西藏驱龙斑岩铜钼矿床中UST石英的发现:初始岩浆流体的直接记录

单向固结结构(UST)是浅成侵位的岩浆出溶过程中形成的一种特殊结构,一般由梳状石英与细晶(斑岩)岩交互生长而成,少数产于斑岩与围岩接触部位,其内的原生包裹体被认为是初始流体出溶的可靠记录.作者在西藏驱龙铜矿床中首次发现了具有单向固结结构的石英.研究表明,驱龙UST石英存在于后期侵位的二长花岗斑岩与花岗闪长岩的接触部位,部分为高温β石英;UST石英中原生包裹体的成分主要为高盐度液相,除石盐子矿物外,还含有硬石膏等其他子矿物.阴极发光及显微测温结果表明,初始流体的出溶发生在高温(t≥573℃)、高压(P≥150～200 MPa)条件下,出溶的流体为高温、高盐度[w(NaCkeq)为44.5%～58%]流体,同时还具有较高的氧逸度.因形成压力较高,判断UST石英不可能由较浅侵位的二长花岗斑岩岩枝冷凝出溶而形成,从而推测驱龙铜矿床深部存在着孕育成矿斑岩的大型岩基.     

便携式Li-K分析仪的研制及其在锂辉石中锂的分析应用

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现了样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345~1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在仪器最佳工作条件下测定Li、K的精密度(RSD,n=14)均低于2%,检出限为0.03μg/m L,检测范围0.1~10μg/m L。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。     

水和水蒸气辅助粗晶三水铝石转化为勃姆石的机制研究

在165℃、175℃、185℃和195℃的温度条件下,对水热处理前和处理后的粗晶三水铝石样品分别进行了XRD分析和SEM表征,研究了粗晶三水铝石在水蒸气和热水中转变成勃姆石的相变过程。结果表明,水热条件下粗晶三水铝石转化成勃姆石的过程受控于溶解-再沉淀机制,而并非是通常认为的固体状态下的转变;相对于在热水中,水蒸气环境可以加速三水铝石向勃姆石的转化;所形成的勃姆石的粒径（4~7 μm）明显比前驱体三水铝石的粒径（120~200 μm）要小得多,表明可以利用粗晶三水铝石生产微晶勃姆石。在转化过程中,勃姆石微晶首先生长在三水铝石的晶体表面上,通过控制反应温度和反应时间,可形成壳层为勃姆石、壳下为三水铝石的具有双层结构的铝的氢氧化物颗粒,也有可能形成具有中空结构的勃姆石集合体颗粒。     

Role of the Nocturnal Low-level Jet in the Formation of the Morning Precipitation Peak over the Dabie Mountains

The diurnal variation of precipitation over the Dabie Mountains(DBM) in eastern China during the 2013 mei-yu season is investigated with forecasts of a regional convection-permitting model. Simulated precipitation is verified against surface rain-gauge observations. The observed morning precipitation peak on the windward(relative to the prevailing synoptic-scale wind) side of the DBM is reproduced with good spatial and temporal accuracy. The interaction between the DBM and a nocturnal boundary layer low-level jet(BLJ) due to the inertial oscillation mechanism is shown to be responsible for this precipitation peak. The BLJ is aligned with the lower-level southwesterly synoptic-scale flow that carries abundant moisture.The BLJ core is established at around 0200 LST upwind of the mountains. It moves towards the DBM and reaches maximum intensity at about 70 km ahead of the mountains. When the BLJ impinges upon the windward side of the DBM in the early morning, mechanical lifting of moist air leads to condensation and subsequent precipitation.     

Preliminary results of 4-D water vapor tomography in the troposphere using GPS

Slant-path water vapor amounts (SWV) from a station to all the GPS (Global Positioning System) satellites in view can be estimated by using a ground-based GPS receiver. In this paper, a tomographic method was utilized to retrieve the local horizontal and vertical structure of water vapor over a local GPS receiver network using SWV amounts as observables in the tomography. The method of obtaining SWV using ground-based GPS is described first, and then the theory of tomography using GPS is presented. A water vapor tomography experiment was made using a small GPS network in the Beijing region. The tomographic results were analyzed in two ways: (1) a pure GPS method, i.e., only using GPS observables as input to the tomography; (2) combining GPS observables with vertical constraints or a priori information, which come from average radiosonde measurements over three days. It is shown that the vertical structure of water vapor is well resolved with a priori information. Comparisons of profiles between radiosondes and GPS show that the RMS error of the tomography is about 1–2mm. It is demonstrated that the tomography can monitor the evolution of tropospheric water vapor in space and time. The vertical resolution of the tomography is tested with layer thicknesses of 600 m, 800 m and 1000 m. Comparisons with radiosondes show that the result from a resolution of 800m is slightly better than results from the other two resolutions in the experiment. Water vapor amounts recreated from the tomography field agree well with precipitable water vapor (PWV) calculated using GPS delays. Hourly tomographic results are also shown using the resolution of 800 m. Water vapor characteristics under the background of heavy rainfall development are analyzed using these tomographic results. The water vapor spatio-temporal structures derived from the GPS network show a great potential in the investigation of weather disasters.     

两种方法提取肠浒苔挥发油成分的比较研究

本研究分别采用水蒸气蒸馏法(SD)和溶剂提取法(SE)提取肠浒苔(Ulva intestinalis)的挥发油,通过GC-MS技术对其进行化学成分分析,以峰面积归一法对各成分进行相对定量.结果显示,SD法对肠浒苔挥发油的提取率(0. 038%)低于SE法(0. 800%). SD法所获得的肠浒苔挥发油共鉴定出46种成分,占挥发油总成分的81. 63%,SE法所获得的挥发油共鉴定出30种成分,占挥发油总成分的94. 89%,两者相同成分21种,主要成分均为烃类和醛类物质. SD样品中十五醛的相对含量最高(18. 12%),SE样品中8-十八烷烯的相对含量最高(51. 49%).     

宇宙信息

火星大气中的超饱和水蒸气 欧洲空间局火星快车探测器发现,在火星的大气层中存在超饱和的水蒸气。这一令人吃惊,的结果对于了解火星上的水循环以及火星大气的历史变迁具有重大的意义。     

真空冷冻干燥和烘干对滑带土孔隙特征的影响试验

采用水蒸气吸附法和恒速压汞法测定了三峡库区巴东县黄土坡滑坡Ⅰ号支洞滑带土在真空冷冻干燥和烘干状态下的孔隙特征.研究表明,滑带土烘干样中墨水瓶形孔道内水分子发生凝聚、堵塞,导致其比表面积和吸附水蒸气的能力均小于滑带土冻干样.滑带土烘干样失水收缩,团粒结构更紧密,滑带土吸附势减小,在微孔区间其累积孔隙体积和最大孔隙体积均小于滑带土冻干样.在考虑水蒸气表面张力情况下,滑带土冻干样吸附和脱附的孔隙表面分形维数均大于烘干样,说明烘干样失水后在各种化学键引力作用下使孔隙表面更趋于平滑.压汞实验结果表明在微孔和中孔区间,冻干滑带土的孔隙直径和孔隙体积均大于烘干样,但孔隙直径在0.133~129.051 μm区间,烘干样的孔隙体积大于冻干样,且直径大于41.421 μm的颗粒体积比冻干样大.