Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

关于网络用户经济效益评测模型的研究

着重讨论了网络用户经济效益的内涵以及用户的投入量和产出量，并提出了评价网络用户经济效益的指标体系，包括成本降低率，成本利润增长率、产品开发时间约率、市场占有增长率等系列指标。     

成都及附近地区旅游气候资源研究

通过对成都及附近等7个地区多年气候资源及人体舒适指数进行分级比较，得出了7个地区的人体舒适指数的时间分布特征及对当地旅游的影响。     

广西岩溶区金属硫化物矿床风化与元素表生迁移特征

对广西岩溶区三个铅锌硫化物矿床风化带观测结果表明，中低山岩溶区硫化物矿床具有更强烈的风化淋滤作用，但次生晕面积较小；岩溶平原区硫化物矿床风化与元素表生迁移特征较相似于非岩溶区的情况，表现在可产生较宽的ｐＨ偏低带和较大面积的次生晕     

Microbial release of potassium from K-bearing minerals by thermophilic fungus Aspergillus fumigatus

A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles.     

An Attempt to Predict the Failure Time of Abandoned Mine Pillars

Summary  Left in place pillars of abandoned mines are subject to weathering (e.g action of water, bacteria) that degrades their mechanical strength and eventually leads to collapse. A simple weathering model is proposed, that is governed by two parameters: the rate of progression of weathered front and the rate of degradation of the compressive strength with time. Both plane strain and axisymmetric analyses are performed and closed form solutions of the variation with time of the bearing capacity of the pillar are given. Experimental data of the tests conducted on gypsum and anhydrite specimens attacked by water are presented. It is shown that in order to fit the experimental data a third parameter must be introduced. New closed form solutions are given and the data are used for estimating the time to failure of abandoned gypsum mines in Northern Italy. Authors’ address: Dr. Riccardo Castellanza, Research Assistant, Department of Structural Engineering, Milan University of Technology (Politecnico), Piazza Leonardo da Vinci 32, 20133 Milan, Italy     

Response of the barrier island coastal region of southwestern Nigeria to climate and non-climate forcing

Despite threats emanating from the influence of climate and non-climate forcing on the barrier island coastal region of southwestern Nigeria, the extent of the coastal erosion is poorly understood. We report evidence of coastal erosion and sediment accumulation in the region over a 34-year period (1973–2017), using Landsat imagery at intervals of approximately six years. Landsat image corrections and various water-extraction algorithms were used to systematically delineate coastal erosion and accumulation in the area. The region was subdivided into western and eastern subregions separated by Lagos Harbour. In the west, erosion took place during the periods 1973–1979, 1979–1984, 1990–1999 and 2005–2011, whereas in the east, erosion occurred during 1973–1979, 1990–1999 and 1999–2005. Coastal sediment accumulation occurred in the east during 1979–1984, 1984–1990, 2005–2011 and 2011–2017, whereas gains in the west occurred during 1984–1990, 1999–2005 and 2011–2017. The study revealed substantial net erosion of 1 228.1 ha in the region as a whole, over the full period. Sediment accumulation accompanying the coastal erosion appears to be linked to longshore drift. Erosion between 1973 and 2011 was probably attributable to climate change (storms and tidal conditions), longshore drift, the inflow and outflow of water at Lagos Harbour, coastal morphology and, possibly, human impacts. However, the coastal changes between 2011 and 2017 were more obviously associated with human activities, such as development of the Eko Atlantic construction project. Coastal surveillance, together with the use of environmentally sensitive protective measures, could possibly help to reduce coastal erosion in the region. Careful coastal management practices, including artificial nourishing and the installation of resilient structures (e.g. seawalls), should be undertaken to protect human settlements that are already at risk from sea-level rise.