水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。     

粘土矿物去除赤潮生物的动力学研究

于１９９２年４－９月进行粘土矿的絮凝赤潮生物（微型原甲藻）的动力学研究；考察粘土种类、浓度、第二组分（ＰＡＣＳ）和ＰＨ等因素对絮凝速率的影响，建立粘土矿物絮凝赤潮生物的动力学模型，从理论上分析和讨论各种因素的影响，并提出提高絮凝速率的方法和途径。结果表明，高岭土体系絮凝速率大于蒙脱土体系，其速率方程可用双分子反应来描述。其中，速率常数随絮凝过程发生变化；粒子间的相互作用能和作用半径是控制和影响絮凝     

Characterization of Estuarine Marine Clays for Coastal Reclamation in Pusan, Korea

Large scale reclamation works in coastal areas of the Nakdong River plain are at various stages of progress, since early 1990's on in-situ soft marine clay deposits. These deposits are of the order of 30 to 40 m thick. A realistic rapid characterization of soft ground would ensure success of any reclamation work in this area. In order to cope with the work carried out with different agencies, it is desirable to evolve a systematic methodology. In this study, engineering properties of clays at three coastal areas, Gadukdo, Noksan and Shinho, have been generated. The analysis of data has been done within the framework of classical developments in soil mechanics. Analysis has also been made by making use of the recent developments in dealing with soft clays. The dominant factors, namely, stress, time, and environment influencing the response of clay to loading are identified.     

Effects of ageing and overconsolidation on the elastic stiffness of a remoulded clay

Summary Results of resonant column tests were used to determine values of low amplitude shear modulus (G ₀) of a remoulded kaolinite clay for different durations of ageing and for different values of consolidation stress (₀) and overconsolidation ratio (OCR). It was found that after completion of primary consolidation the values of G ₀ increased linearly with the logarithm of time and after a week of confinement the value of normalized rate of secondary increase of shear modulus (N _G ) could be reliably estimated. Values of N _G were found to derease linearly with the logarithm of OCR and with the logarithm of ageing duration. This similarity of behaviour provided a basis for establishing an equivalency between age and equivalent overconsolidation ratio (OCR)_eq. The effects of ₀ and OCR on the value of G ₀ were also established in a functional form that indicated a stronger influence compared to that predicted by the Hardin Equation.     

Nature minéralogique et rôle nutritionnel des argiles de sols céréaliers en région subhumide à semi-aride (Tunisie)

The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca⁺⁺, Mg⁺⁺ and K⁺ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).     

Stress induced time dependent behavior of clayey soils

It is shown that time compression curve obtained from one-dimensional consolidation curve in the laboratory may include six phases. These are initial compression, first primary compression, transition from first primary compression to second primary compression, second primary compression, and transition from second primary compression to creep and lastly creep. This paper attempts to identify the quantitative beginnings and characteristics of these phases. A mathematical characteristic of all the soils that follow primary consolidation as per Terzaghi’s one dimensional consolidation theory is derived. It is known as the constant of primary consolidation. It is used to study the beginning of secondary consolidation and its effects on primary consolidation. Another characteristic of soils for creep and total absence of primary compression is derived. Methods are suggested for the determination of coefficients of Primary and Secondary consolidations and the compression index.     

New method for in situ characterization of loose material for landslide mapping purpose

The assessment of grain size distribution and plasticity of loose geological material, during in situ geological investigations, is not obvious. Visual appreciation allows an approximative quantification of the coarse granulometric fractions, but not of the fine ones. Field soils determination methods suggested until now, are visual and tactile tests leading to a very rough estimate, which is only qualitative and not very reproducible. The new proposed field test (GEOLEP method) allows a quick quantification of the fine fraction of loose material. It allows the determination of the sand fraction (fine and medium grained sands) as well as the methylene blue value of the samples. The necessary equipment to perform this test is light and compact and the time needed to analyze one sample is approximately 15 min. Thus it is also possible to carry out numerous measurements in one day. The calibrations were carried out on a selection of 13 natural samples, chosen for their representativeness of the typical alpine quaternary deposits. The results obtained with GEOLEP method are relevant compared with standardized laboratory tests; the obtained correlation indexes are of 73% for the comparison with laboratory stain test results and of 89% with a laboratory method using a similar procedure than the field test. The correlation we performed with Atterberg's limits tests shows that a rough approximation of plasticity index can also be obtained (R² = 75%). This method thus brings a new tool which should allow taking into account the lithological factor (by some quantitative and representative variables) in a reliable way for the evaluation of landslide hazards.     

Numerical estimation of effective diffusion coefficients for charged porous materials based on micro-scale analyses

In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.     

A simple prediction model for wall deflection caused by braced excavation in clays

Deep excavations particularly in deep deposits of soft clay can cause excessive ground movements and result in damage to adjacent buildings. Extensive plane strain finite element analyses considering the small strain effect have been carried out to examine the wall deflections for excavations in soft clay deposits supported by retaining walls and bracing. The excavation geometry, soil strength and stiffness properties, and the wall stiffness were varied to study the wall deflection behavior. Based on these results, a simple Polynomial Regression (PR) model was developed for estimating the maximum wall deflection. Wall deflections computed by this method compare favorably with a number of field and published records.     

Experimental study of the sublimation of ice through an unconsolidated clay layer: Implications for the stability of ice on Mars and the possible diurnal variations in atmospheric water

We have studied the sublimation of ice and water vapor transport through various thicknesses of clay (<63 μm grain size). We experimentally demonstrate that both adsorption and diffusion strongly affect the transport of water, and that the processes of diffusion and adsorption can be separately quantified once the system comes to a steady state. At shallow depths of clay, water vapor transport is determined by diffusion through both the atmosphere and the clay layer, whereas at greater depth the rate of sublimation of the ice is governed only by diffusion through the clay. Using two different models, we determine the diffusion coefficient for water vapor through unconsolidated clay layer to be 1.08±0.04×¹⁰⁻⁴ and . We also determined the adsorption isotherms for the clay layer, which follow the Langmuir theory at low water vapor pressure (<100 Pa, where a monolayer of water molecules forms on the surface of the clay) and the BET theory at higher pressure (where multiple water layers form). From our analysis of both types of isotherms we determined the adsorption constants to be and c=30±10, respectively, and specific surface areas of 1.10±0.2×¹⁰⁵ and , respectively. Finally, we report a theoretical kinetic model for the simultaneous diffusion and adsorption from which we determine adsorption kinetic constants according to the Langmuir theory of and . If the martian regolith possesses diffusive properties similar to those of the unconsolidated montmorillonite soil we investigated here, it would not represent a significant barrier to the sublimation of subsurface ice. However, at the low subsurface temperatures of high latitude (180 K on average), ice could survive from the last glaciation period (about 300 to 400,000 years ago). Higher subsurface temperatures in the equatorial regions would prevent long-timescale survival of ice in the shallow subsurface. In agreement with previous work, we show that adsorption of water by a clay regolith could provide a significant reservoir of subsurface water and it might account for the purported diurnal cycle in the water content of the atmosphere.