北疆阿尔泰南缘泥盆系浅变质碎屑沉积岩地球化学特征及其形成环境

对于北疆阿尔泰地区泥盆纪所处的大地构造环境,目前仍旧存在不同观点。前人基于阿尔泰南缘泥盆纪火山岩地球化学研究,分别提出了活动大陆边缘和被动大陆边缘裂谷等不同构造观点。阿尔泰造山带南缘的泥盆纪浅变质碎屑沉积岩地球化学研究表明,该套浅变质碎屑沉积岩原岩主要为泥质或砂质沉积岩。尽管不同岩性样品主量元素含量不同,但其化学蚀变指数(CIA)小于75,成分变异指数(ICV)接近或小于1.0,斜长石蚀变指数(PIA)平均70,说明其源区物质比较新鲜,成熟度相对较低,化学风化作用较弱。同样,不同岩性样品微量元素含量差别较大,但表生过程中不活泼的微量元素比值却比较一致,轻稀土(LREE)中度富集(La_N/Yb_N=2.88～9.90),重稀土(HREE)比较平坦,并伴有明显的Eu负异常(Eu/Eu~*= 0.45～0.89)。绝大多数样品具有高的La/Sc(1～3)、La/Y(0.5～1)和Ti/Zr(10～35),以及较低的Sc/Cr(0.1～0.3)比值,类似于大陆岛弧相关环境碎屑沉积物。在La-Th-Sc和Th-Sc-Zr/10构造环境判别图解中,除一千枚岩样品外,其他所有样品均落入大陆岛弧区。以上地球化学特征明显不同于大洋岛弧和被动陆缘沉积物,说明该套浅变质碎屑沉积岩可能沉积于活动大陆边缘的大陆岛弧相关环境,为认识阿尔泰造山带泥盆纪岛弧增生构造演化过程提供了一个重要证据。     

Interstitial water chemistry of the inner continental shelf sediments off the gironde estuary

The interstitial water composition ( , alkalinity, Ca²⁺, Mg²⁺, Sr²⁺, Na⁺, K⁺) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of and Ca²⁺ and below a 30 cm depth show depletions of Mg²⁺. Inversely, the upper 10 cm an enrichment of Ca²⁺ concentration, and an increase of K⁺ concentration to a 40 cm depth. High values of are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca²⁺ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg²⁺ depletion is accompanied by bicarbonate loss. This proves that Mg²⁺ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg²⁺ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core.     

末次盛冰期以来渤、黄、东海陆架底质分布演变过程模拟研究

渤、黄、东海陆架底质的形成分布与末次盛冰期之后的海侵密切相关。末次盛冰期结束、海侵开始以来 ,潮流是渤、黄、东海陆架上的永久性主导作用应力。为从长期沉积动力演变过程的角度 ,探讨渤、黄、东海陆架底质形成分布的有关成因问题 ,利用数值模拟手段 ,再现了末次盛冰期以来 6个时期渤、黄、东海陆架潮流作用下海底的冲淤格局及底质分布。结果表明 ,扬子浅滩南侧东海外陆架的砂质沉积基本上是自 - 80 m海面以来形成的。扬子浅滩形成于 -5 2 m海面之后 ,至 - 3 0 m海面时已有一定规模 ,全新世最大海侵之后 ,逐渐形成现在规模的扬子浅滩。南黄海中部泥自 - 5 2 m海面时就已开始形成 ,- 3 0 m海面时范围很大 ,侵入北黄海 ,全新世最大海侵以来 ,逐渐调整到现在的范围。渤海中央泥、北黄海西部泥、浙闽岸外泥、辽东半岛西侧与北侧的砂质沉积、西朝鲜湾与江华湾中的砂质沉积以及苏北浅滩是自全新世最大海侵以来逐渐形成的。海州湾中砂质沉积形成的盛期在公元 8世纪之后。济洲岛西南泥、南黄海东部泥很可能分别形成于 - 3 0 m海面、- 5 2 m海面以来。全新世渤、黄、东海陆架底质分布的演变过程大致分为 2个阶段 :全新世最大海侵之前为渤、黄、东海陆架底质分布宏观格局的形成阶段 ;全新世最大海侵至今为渤     

Influence of sedimentary environments on mechanical properties of clastic rocks

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.     

Diagenesis and origin of calcite cement in the Flemish Pass Basin sandstone reservoir (Upper Jurassic): Implications for porosity development

The Flemish Pass Basin is a deep-water basin located offshore on the continental passive margin of the Grand Banks, eastern Newfoundland, which is currently a hydrocarbon exploration target. The current study investigates the petrographic characteristics and origin of carbonate cements in the Ti-3 Member, a primary clastic reservoir interval of the Bodhrán Formation (Upper Jurassic) in the Flemish Pass Basin.The Ti-3 sandstones with average Q_86.0F_3.1R_10.9 contain various diagenetic minerals, including calcite, pyrite, quartz overgrowth, dolomite and siderite. Based on the volume of calcite cement, the investigated sandstones can be classified into (1) calcite-cemented intervals (>20% calcite), and (2) poorly calcite-cemented intervals (porous). Petrographic analysis shows that the dominant cement is intergranular poikilotopic (300–500 μm) calcite, which stared to form extensively at early diagenesis. The precipitation of calcite occured after feldspar leaching and was followed by corrosion of quartz grains. Intergranular calcite cement hosts all-liquid inclusions mainly in the crystal core, but rare primary two-phase (liquid and vapor) fluid inclusions in the rims ((with mean homogenization temperature (T_h) of 70.2 ± 4.9 °C and salinity estimates of 8.8 ± 1.2 eq. wt.% NaCl). The mean δ¹⁸O and δ¹³C isotopic compositions of the intergranular calcite are −8.3 ± 1.2‰, VPDB and −3.0 ± 1.3‰, VPDB, respectively; whereas, fracture-filling calcite has more depleted δ¹⁸O but similar δ¹³C values. The shale normalized rare earth element (REE_SN) patterns of calcite are generally parallel and exhibit slightly negative Ce anomalies and positive Eu anomalies. Fluid-inclusion gas ratios (CO₂/CH₄ and N₂/Ar) of calcite cement further confirms that diagenetic fluids originated from modified seawater. Combined evidence from petrographic, microthermometric and geochemical analyses suggest that (1) the intergranular calcite cement precipitated from diagenetic fluids of mixed marine and meteoric (riverine) waters in suboxic conditions; (2)the cement was sourced from the oxidation of organic matters and the dissolution of biogenic marine carbonates within sandstone beds or adjacent silty mudstones; and (3) the late phases of the intergranular and fracture-filling calcite cements were deposited from hot circulated basinal fluids.Calcite cementation acts as a main controlling factor on the reservoir quality in the Flemish Pass reservoir sandstones. Over 75% of initial porosity was lost due to the early calcite cementation. The development of secondary porosity (mostly enlarged, moldic pores) and throats by later calcite dissolution due to maturation of organic matters (e.g., hydrocarbon and coals), was the key process in improving the reservoir quality.     

Small channels: Their experimental formation,nature, and significance

The manner in which small channels are generated, from plane beds beneath sheet flows, has been experimentally elucidated. On plane, erodible, sand beds, the transition from thin, supercritical sheet flows to the channelled condition was studied over ranges of discharge, slope, and temperature. Secondary flow of the second kind, its action facilitated by steep vertical velocity gradients in the primary flows, caused sheet-flow instability. Along junctions between neighbouring secondary cells, both either raised or lowered elements of the primary flow. In the latter case, fast surface water was lowered to the bed, causing relatively intense, local, longitudinal scour. Dislodged grains were moved divergently to either side, leaving straight, central trenches. Development of positive feedback between cells and trenches led to rapid enlargement of the latter and concomitant growth of paired levees. The resulting structures, ‘protochannels’, were themselves ephemeral, developing two types of instability associated with secondary flow of the first kind. Firstly, small deviations from bilateral symmetry were enhanced, causing evolution into meandering channels. Secondly, headcutting led to multiple tributary development and, at resulting confluences, the action of strong pairs of secondary cells led to the development of braiding channels. Because they are shortlived, protochannels are but rarely seen in nature. Their seeding is markedly temperature-sensitive, reflecting their frictional origin. The erosive power of shallow overland flow largely depends on flow-energy concentration by secondary flow, firstly into channels, then within the channels themselves. Suppression of secondary flow, as by intense raindrop bombardment, can stabilize sheet flows. In deeper water, the effects of secondary flow appear relatively less dramatic. However, even if such motion is weak, bedload divergence from attachment lines can favour entrainment locally and thus affect bed geometry. Analogy between our results and river behaviour appears close and. on continental shelves where water must often flow as sheets, structures resembling giant protochannels evidently persist.     

永平水泄铜钴矿控矿因素

水泄铜钴矿区地质条件较为复杂,控矿因素较多,通过分析认为主要受断层及岩性控制,地层初始富集,构造及区域变质作用提供通道及热源。水的循环、溶解作用形成热卤水成矿。     

Shallow-marine massive sandstone sheets as indicators of palaeoseismic liquefaction — An example from the Ordovician shelf of Central Bolivia

The Middle to Upper Ordovician siliciclastic succession in Central Bolivia provides excellent exposures of up to 1 m thick massive sandstone beds produced by liquefaction-induced sediment remobilisation. These fine-grained massive sandstones occur in shallow-marine nearshore facies that were deposited above storm wave base. Vertical to steeply inclined clastic dykes, which penetrate up to 1.5 m of the overlying sediment pile, feed into the basal parts of massive sandstone sheets. These dykes are interpreted as pathways used by liquefied sediment during upward-directed escape from a subsurface horizon. The relatively short lateral spacing of 5 to 25 m between the individual dykes initiated lateral coalescence of ejected individual sediment bodies. As a result, massive sandstone sheets formed and can be traced laterally over several kilometres. While undeformed sandy deposits contain between 5 to 10% dispersed clay the average clay content in massive sandstone sheets is ∼ 15%. The elongated, sometimes S-shaped form of the sandy, laminated fragments reflects squeezing during movement showing that they have been deformed under shear stress during flow. The axis of maximum elongation of the fragments indicates local flow direction. As the massive sandstone sheets are likely the products of seismic shocks they provide the first evidence of tectonic activity in this part of the basin during the Middle to Late Ordovician.     

辽东半岛南部早古生代馒头组—冶里组沉积盆地演化

辽东半岛南部早古生代地层发育,其中馒头组—冶里组的沉积过程,具有完整的陆源碎屑岩—碳酸盐岩堆积特点。从层序划分、沉积环境演化、古气候变迁等方面分析,馒头组—冶里组反映了一个完整的碳酸盐岩台地的发展过程,可划分出准备阶段（形成碎屑岩垫板）、生长—发育阶段（形成碳酸盐岩缓坡）及衰亡阶段（发育白云岩盖层）。     

Provenance of Oligocene–Miocene sediments in the Subei area,eastern Altyn Tagh fault and its geological implications: Evidence from detrital zircons LA-ICP-MS U–Pb chronology

Oligocene–Miocene strata in the Subei and Xiaobiegai basins of the Subei area, located in the eastern Altyn Tagh fault (ATF), northern Tibetan Plateau, record important characteristics of the ATF evolution. Detrital zircons laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb ages from two samples, together with paleocurrent directions and clastic composition in the Xishuigou section demonstrate that sediments in the Subei basin originated from the Danghenanshan range along its southern margin. Detrital zircons U–Pb ages from three samples in the Xiaobiegai basin, together with paleocurrent directions and clastic composition, indicate that sediments in the Xiaobiegai basin may partly originate from terranes along the northeastern margin of the basin in addition to the Danghenanshan range. Our results, combined with regional evolution, suggest that the Xiaobiegai and the Subei basins was a combined basin in Oligocene–early Miocene. This basin was folded, tilted, and dislocated at ca. 8 Ma by rapid uplift of the northern Tibetan plateau and rapid strike-slip of the ATF. As a result, the Subei basin became a thrust–fold belt of the Danghenanshan range front, and the Xiaobiegai basin grew into an intermontane basin in the northeastern part of the Danghenanshan range. Thus, the Subei area gradually acquired its present morphotectonic patterns.