土壤聚合物对几种重金属离子固化效果的研究

土壤聚合物是一种新型的无机聚合物,其分子链由Si、O、Al等以共价键或离子键连接而成,形成网络结构,对重金属有较强的固定作用.本文试图利用土壤聚合物固化铜、锌、铅三种重金属离子,实现资源化利用.实验以固化体抗压强度和浸出毒性作为性能表征量,结果表明:土壤聚合物对不同重金属的固化有各自的极限浓度,Cu2 、Zn2 、Pb2 的理想固化量分别为0.9%、1%、2%;若固化过程中添加一定量的高炉矿渣,则可以提高固化体的抗压强度.本文通过土壤聚合物固化体SEM分析,从固化体微观结构的形态来阐述土壤聚合物宏观上的优越表现.     

Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum

Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc.     

汞对三角褐指藻生长影响的研究——汞与浮游植物相互作用(Ⅰ)

采用连续培养技术研究汞对三角褐指藻生长的影响。当长时间接触含HgCl_2(范围5～25μg/dm~3)的培养介质中,得到结果表明,藻的生长速率随汞浓度增加而降低,细胞所排泄的有机物增加,对细胞中Chl-a的含量有一定程度影响,并抑制对硝酸盐和磷酸盐的吸收。在最初的2—4天中,汞对生物化学过程影响最大。     

盐碱水NaCl浓度和碱度对银鲫(Carassius auratus gibelio)幼鱼毒性的初步研究

通过对银鲫(Carassiusauratusgibelio)幼鱼(L=3.56±0.28cm)的NaCl浓度(pH=8.80±0.10)及碱度(pH=8.84±0.26)的急性毒性试验，用概率单位法求得其24，48，96h的半致死浓度(LC50值)NaCl浓度分别为11.53、10.77、8.58g/L；碱度分别为98.74、79.49、64.19mmol/L。在此基础上采用水生毒理联合效应相加指数法进行了氯化钠与碳酸氢钠浓度的联合毒性实验(浓度=11)，结果在96h内二者的关系全部为协同作用,且其协同性逐渐减弱并趋向于相加作用。     

长江口水域双带蛤科一新种

于１９８５－１９８６年在长江口的底栖生物取样中，采到大量双壳类软体动物标本。鉴定表明，其中一新种，被定名为中华团结蛤Ａｂｒａ ｓｉｍｉｃａ ｓｐ．ｎｏｖ。，属樱蛤超科中的双带科（Ｓｅｍｅｌｉｄａｅ）。模式标本保存于中国科学院海洋研究所。     

四氯化碳对杜氏盐藻的毒性实验

按等浓度对数间距0．2设置毒物四氯化碳(CCl4)浓度对杜氏盐藻进行了毒性实验，根据细胞的生长以及β-胡萝卜素含量的变化，观察CCl4,对盐藻的毒性效应。结果表明，CCl4浓度小于0．13％时对盐藻生长及β-胡萝卜素累积几乎没有影响。盐藻对CCl4的最大耐受浓度为0．20％。CCl4浓度达到0．32％时，5天之后造成细胞全部死亡和β-胡萝卜素累积消失。     

卤虫的发育与蜕皮

我国北方孤雌生殖卤虫在盐度为60,水温为19—28℃的条件下,自卵内孵出无节幼虫长成至性成熟产仔(无节幼虫或卵),需经蜕皮12—15次,其中多数为14次,历时15—18天,随后每次产仔即行蜕皮一次,本文描述了卤虫各个不同令期发育的外部形态变化,并根据其蜕皮次数和形态特征,将卤虫的发育分为十五令(15th instar)。此外还观察到在孤雌生殖的卵中有发育成为雄性的个体。     

用纤维素乙酸平板电泳测定中国卤虫的同功酶变异(英文)

本文报导了应用纤维素乙酸平板电泳方法,测定采于中国山东省东方红盐场卤虫(Artemia)的同功酶。经测定,8种同功酶其中有6种是多态的,即:苹果酸脱氢酶(MDH)、异柠檬酸酶(IDH)、谷氨酸草醋酸转移酶(GOT)、葡糖-6-磷酸盐脱氢酶(D6PHD)、6-磷酸萄糖脱氢酶(6PGDH)和磷酸葡糖异构酶(PGI)。本文所提供的研究方法,不仅适用于基础研究,而且在水产养殖业上有助于对卤虫的筛选和确证。     

4种重金属离子对海洋三角褐指藻生长影响的研究

于１９９３年４月－１９９３年５月以Ｚｎ＾２＋，Ｃｄ＾２＋，Ｐｂ＾２＋，Ｃｕ＾２＋不同浓度的海水对三角褐指藻进行生长影响的研究。实验表明，Ｃｕ＾２＋对三角褐指藻生长的毒性最大，其９６ｈＥＣ５０为０．０１７ｍｇ／Ｌ。Ｐｂ＾２＋的毒性最小，其９６ｈＥＣ５０为０．４６８ｍｇ／Ｌ。４种重金属离子的毒性顺序是Ｃｕ＾２＋＞Ｃｄ＾２＋＞Ｚｎ＾２＋＞Ｐｂ＾２＋，除Ｃｄ＾２＋外，其他３种金属离子对该单细胞藻的生长安全     

珠江河口铜、铅、锌、铬和镉对单细胞藻类生长的影响

通过现场采水样和实验室模拟,研究珠江河口环境在一连串变化过程中,当各种浓度的Cu,zn,Pb,Cr和Cd单独存在或共存时,对单细胞藻类——硅藻和扁藻的毒性影响。