, or carry on travelling westwards. The transport to the west up to SF is greatly influenced by the trajectory, intensity and proximity of the YC jet to the peninsula, which enhances the westward circulation in the Yucatan Shelf. Numerical experiments show that patch dispersion is consistently to the west even under the influence of northerly winds. When the YC flows westward towards the Campeche Bank, momentum transfer caused by the YC jet dominates the dispersion processes over wind stress. On the other hand, when it flows closer to Cuba, the local processes (i.e. wind and bathymetry) become dominant. Coastal orientation and the Coriolis force may be responsible for driving the patch offshore at SF if external forcing decreases.     

Organic carbon inputs,common ions and degassing: rethinking mixing dissolution in coastal eogenetic carbonate aquifers

Caves deliver freshwater from coastal carbonate landscapes to estuaries but how these caves form and grow remains poorly understood. Models suggest fresh and salt water mixing drives dissolution in eogenetic limestone, but have rarely been validated through sampling of mixing waters. Here we assess controls on carbonate mineral saturation states using new and legacy geochemical data that were collected in vertical profiles through three cenotes and one borehole in the Yucatan Peninsula. Results suggest saturation states are primarily controlled by carbon fluxes rather than mixing. Undersaturation predicted by mixing models that rely on idealized end members is diminished or eliminated when end members are collected from above and below actual mixing zones. Undersaturation due to mixing is limited by CO₂ degassing from fresh water in karst windows, which results in calcite supersaturation. With respect to saline groundwater, controls on capacity for mixing dissolution were more varied. Oxidation of organic carbon increased pCO₂ of saline groundwater in caves (pCO₂ = 10^–2.06 to 10^–0.96 atm) relative to matrix porosity (10^–2.39 atm) and local seawater (10^–3.12 atm). The impact of increased pCO₂ on saturation state, however, depended on the geochemical composition of the saline water and the magnitude of organic carbon oxidation. Carbonate undersaturation due to mixing was limited where gypsum dissolution (Cenote Angelita) or sulfate reduction (Cenote Calica) increased concentrations of common ions (Ca²⁺ or HCO₃^?, respectively). Maximum undersaturation was found to occur in mixtures including saline water that had ion concentrations and ratios similar to seawater, but with moderately elevated pCO₂ (Cenote Eden). Undersaturation, however, was dominated by the initial undersaturation of the saline end member, mixing was irrelevant. Our results add to a growing body of literature that suggests oxidation of organic carbon, and not mixing dissolution, is the dominant control on cave formation and enlargement in coastal eogenetic karst aquifers. Copyright © 2016 John Wiley & Sons, Ltd.     

Water management by early people in the Yucatan,Mexico

The Yucatan Peninsula is a coastal plain underlain by permeable limestone and receives abundant rainfall. Such hydrogeologic conditions should provide major supplies of water; however, factors of climate and hydrogeology have combined to form a hydrologic system with chemical boundaries that limits the amount of fresh water available. Management of water resources has long had a major influence on the cultural and economic development of the Yucatan. The Mayan culture of the northern Yucatan developed on extensive use of groundwater. The religion was water oriented and the Mayan priests prayed to Chac, the water god, for assistance in water management, primarily to decrease the severity of droughts. The Spaniards arrived in 1517 and augmented the supply by digging wells, which remained the common practice for more than 300 years. Many wells now have been abandoned because of serious problems of pollution. A historical perspective of a paper such as this provides insight into the attitudes concerning water of early people and perhaps provides insight into current attitudes concerning water. Hydrogeologists possess the expertise to generate relevant information required by water managers to arrive at management programs to achieve sustainable development.     

An alternative Pangea reconstruction for Middle America with the Chortis Block in the Gulf of Mexico: tectonic implications

Understanding Pangea breakup requires a robust reconstruction, and this article focuses on the Middle America sector of the supercontinent. Although most Pangean reconstructions locate the Yucatan Block along the southern USA, the Chortis Block is generally placed off southern Mexico (Pacific model), undergoing sinistral relative motion during the Mesozoic and Cenozoic. However, the Pacific model is inconsistent with the absence of a Cenozoic fault linking the Cayman transforms and the Middle America Trench. We present an alternative Pangean reconstruction, where both the Yucatan and Chortis Blocks are placed in the future Gulf of Mexico, moving Mexico westwards along the Mojave–Sonora megashear to accommodate overlap with South America. Subsequent Mesozoic and Cenozoic evolution is inferred to have occurred in two stages: (i) Jurassic clockwise rotation along the Mojave–Sonora and West Florida megashears, followed by (ii) Cenozoic anticlockwise rotation along the Sierra Madre Oriental and East Yucatan megashears. The first stage is linked to the breakup of Pangea where the Gulf of Mexico formed as a pull-apart basin. The second stage is related to the evolution of the Caribbean where the Chortis and Yucatan Blocks rotated into the trailing side of the Caribbean Plate (pirate model). The new reconstruction is consistent with major parameters, such as (i) gravity, magnetic, and palaeomagnetic data; (ii) the westward continuation of the Cayman transform faults through the Chiapas foldbelt and along the N–S front of the Sierra Madre Oriental foldbelt; (iii) the 27–19 Ma removal of the southern Mexican forearc; (iv) offset of the Cretaceous volcanic arc (Guerrero-Suina); (v) the deflection of the Laramide orogen (Sierra Madre Oriental–Zongolica–Colon); and (vi) the continuity of Cretaceous platformal carbonates containing Caribbean fauna across Middle America. In this latter context, the Motagua high-pressure belt is interpreted as a Cretaceous extrusion zone into the upper plate above a subduction zone rather than as an oceanic suture.     

Benthic community response to habitat variation: A case of study from a natural protected area,the Celestun coastal lagoon

Little information currently exists on spatial and temporal benthic community variations in tropical coastal lagoons. Here, the benthic community response to habitat variation in the Celestun coastal lagoon, northwest Yucatan peninsula, was seasonally examined during the 1994–1995 climatic cycle into a grid of 12 sampling sites distributed along the salinity gradient of the lagoon. Habitat variation was assessed through physical factors associated both to the water column (e.g. salinity) and the bottom sediment (e.g. sand, silt and clay fractions). The benthic community response was assessed through species diversity measures and abundance. Under the influence of climatic seasonality, variations in habitat conditions followed by changes in the benthic community characteristics were expected. Results from two-way ANOVAs showed that for the period of study, Celestun lagoon was more heterogeneous along the spatial axis of variability than along the temporal one. Multiple regression analysis showed that salinity was spatially the main factor influencing the benthic community characteristics. Temporally, the sediment characteristics were observed to exert significant effects on the species diversity characteristics but not on abundance. Other variables assessed (dissolved oxygen, pH, temperature and water column transparency) exhibited no significant covariance with species diversity and abundance. Since generated from historical data, these results have the potential to be useful as a benchmark to the establishment of monitoring programs in the light of the increasing anthropogenic pressure on the natural resources of the lagoon and surrounding coastal area.     

Experiencing agricultural failure: Internal migration, tourism and local perceptions of regional change in the Yucatan

In response to a growing body of literature encouraging geographers to present textured, regional case studies that demonstrate how neoliberalism functions at diverse scales, this article presents a nuanced account of neoliberalism in Mexico’s Yucatan peninsula. The study seeks to illustrate how neoliberal reforms to agriculture and ongoing neoliberal tourism development in the Yucatecan state of Quintana Roo intersect to create a unique regional context for migration between the state’s rural areas and Mexico’s largest planned tourism development zone in Cancun. The research presented is based on a series of in-depth qualitative interviews that took place in 2003 with rural residents and regional migrants working in Cancun. Through the employment of an experiential definition of neoliberalism, grounded in the lived experiences and perceptions of study participants, the article suggests that rural-urban tourist pole migration is the result of a complex negotiation of the region’s neoliberal landscape. The article argues that rural residents’ and migrants’ perceptions of the failure of agriculture as a livelihood is shaped relative to the perceived success of the tourism industry and better livelihood opportunities in Cancun. These widespread perceptions of agricultural failure in the Yucatan peninsula are constructed not solely in response to local conditions but rather in response to the overall regional outcome of neoliberal economic restructuring initiatives which have negatively affected traditional agriculture in the rural sphere while privileging tourism development in the urban sphere centered in Cancun.