藻类分子生物技术两年评─—与藻类活性物质研究有关的生物技术

根据１９９２年６月－１９９４年６月国内外发表资料，评述海洋藻类活性物质研究的生物技术及最新成果。认为，海洋生物活性物质研究的重心正转向与海洋生物技术有关的研究。运用生物技术筛选、提取并生产藻类活性物质已经成为这一领域的主流。综合文献表明，藻类活性物质的生物技术正走向成熟，大量的活性物质被发现，光生物反应器将成为主要的下游生产技术，通过藻类基因工程生产药物已初现端倪。     

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

西藏马攸木金矿床金银互化物的赋存状态

马攸木金矿床是西藏近年发现的首例规模较大、矿石品位富、金成色高的岩金矿床.作者通过对马攸木金矿床矿石组构、矿石共生组合及矿物特征研究发现,金银互化物主要有自然金、含银自然金、银金矿、自然银.载金矿物为黝铜矿、针铁矿、脆硫锑铅矿及石英;金银互化物的赋存形式主要为包裹体金、裂隙金及粒间金.金银互化物的形成、富集与热液成矿作用及表生风化作用关系密切.     

加氯水体有机浓集物对团头鲂血液指标的影响

本文对团头鲂 2项血液学指标 (红细胞数 RBC和血红蛋白量 Hb)的正常值进行了研究 ,同时检测了加氯水体中有机浓集物对这 2项指标的影响。结果表明 ,团头鲂血液中 RBC和 Hb的正常值受生长和水温等因素影响 ;在相同的试验条件下 ,加氯水体中的有机浓集物对团头鲂血液 RBC和 Hb有抑制作用 ,抑制率分别为 4 .3 %～ 2 6.0 %和 5.0 %～ 2 2 .5% ,表明此类物质对鱼类正常的生长代谢有一定的危害。     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

微区分析在地质研究中的应用

微区分析是现代分析技术在地质研究应用中的一个重要领域。通过电子探针对矿物的微区分析，提供了矿床成因理论研究的新依据。本文以金银互化物的研究为例，讨论了在不同在因类型矿床中，金－银构成一个连续的类质同象系列，且变化是有规律可循，其微量元素的含量与该矿床成矿地质环境和相应的地球化学场有关，从而为找矿提供了新的地质信息，拓宽了寻找同类伴生元素矿床或发现新类型矿床的途径。     

有机溴化物的溴同位素测试技术及其生物地球化学指示意义

有机溴化物已成为继有机氯化物之后又一值得关注的全球性新兴持久性有机污染物。稳定Br同位素测试技术的快速发展,为有机溴化物生物地球化学循环研究提供了更为有效的技术支撑。在综述稳定Br同位素研究进展的基础上认为：①基于GC-MC-ICPMS技术基础上的有机单体Br同位素（CSIA-OBr）是Br同位素研究的主要趋势,难点是...     

苯并噻吩系列化合物的成因模拟及其地球化学意义

在硫和β胡萝卜素反应产物中有丰富的苯并噻吩系列化合物,在硫与饱和链状化合物反应产物中既有噻吩系列化合物也有苯并噻吩系列化合物。所以推断苯并噻吩系列是硫作用于噻吩系列或含侧链的苯而形成的。噻吩系列和苯并噻吩系列的相对含量可以指示成熟度:在沉积条件相同的前提下,前者多后者少指示成熟度低,反之则指示成熟度高。