酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

Subsurface dams to harvest rainwater— a case study of the Swarnamukhi River basin, Southern India

Declining water level trends and yields of wells, deterioration of groundwater quality and drying up of shallow wells are common in many parts of India. This is mainly attributed to the recurrence of drought years, over exploitation of groundwater, increase in the number of groundwater structures and explosion of population. In this subcontinent, the saving of water has to be done on the days it rains. India receives much of its rainfall in just 100 h in a year mostly during the monsoon period. If this water is not captured or stored, the rest of the year experiences a precarious situation manifest in water scarcity. The main objective behind the construction of subsurface dams in the Swarnamukhi River basin was to harvest the base flow infiltrating into sandy alluvium as waste to the sea and thereby to increase groundwater potential for meeting future water demands. An analysis of hydrographs of piezometers of four subsurface dams, monitored during October 2001–December 2002, reveals that there is an average rise of 1.44 m in post-monsoon and 1.80 m in the pre-monsoon period after the subsurface dams were constructed. Further, during the pre-monsoon month of June, much before construction of subsurface dams in October 2001, the water level was found fluctuating in the range of 3.1–10 m, in contrast to the fluctuation ranging from 0.4 to 3.1 m during the period following the construction of dams. Hence, the planning of rainwater harvesting structures entails thorough scientific investigations for identifying the most suitable locations for subsurface dams.     

Origin and tectonic significance of a Mesozoic multi-layer over-thrust system within the Yangtze Block (South China)

In the Yangtze Block (South China), a well-developed Mesozoic thrust system extends through the Xuefeng and Wuling mountains in the southeast to the Sichuan basin in the northwest. The system comprises both thin- and thick-skinned thrust units separated by a boundary detachment fault, the Dayin fault. To the northwest, the thin-skinned belt is characterized by either chevron anticlines and box synclines to the northwest or chevron synclines to the southeast. The former structural style displays narrow exposures for the cores of anticlines and wider exposures for the cores of synclines. Thrust detachments occur along Silurian (Fs) and Lower Cambrian (Fc) strata and are dominantly associated with the anticlines. To the southeast, this style of deformation passes gradually into one characterized by chevron synclines with associated principal detachment faults along Silurian (Fs), Cambrian (Fc) and Lower Sinian (Fz) strata. There are, however, numerous secondary back thrusts. Therefore, the thin-skinned belt is like the Valley and Ridge Province of the North American Applachian Mountains. The thick-skinned belt structurally overlies the thin-skinned belt and is characterized by a number of klippen including the Xuefeng and Wuling nappes. It is thus comparable to the Blue Ridge Province of Appalachia.The structural pattern of this thrust system in South China can be explained by a model involving detachment faulting along various stratigraphic layers at different stages of its evolution. The system was developed through a northwest stepwise progression of deformation with the earliest delamination along Lower Sinian strata (Fz). Analyses of balanced geological cross-sections yield about 18.1–21% (total 88 km) shortening for the thin-skinned unit and at least this amount of shortening for the thick-skinned unit. The compressional deformation from southeast to northwest during Late Jurassic to Cretaceous time occurred after the westward progressive collision of the Yangtze Block with the North China Block and suggests that the orogenic event was intracontinental in nature.     

Problems of the solution: intervention into small-scale irrigation for drought proofing in the Mekele Plateau of northern Ethiopia

The Mekele Plateau, located in the semi-arid northern highland region of Ethiopia, is a drought-prone, highly degraded area. It has long been neglected by policymakers and thus recurring famine, widespread poverty, armed conflicts and mass outmigration have contributed to the near collapse of the farming systems and the livelihoods of the population. Traditional stream diversion irrigation has been practised in this area for several centuries. The systems of water management in particular may be considered inappropriate owing to the need for thriftiness in water use imposed by the local environment. The systems of headworks and canals are crude and wasteful on water. Recent interventions to improve the small-scale irrigation systems of the area have not been successful. Most interventions have preferred to introduce rainwater harvesting systems using micro-dams rather than trying to upgrade the traditional diversion schemes. Evaluation of irrigation structures in the field, interviews with key informants in government, analysis of documents and discussions with irrigators indicate that both the Ministry of Agriculture and SAERT-Commission's rainwater harvesting programmes have generally failed. The case of the most recent intervention by SAERT has failed because of myopic project planning, inadequate engineering studies, unsound designs, too short a time for implementation, and lack of full farmer involvement at different levels of project planning and implementation.     

Economic analysis for the production of four grape cultivars using microcatchment water harvesting systems in Iran

An economic analysis was conducted for temporal yield variations of four local grape cultivars grown in rain-fed microcatchments in the Bajgah area of Fars province, in Islamic Republic of Iran. For this study, four local cultivars of grapes were considered. The cultivars examined were Black Rishbaba, Rotabi, Asgari and Black grapes. The soil type was a gravely loam with an average slope of 5–6%, in microcatchment systems, and in plots without microcatchments. Analysis of yield data with a multiple regression model indicated that a 9 m² (3×3 m) microcatchment area for each individual plant (vine) was the most appropriate area for vineyards in this region. The results also demonstrated that by using this area for each grapevine, yields (kg/ha) were 40% greater than yields obtained for vines in the standard vineyard (without microcatchments) in this area. Economic analysis was performed and the cost and income were compared for a depreciation period (life-span period) of 50 years and interest rate of 14%. The analysis showed that a microcatchment area of 9 m² is economically feasible. The Black Rishbaba rain-fed vines were the most suitable cultivar for this region. The benefit probabilities of rain-fed Black Rishbaba, Rotabi, Asgari and Black grapes with a microcatchment area of 9 m² and without such an area were 63.3% (i.e. two of 3 years), 52.4% (i.e. one of 2 years), 32.9% (i.e. one of 3 years), 13.3% (i.e. one of 8 years), and 59.5% (i.e. two of 3 years), 39.4% (i.e. two of 5 years), 31.8% (i.e. one of 3 years), and 10.7% (i.e. one of 9 years), respectively. Therefore, the Black Rishbaba and Rotabi cultivars are economically more stable in microcatchment system, while only the Black Rishbaba cultivar would be such in the standard vineyard system.     

Experimental investigation on a cabin-suspended catamaran in terms of motion reduction and wave energy harvesting by means of a semi-active motion control system

A novel concept catamaran equipped with a suspended cabin, named Wave Harmonizer Type 4 (WHzer-4), is proposed and evaluated. The mass-spring-mass system is constructed by mounting four sets of suspensions in-between the cabin and the twin-hull. Two sets of dual motor/generators (M/Gs) are attached on the center beam of the cabin's deck fore and aft. Each shaft-end of the dual M/Gs is connected to the twin-hull through a rack-pinion gear unit. In this way the vertical relative motion between the cabin and the twin-hull can be transferred into the rotational motion of the M/Gs, and vice versa. A semi-active motion control system, which contains a proportional-integral (PI) controller, is designed and applied to each of the dual M/Gs for the aim of absorbing wave energy under the condition of suppressing the local vertical velocity of the cabin as much as possible. A 1/5 scale model ship with a length of 1.6 m is built, and a forced-oscillation bench test is implemented to validate the performance of the control system. Then, a series of towing tank tests is carried out in regular head waves. The heave and pitch responses of the cabin, those of the twin-hull and the corresponding wave energy capture width ratio (CWR) at five control scenarios and two reference scenarios are investigated. Discussion on the results of the tank test shows that the motion reduction of the cabin and the wave energy harvesting can be achieved simultaneously at a few wave conditions. However, at other conditions, although noticeable amount of wave energy is harvested, motion reduction of the heave and pitch of the cabin could not be obtained at the same time. It is suggested that varying the gain settings of the PI controllers according to the location of the controllers may improve the effectiveness of the proposed control system.     

Effect of connecting rain barrels on the storage size reduction

In this article, the possibility of sharing rain barrels and the potential benefit of reducing storage size through physical and non‐physical connections of rain barrels in a community are investigated. Using the concepts of homogeneous/heterogeneous users in rainwater harvesting systems (RWHS), two simple cases of a community composed of four prospective users are examined. The first is performed with the users who have the same mean and variance in water demands (homogeneous users), and the second is with the users with different means and variances (heterogeneous users). To take account for the rainfall characteristics in different places, historical records from six cities in the USA are used for storage–reliability–yield analysis. The result indicates that required total storage can be reduced by connecting multiple rain barrels. In addition, a significant difference is found between homogeneous and heterogeneous user groups. Homogeneous users do not achieve a substantial benefit from connecting their rain barrels; these users may even be disadvantaged by sharing. In contrast, heterogeneous users receive benefit by reducing the total required storage. Most benefit is expected between users with maximum difference in mean water demands. The reduction in storage size was as considerable as 37% in this study. The quantity of storage reduction depends on locations and target reliabilities. Knowledge of the benefits and limitations of rain barrel connections can improve RWHS performance through ability to customize a network plan for individual users. Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of commercial timber harvesting on streamflow regimes in the Plynlimon catchments,mid‐Wales

This paper presents the first large‐scale British study of the impacts of commercial forest cutting on stream‐flow regimes. The 70% forested headwaters of the River Severn are part of the intensively instrumented long‐term Plynlimon catchment study into the impact of land use on stream flow. The forest area, comprising predominantly Sitka spruce (Picea sitchensis), was planted mainly in the 1930s and 1940s. Harvesting commenced in the mid‐1980s and over the study period about half the forest has been felled. Changes in annual water yield and extreme flows were studied in four nested catchments ranging in area from about 1 to 10 km² and compared with an adjacent benchmark grassland catchment. As expected from earlier process studies the cutting of the forest increased total annual flows. Less expected was the clear evidence that the felling augmented low flows. This informs a long‐standing debate whether upland forestry increases or reduces baseflows. A particularly notable result was the lack of impact of the harvesting on storm peak flows. This may result from the application of forest management guidelines designed to reduce soil damage and erosion during the harvesting, and indicates that the forest itself has a limited impact on flooding. These findings are timely because British forest expansion peaked in the 30 years following the Second World War, and large areas of these woodlands are now approaching economic maturity and will be harvested in the next two decades. Copyright © 2004 John Wiley & Sons, Ltd.     

最近十年来中国地理科学的进展

最近十年来中国地理科学的最重要进展有:自然地理学与人文地理学的平衡发展,人口、资源、环境的研究,遥感的应用与地理信息系统的建立,自然地理定位观测,青藏高原隆起对自然环境的影响,城市与城市规划,中国历史地理研究等。最近,并已开始研究气候变化与海平面上升对中国的影响,使我国地理科学研究紧紧跟上世界发展的步伐。