Ab Initio Prediction of ^29Si-NMR Chemical Shifts

The ability of several ab initio models to predict experimental 29Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allyltrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6-31G^*, B3LYP/6-31G^* , HF/6-311 G^**, B3LYP/6-311 G^** and MPWlPW91/6-311 G^** models respectively. The 29Si chemical shifts calculated by GIAO method using HF/6-311 G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

银盘恒星运动学和化学丰度与银河系结构

大样本的银盘恒星的运动学数据和元素丰度特征是研究银河系结构及演化，尤其是银盘形成和演化的2个重要探针。本文首先介绍了银河系的总体结构特征，然后较详细的综述了以上2个探针的重要性。对我国LAMOST项目在研究银河系结构方面，尤其是银盘的形成和演化方面的能力作了合理的分析。     

The Relation between the Amplitude and the Period of Solar Cycles

The maximum amplitudes of solar activity cycles are found to be well anti-correlated (r = -0.72) with the newly defined solar cycle lengths three cycles before (at lag -3) in 13-month running mean sunspot numbers during the past 190 years. This result could be used for predicting the maximum sunspot numbers. The amplitudes of Cycles 24 and 25 are estimated to be 149.5±27.6 and 144.3±27.6, respectively.     

利用历史有感地震目录（M≥3（1／2））研究华北地区地震活动性特征

对新编的华北地区历史有感地震目录（３（１／２）≤Ｍ＜４（１／２））的精度和可信度进行了讨论。认为该地震目录从１４８４年后的记载率较高，它的发震时间、震中位置和震级的精度基本可以满足研究历史地震活动性的需要。它与中国地震目录（Ｍ≥４（３／４））比较，补充了相当数量的３（１／２）≤Ｍ≤４（１／２）的地震。利用历史有感地震目录分析了华北北部部分６级以上的历史地震，结果表明，这些地震在强震发生前具有明显的空区、条带、地震活动性增强、平静等前兆特征，同时，也显示了某些强＊发生前的前震活动和主震之后起伏的强余震活动     

SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…